ChemicalBook >> CAS DataBase List >>Chloromethyltrimethoxysilane

Chloromethyltrimethoxysilane

CAS No.
5926-26-1
Chemical Name:
Chloromethyltrimethoxysilane
Synonyms
ND-40;DK833;DK343;DK342;DKSI159;DKFELEX0218;Co-Formula CFS-C261;CHLOROMETHYLTRIMETHOXYSILANE;Chloromethvltrimethoxysilane;chloromethyl-trimethoxy-silan
CBNumber:
CB0114833
Molecular Formula:
C4H11ClO3Si
Molecular Weight:
170.67
MDL Number:
MFCD00468107
MOL File:
5926-26-1.mol
MSDS File:
SDS
Last updated:2026-01-13 11:12:52
Product description Number Pack Size Price
Chloromethyltrimethoxysilane 96% 597201 25g $290
(Chloromethyl)trimethoxysilane >98.0%(GC) C3073 5g $58
(Chloromethyl)trimethoxysilane >98.0%(GC) C3073 25g $173
Chloromethyltrimethoxysilane 96% JK118720 5g $60
(Chloromethyl)trimethoxysilane J99963 100g $154
More product size

Chloromethyltrimethoxysilane Properties

Boiling point 151 °C (lit.)
Density 1.132 g/mL at 25 °C (lit.)
refractive index 1.407 [25°C]
Flash point 26 °F
storage temp. Storage temp. 2-8°C
form clear liquid
Specific Gravity 1.125
color Colorless to Almost colorless
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
InChI InChI=1S/C4H11ClO3Si/c1-6-9(4-5,7-2)8-3/h4H2,1-3H3
InChIKey FPOSCXQHGOVVPD-UHFFFAOYSA-N
SMILES [Si](CCl)(OC)(OC)OC
CAS DataBase Reference 5926-26-1(CAS DataBase Reference)
NIST Chemistry Reference Silane, chloromethyl-trimethoxy-(5926-26-1)
UNSPSC Code 12352103
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  F
Risk Statements  11
Safety Statements  16-29-33
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  VV2625000
TSCA  No
HazardClass  3
PackingGroup  II
HS Code  29319090
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 2
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Chloromethyltrimethoxysilane price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 597201 Chloromethyltrimethoxysilane 96% 5926-26-1 25g $290 2023-06-20 Buy
TCI Chemical C3073 (Chloromethyl)trimethoxysilane >98.0%(GC) 5926-26-1 5g $58 2026-04-30 Buy
TCI Chemical C3073 (Chloromethyl)trimethoxysilane >98.0%(GC) 5926-26-1 25g $173 2026-04-30 Buy
Frontier Specialty Chemicals JK118720 Chloromethyltrimethoxysilane 96% 5926-26-1 5g $60 2021-12-16 Buy
AK Scientific J99963 (Chloromethyl)trimethoxysilane 5926-26-1 100g $154 2021-12-16 Buy
Product number Packaging Price Buy
597201 25g $290 Buy
C3073 5g $58 Buy
C3073 25g $173 Buy
JK118720 5g $60 Buy
J99963 100g $154 Buy

Chloromethyltrimethoxysilane Chemical Properties,Uses,Production

Chemical Properties

Clear transparent liquid

Uses

Chloromethyltrimethoxysilane may be used in the preparation of 1-methyl-1H-benzimidazole (MBI)-modified nanoparticles.{33} Mesoporous monolithic silica gels can also be prepared from Chloromethyltrimethoxysilane. {34}

General Description

Chloromethyltrimethoxysilane (CMTMS) is a trialkoxysilane with chloromethyl as the organofunctional group having hydrophobic characteristics. Chloromethyl is the electron withdrawing group that improves the mechanical properties of the molecule. CMTMS is mainly utilized as a silane based precursor material for the preparation of surface enhancement based coatings and other silane based products.

Synthesis

(Chloromethyl)trichlorosilane

1558-25-4

Trimethoxymethane

149-73-5

Chloromethyltrimethoxysilane

5926-26-1

The general procedure for the synthesis of chloromethyltrimethoxysilane from chloromethyltrichlorosilane and trimethyl orthoformate was as follows: 570.2 g (3.1 mol) of chloromethyltrichlorosilane was slowly added dropwise to 1127.8 g (10.64 mol) of trimethyl orthoformate, and the dropwise acceleration was controlled so that the reaction mixture was kept at a slight boiling state. After the dropwise addition was completed, the reaction system was heated to 90°C and the reaction was maintained at this temperature for 5 hours. Upon completion of the reaction, the reaction mixture was purified by distillation, resulting in 449.8 g of the target product chloromethyltrimethoxysilane (Compound 2a). The structure of the product was confirmed by 1H NMR spectrum with the following chemical shifts δ (ppm): 2.77 (single peak, 2H, CH2), 3.58 (single peak, 9H, OCH3).

References

[1] Russian Journal of General Chemistry, 2016, vol. 86, # 8, p. 1859 - 1863
[2] Zh. Obshch. Khim., 2016, vol. 86, # 8, p. 1321 - 1326,6

Chloromethyltrimethoxysilane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Chloromethyltrimethoxysilane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Chloromethyltrimethoxysilane pictures 2021-08-11 Chloromethyltrimethoxysilane
5926-26-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Chloromethyltrimethoxysilane pictures 2019-07-06 Chloromethyltrimethoxysilane
5926-26-1
US $2.00 / KG 1KG 98% customise Career Henan Chemical Co

Chloromethyltrimethoxysilane Spectrum

(trimethoxychloromethyl)silane chloromethyl-trimethoxy-silan CHLOROMETHYLTRIMETHOXYSILANE Silane,(chloromethyl)trimethoxy- ND-40 (Trimethoxysilyl)chloromethane Chloro(trimethoxysilyl)methane Co-Formula CFS-C261 (Chloromethyl)trimethoxysilane > DK343 DK833 DK342 Chloromethvltrimethoxysilane DKFELEX0218 DKSI159 chloromethyl-trimethoxy-silan,95% 5926-26-1 C4H11ClO3Si C4H14ClO3Si H3CO3SiCH2Cl Alkoxy Silanes Alpha Silanes Self Assembly&Contact Printing Self-Assembly Materials Silanes