Chloromethyltrimethoxysilane
- CAS No.
- 5926-26-1
- Chemical Name:
- Chloromethyltrimethoxysilane
- Synonyms
- ND-40;DK833;DK343;DK342;DKSI159;DKFELEX0218;Co-Formula CFS-C261;CHLOROMETHYLTRIMETHOXYSILANE;Chloromethvltrimethoxysilane;chloromethyl-trimethoxy-silan
- CBNumber:
- CB0114833
- Molecular Formula:
- C4H11ClO3Si
- Molecular Weight:
- 170.67
- MDL Number:
- MFCD00468107
- MOL File:
- 5926-26-1.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Chloromethyltrimethoxysilane 96% | 597201 | 25g | $290 |
| (Chloromethyl)trimethoxysilane >98.0%(GC) | C3073 | 5g | $58 |
| (Chloromethyl)trimethoxysilane >98.0%(GC) | C3073 | 25g | $173 |
| Chloromethyltrimethoxysilane 96% | JK118720 | 5g | $60 |
| (Chloromethyl)trimethoxysilane | J99963 | 100g | $154 |
| More product size | |||
| Boiling point | 151 °C (lit.) |
|---|---|
| Density | 1.132 g/mL at 25 °C (lit.) |
| refractive index | 1.407 [25°C] |
| Flash point | 26 °F |
| storage temp. | Storage temp. 2-8°C |
| form | clear liquid |
| Specific Gravity | 1.125 |
| color | Colorless to Almost colorless |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| InChI | InChI=1S/C4H11ClO3Si/c1-6-9(4-5,7-2)8-3/h4H2,1-3H3 |
| InChIKey | FPOSCXQHGOVVPD-UHFFFAOYSA-N |
| SMILES | [Si](CCl)(OC)(OC)OC |
| CAS DataBase Reference | 5926-26-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Silane, chloromethyl-trimethoxy-(5926-26-1) |
| UNSPSC Code | 12352103 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS02 |
|---|---|
| Signal word | Danger |
| Hazard statements | H225 |
| Precautionary statements | P210 |
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard Codes | F |
| Risk Statements | 11 |
| Safety Statements | 16-29-33 |
| RIDADR | UN 1993 3/PG 2 |
| WGK Germany | 3 |
| RTECS | VV2625000 |
| TSCA | No |
| HazardClass | 3 |
| PackingGroup | II |
| HS Code | 29319090 |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Flam. Liq. 2 |
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
Chloromethyltrimethoxysilane price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 597201 | Chloromethyltrimethoxysilane 96% | 5926-26-1 | 25g | $290 | 2023-06-20 | Buy |
| TCI Chemical | C3073 | (Chloromethyl)trimethoxysilane >98.0%(GC) | 5926-26-1 | 5g | $58 | 2026-04-30 | Buy |
| TCI Chemical | C3073 | (Chloromethyl)trimethoxysilane >98.0%(GC) | 5926-26-1 | 25g | $173 | 2026-04-30 | Buy |
| Frontier Specialty Chemicals | JK118720 | Chloromethyltrimethoxysilane 96% | 5926-26-1 | 5g | $60 | 2021-12-16 | Buy |
| AK Scientific | J99963 | (Chloromethyl)trimethoxysilane | 5926-26-1 | 100g | $154 | 2021-12-16 | Buy |
Chloromethyltrimethoxysilane Chemical Properties,Uses,Production
Chemical Properties
Clear transparent liquid
Uses
Chloromethyltrimethoxysilane may be used in the preparation of 1-methyl-1H-benzimidazole (MBI)-modified nanoparticles.{33} Mesoporous monolithic silica gels can also be prepared from Chloromethyltrimethoxysilane. {34}
General Description
Chloromethyltrimethoxysilane (CMTMS) is a trialkoxysilane with chloromethyl as the organofunctional group having hydrophobic characteristics. Chloromethyl is the electron withdrawing group that improves the mechanical properties of the molecule. CMTMS is mainly utilized as a silane based precursor material for the preparation of surface enhancement based coatings and other silane based products.
Synthesis
1558-25-4
149-73-5
5926-26-1
The general procedure for the synthesis of chloromethyltrimethoxysilane from chloromethyltrichlorosilane and trimethyl orthoformate was as follows: 570.2 g (3.1 mol) of chloromethyltrichlorosilane was slowly added dropwise to 1127.8 g (10.64 mol) of trimethyl orthoformate, and the dropwise acceleration was controlled so that the reaction mixture was kept at a slight boiling state. After the dropwise addition was completed, the reaction system was heated to 90°C and the reaction was maintained at this temperature for 5 hours. Upon completion of the reaction, the reaction mixture was purified by distillation, resulting in 449.8 g of the target product chloromethyltrimethoxysilane (Compound 2a). The structure of the product was confirmed by 1H NMR spectrum with the following chemical shifts δ (ppm): 2.77 (single peak, 2H, CH2), 3.58 (single peak, 9H, OCH3).
References
[1] Russian Journal of General Chemistry, 2016, vol. 86, # 8, p. 1859 - 1863
[2] Zh. Obshch. Khim., 2016, vol. 86, # 8, p. 1321 - 1326,6
Chloromethyltrimethoxysilane Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13843 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29819 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| Hubei Co-Formula Material Tech Co., Ltd. | +86-27-84459282 | sales@cfmats.com | CHINA | 882 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-87569266 +86-17392581500 | 1015@dideu.com | China | 3992 | 58 |
| BEYOND INDUSTRIES (CHINA) LIMITED | +86-21-52699951; +8613917686115 | sales@beyondindustriesgroup.com | China | 699 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD. | +86-0532-8699-9256 +8615254267723 | kaley@cnfdevelop.com | China | 1410 | 58 |
View Lastest Price from Chloromethyltrimethoxysilane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2021-08-11 | Chloromethyltrimethoxysilane
5926-26-1
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
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2019-07-06 | Chloromethyltrimethoxysilane
5926-26-1
|
US $2.00 / KG | 1KG | 98% | customise | Career Henan Chemical Co |
-

- Chloromethyltrimethoxysilane
5926-26-1
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-

- Chloromethyltrimethoxysilane
5926-26-1
- US $2.00 / KG
- 98%
- Career Henan Chemical Co
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