(2R)-Bornane-10,2-sultam
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- CAS-Nr.
- 94594-90-8
- Englisch Name:
- (2R)-Bornane-10,2-sultam
- Synonyma:
- D-SultaM;(1S,2R)-(-)-;(2R)-Bornane-10;L-(+)-CAMPHOR SULTAM;(2R)-Bornane-10,2-su;(-)-10,2-CAMPHORSULTAM;(1S)-(-)-Camphorsultam;(2R)-Borne-10,2-sultam;(-)-2,10-Camphorsultam;(1S)-2,10-CAMPHORSULTAM
- CBNumber:
- CB9468760
- Summenformel:
- C10H17NO2S
- Molgewicht:
- 215.31
- MOL-Datei:
- 94594-90-8.mol
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(2R)-Bornane-10,2-sultam Eigenschaften
- Schmelzpunkt:
- 183-185 °C
- alpha
- -33 º (c=4.9, CHCl3)
- Siedepunkt:
- 324.8±25.0 °C(Predicted)
- Dichte
- 1.1469 (rough estimate)
- Brechungsindex
- -31 ° (C=1, CHCl3)
- storage temp.
- Sealed in dry,Room Temperature
- Löslichkeit
- Chloroform, Ethanol, Methanol
- Aggregatzustand
- Liquid
- pka
- 11.05±0.40(Predicted)
- Farbe
- Clear colorless
- Optische Aktivität
- [α]19/D 32°, c = 5 in chloroform
- Wasserlöslichkeit
- Slightly soluble in water.
- BRN
- 83811
- CAS Datenbank
- 94594-90-8(CAS DataBase Reference)
- NIST chemische Informationen
- (-)-10,2-Camphorsultam(94594-90-8)
(2R)-Bornane-10,2-sultam Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
white to light yellow crystal powde
Verwenden
(2R)-Bornane-10,2-sultam is a reagent used to make Camphorsultam conjugates.
Allgemeine Beschreibung
(1
S,2
R,4
R)-(?)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.
läuterung methode
The (-)-enantiomer is recrystallised from 95% EtOH and dried in a vacuum desiccator. It dissolves in dilute aqueous NaOH and can be precipitated without hydrolysis by acidifying. It forms the N-Na salt in EtOH (by addition of Na to the EtOH solution), and the salt can be methylated with MeI to give the (-)-N-Me lactam with m 80o after recrystallisation from hot H2O and has []D -59.6o (c 5, CHCl3) [Shriner et al. J Am Chem Soc 60 2794 1938]. [Oppolzer et al. Helv Chim Acta 69 1142 1986, Weismiller et al. Org Synth 69 154 1955, Beilstein 27 III/IV 1007.]
(2R)-Bornane-10,2-sultam Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(2R)-Bornane-10,2-sultam Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 263)Lieferanten
94594-90-8()Verwandte Suche:
- (-)-EXO-10,2-BORNANESULTAM
- (-)-D-2,10-CAMPHORSULTAM
- (-)-D-2,10-CAMPHOSULTAM
- D(-)-10,2-CAMPHORSULTAME
- (2R)-BORNANE-10,2-SULTAM
- (1S)-(-)-2,10-CAMPHORSULTAM
- (1S)-2,10-CAMPHORSULTAM
- (1S,2R)-(-)-2,10-CAMPHORSULTAM
- (1S,5R)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.0(1,5)]DECANE 3,3-DIOXIDE
- (-)-10,2-CAMPHORSULTAM
- [3AS-(3A-ALPHA,6-ALPHA,7A-BETA)]-HEXAHYDRO-8,8-DIMETHYL-2,2-DIOXIDE-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE
- [3as-(3aalpha,6alpha,7abeta)]-hexahydro-8,8-dimethyl-2,2-dioxide-3h-3a,6-methano-2,1-benzisothiazole
- [3AS-(3AALPHA,6ALPHA,7ABETA)]-HEXAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE-2,2-DIOXIDE
- (1S)-(-)-Camphorsultam
- (1S,2R)-(-)-10,2-Camphorsultam
- (1S,2R)-(-)-2,10-CAMPHORSULTAME
- 3H-3a,6-Methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)-
- (-)-exo-10,2-Bornanesultam, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide
- (-)-10,2-Camphorsultam, (-)-exo-10,2-Bornanesultam, [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide, (1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide
- (2R)-10,2-Camphorsultam
- (2R)-Bornane-10,2-sultam, 99+%, ee:>99%
- D-(+)-CAMPHOR SULTAM INFRA-ACIDAMIDE
- L-(+)-CAMPHOR SULTAM
- (IS)-(-)-2,10-Camphorsultam
- (2R)-Bornane-10,2-sultam ,98%
- [3aS-(3aα,6α,7aβ)]-hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide
- (2R)-Bornane-10,2-sultam99+%(>99% ee)
- (3aR)-Hexahydro-8,8-dimethyl-3H-3aα,6α-methano-2,1-benzisothiazole 2,2-dioxide
- (3aS)-1,3,5,6,7,7aα-Hexahydro-4H-3aβ,6β-isopropylidene-2,1-benzisothiazole 2,2-dioxide
- (3aS)-1,4,5,6,7,7aα-Hexahydro-8,8-dimethyl-3H-3aβ,6β-methano-2,1-benzisothiazole 2,2-dioxide
- (3aS,7aα)-8,8-Dimethyl-3aβ,6β-methanooctahydro-2,1-benzisothiazole 2,2-dioxide
- (7aα)-8,8-Dimethyl-3aβ,6β-methanooctahydro-2,1-benzisothiazole 2,2-dioxide
- [3aS,7aα,(-)]-Hexahydro-8,8-dimethyl-3H-3aβ,6β-methano-2,1-benzisothiazole 2,2-dioxide
- (1S,2R)-(-)-
- (2R)-Bornane-10,2-su
- (2R)-Bornane-1,2-sultaM
- (1S)-(-)-10,2-CaMphorsultaM
- Hexahydro-8,8-diMethyl-3H-3a,6-Methano-2,1-benzisothiazole
- D-SultaM
- (2R)-Bornane-10,2-sultam
(1S,5R)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]decane 3,3-Dioxide
- (2R)-Bornane-10,2-sultaM, 99+%
- (1S,2R)-(-)-2,10-CAMPHORSULTAME FOR SYNT
- (3aS,6S,7aS)-8,8-DiMethylhexahydro-1H-3a,6-Methanobenzo[c]isothiazole 2,2-dioxide
- (2R)-Bornane-10,2-sultam
(1S)-(-)-2,10-Camphorsultam
- (1S)-(-)-2,10-Camphorsultam
- (2R)-Borne-10,2-sultam
- D-2,10-Camphorsultam,99%e.e.
- (2R)-Bornane-10, 2-sultam, ≥99% ee
- (-)-10,2-Camphorsultam >
- (1S)-(?)-2,10-CamphorsuL
- (-)-10,2-Camphorsultam?
- (1S)-(-)-2,11-Camphorsultam
- (2R)-Bornane-10,2-sultam ISO 9001：2015 REACH
- (-)-2,10-Camphorsultam
- (1S,2R)-(-)-10,2-Camphorsultam, 99%,
- (5R,7R)-10,10-dimethyl-3thia-4-azatricyclo[5.2.1.01?]decane 3,3-dioxide
- (3aS,6R,7aR)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide
- (2R)-Bornane-10
