Nonansure Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R34:Verursacht Verätzungen.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Beschreibung
Nonanoic acid , also called pelargonic acid, is an organic compound composed of a nine - carbon chain terminating in a carboxylic acid with structural formula CH
3(CH
2)
7COOH. Nonanoic acid forms esters—nonanoates. It is a clear, oily liquid with an unpleasant, rancid odor. It is nearly insoluble in water, but very soluble in chloroform, ether, and hexane.
Its refractive index is 1.4322. Its critical point is at 712 K ( 439 °C ) and 2.35 MPa.
Chemische Eigenschaften
Nonanoic acid has a fatty, characteristic odor and a corresponding unpleasant taste. May be prepared by oxidation of methylnonyl ketone; by oxidation of oleic acid; or from heptyl iodide via malonic ester synthesis.
Occurrence
Nonanoic acid is a fatty acid which occurs naturally as esters in the oil of pelargonium. Synthetic esters, such as methyl nonanoate, are used as flavorings.
Nonanoic acid is also used in the preparation of plasticizers and lacquers.
The derivative 4-nonanoylmorpholine is an ingredient in some pepper sprays.
The ammonium salt of nonanoic acid, ammonium nonanoate, is used as an herbicide.
Verwenden
The primary uses of this acid are in organic synthesis and in
the manufacture of lacquers, plastics, pharmaceuticals, synthetic
odors and flavorings, gasoline additives, flotation
agents, lubricants, and vinyl plasticizers. Nonanoic acid
has found some use in pharmaceutical preparations and as
a topical bactericide and fungicide. It is also used in
herbicides.
Definition
ChEBI: A C9 straight-chain saturated fatty acid which occurs naturally as esters of the oil of pelargonium. Has antifungal properties, and is also used as a herbicide as well as in the preparation of plasticisers and lacquers.
Allgemeine Beschreibung
Nonanoic acid occurs naturally in Pelargonium L′Her. It one of the flavor constituents of cooked rice, acerola fruit, licorice and yogurt.
Landwirtschaftliche Anwendung
Herbicide, Fungicide: Pelargonic acid occurs naturally in many plants and
animals. It is used to control the growth of weeds and as a
blossom thinner for apple and pear trees. It is also used as
a food additive; as an ingredient in solutions used to commercially
peel fruits and vegetables
Handelsname
CIRRASOL®-185A; ECONOSAN®;
EMERY® 202 (mixture with n-octoic acid);
EMFAC®-1202; HEXACID® C-9; PELARGON®;
SCYTHE®; WEST AGRO ACID SANITIZER®
Sicherheitsprofil
Poison by intravenous
route. Moderately toxic by ingestion. A
severe skin and eye irritant. When heated to
decomposition it emits acrid smoke and
irritating fumes.
mögliche Exposition
Pelargonic acid, a naturally occurring
fatty acid herbicide/fungicide. It is used to control the
growth of weeds and as a blossom thinner for apple and
pear trees. It is also used as a food additive; as an ingredient
in solutions used to commercially peel fruits and
vegetables; in the manufacture of lacquers, plastics and
pharmaceuticals.
läuterung methode
Esterify the acid with ethylene glycol and distil the ester. (This removes dibasic acids as undistillable residues.) The acid is regenerated by hydrolysing the ester in the usual way and is distilled in vacuo. [Beilstein 2 IV 1018.]
Inkompatibilitäten
Heated vapors may form explosive mixture
with air. May react violently with strong oxidizers,
bromine, 90% hydrogen peroxide, phosphorus trichloride,
silver powders or dust. Incompatible with strong bases and
silver compounds; mixture with some silver compounds
may form explosive salts of silver oxalate.
Waste disposal
Do not discharge into drains
or sewers. Dispose of waste material as hazardous waste
using a licensed disposal contractor to an approved landfill.
Contact a licensed disposal facility about surplus and
non-recyclable solutions. Burn in a chemical incinerator
equipped with an afterburner and scrubber. Extra care must
be exercised as the material in an organic solvent is highly
flammable. Consult with environmental regulatory agencies
for guidance on acceptable disposal practices. Incineration
with effluent gas scrubbing is recommended. Containers
must be disposed of properly by following package label
directions or by contacting your local or federal environmental
control agency, or by contacting your regional EPA
office.
Nonansure Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
