ChemicalBook >> CAS DataBase List >>2,5-Diaminobenzenesulfonic acid

2,5-Diaminobenzenesulfonic acid

CAS No.
88-45-9
Chemical Name:
2,5-Diaminobenzenesulfonic acid
Synonyms
2,5-Diaminobenzenesulfonic;2-Sulfo-1,4-phenylenediamine;2-Sulfo-p-phenylenediamine;2,5-Diaminobenzolsulfonsure;2,5-diaminobenzenesulfonate;2,5-diamino-benzenesulfonicaci;2,5-DIAMINOBENZENESULFONIC ACID;P-PHENYLENEDIAMINESULFONIC ACID;2,5-diaminobenzenesulphonic acid;2,5-Diaminophenyl-1-sulfonic acid
CBNumber:
CB0117652
Molecular Formula:
C6H8N2O3S
Molecular Weight:
188.2
MDL Number:
MFCD00007904
MOL File:
88-45-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-12 09:10:49
Product description Number Pack Size Price
2,5-Diaminobenzenesulfonic acid ≥97.0% (T) 32776 50g $80.9
2,5-Diaminobenzenesulfonic acid ≥97.0% (T) 32776 250g $193
1,4-Phenylenediamine-2-sulfonic Acid >98.0%(HPLC)(T) P1691 5g $28
1,4-Phenylenediamine-2-sulfonic Acid >98.0%(HPLC)(T) P1691 25g $89
2,5-Diaminobenzenesulfonic acid D422570 250mg $45
More product size

2,5-Diaminobenzenesulfonic acid Properties

Melting point 298-300 °C (dec.) (lit.)
Boiling point 500°C
Density 1.366 (estimate)
vapor pressure 0Pa at 25℃
refractive index 1.6490 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility 2.308g/L in organic solvents at 20 ℃
pka 5.17±0.10(Predicted)
form solid
color White to Light gray to Light orange
Water Solubility 4g/L at 26℃
BRN 2970398
InChI 1S/C6H8N2O3S/c7-4-1-2-5(8)6(3-4)12(9,10)11/h1-3H,7-8H2,(H,9,10,11)
InChIKey HEAHMJLHQCESBZ-UHFFFAOYSA-N
SMILES Nc1ccc(N)c(c1)S(O)(=O)=O
LogP 0.146 at 26℃
CAS DataBase Reference 88-45-9(CAS DataBase Reference)
FDA UNII UP8112D78N
EPA Substance Registry System Benzenesulfonic acid, 2,5-diamino- (88-45-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C,Xi
Risk Statements  34-36/37/38
Safety Statements  26-36/37/39-45-36
RIDADR  UN 2583 8/PG 2
WGK Germany  2
RTECS  DB5900100
TSCA  TSCA listed
HS Code  2921.59.8090
HazardClass  8
PackingGroup  III
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Skin Corr. 1B
REACH Registrations Active
NFPA 704
1
3 0

2,5-Diaminobenzenesulfonic acid price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 32776 2,5-Diaminobenzenesulfonic acid ≥97.0% (T) 88-45-9 50g $80.9 2026-04-30 Buy
Sigma-Aldrich 32776 2,5-Diaminobenzenesulfonic acid ≥97.0% (T) 88-45-9 250g $193 2026-04-30 Buy
TCI Chemical P1691 1,4-Phenylenediamine-2-sulfonic Acid >98.0%(HPLC)(T) 88-45-9 5g $28 2026-04-30 Buy
TCI Chemical P1691 1,4-Phenylenediamine-2-sulfonic Acid >98.0%(HPLC)(T) 88-45-9 25g $89 2026-04-30 Buy
TRC D422570 2,5-Diaminobenzenesulfonic acid 88-45-9 250mg $45 2021-12-16 Buy
Product number Packaging Price Buy
32776 50g $80.9 Buy
32776 250g $193 Buy
P1691 5g $28 Buy
P1691 25g $89 Buy
D422570 250mg $45 Buy

2,5-Diaminobenzenesulfonic acid Chemical Properties,Uses,Production

Chemical Properties

violet powder

Uses

2,5-Diaminobenzenesulfonic acid was used in preparation of a polymeric dye, required for laccase-mediated dyeing of cotton.

General Description

2,5-Diaminobenzenesulfonic acid is a dye precursor. Electrochemical copolymerization of 2,5-diaminobenzensulfonic acid and aniline by cyclic voltammetry on IrO2 coated titanium electrodes was reported.

Flammability and Explosibility

Non flammable

Synthesis

Weigh 39g of iron powder added to 1000mL four flask, add water 300mL stirring, add 6g of ammonium chloride and 4mL concentrated hydrochloric acid, warming to 95 , slowly add nitro to add speed to regulate the temperature to maintain above 90 , add too fast easy to rush material danger, add continue to hold for a period of time, when taking a drop of the reaction liquid drop to the disappearance of the yellow ooze circle on the filter paper that is the end point of the reaction, add sodium hydroxide solution to adjust pH = 10, filtration, filtration is 2,5-diaminobenzenesulfonic acid. Add sodium hydroxide solution, adjust pH=10, filter, add hydrochloric acid to the filtrate acid precipitation, filtration that is 2,5-diaminobenzenesulfonic acid.

3457-98-5
88-45-9
Synthesis of 2,5-Diaminobenzenesulfonic acid from 4-AMINOAZOBENZENE HYDROCHLORIDE
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View Lastest Price from 2,5-Diaminobenzenesulfonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,5-Diaminobenzenesulfonic acid  pictures 2025-11-18 2,5-Diaminobenzenesulfonic acid
88-45-9
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
2,5-Diaminobenzenesulfonic acid pictures 2025-04-15 2,5-Diaminobenzenesulfonic acid
88-45-9
US $45.00 / kg 1kg 99% 5000kg/week Hebei Zhuanglai Chemical Trading Co.,Ltd
2,5-Diaminobenzenesulfonic acid pictures 2023-03-13 2,5-Diaminobenzenesulfonic acid
88-45-9
US $0.00-0.00 / kg 1kg 98%Min 1000kg LY Global chemicals co.,ltd .
1,4-PHENYLENEDIAMINE-2-SULPHONIC ACID 1,4-PHENYLENEDIAMINE-3-SULFONIC ACID 1,4 DIAMINOBENZENE 2 SULFONIC ACID 2,5-DIAMINOBENZENESULFONIC ACID 2,5-DiaMinobenzenesulfonic acid, 97%, contains <10% Monohydrochloride salt 1,4-Diamino-2-benzenesulfonic acid 2,5-Diaminophenyl-1-sulfonic acid 2,5-Diaminobenzene-1-sulfonic acid 2,5-Diaminobenzenesulfonic acid,90%,tech. P-PHENYLENEDIAMINESULFONIC ACID PARA PHENYLENE DIAMINE SULFONIC ACID 2,5-diamino-benzenesulfonicaci Benzenesulfonic acid,2,5-diaMino- 2,5-DiaMinobenzenesulfonic acid >=97.0% (T) 2-Sulfo-p-phenylenediamine 2,5-DIAMINOBENZENESULFONIC ACID, TECH., 90% p-Phenylenediamine-2-sulfonic acid 2,5-diaminobenzenesulphonic acid P-phenylene-diamine-ortho-sulphonic acid p-Phenylenediamine-3-sulfonic acid 2,5-Diaminobenzolsulfonsure p-Phenylenediamine-5-sulfonic acid Para Phenylene Di Amine Ortho Sulfonic Acid (PPDSA) 2,5-diaminobenzenesulfonate 1,4-Phenylenediamine-2-sulfonicAcid> 2,5-Diaminobenzenesulfonic acid ISO 9001:2015 REACH p-Phenylenediamine-2-sulphonic acid TIANFUCHEM--88-45-9---2,5-Diaminobenzenesulfonic acid 2-Sulfo-1,4-phenylenediamine 2,5-Diaminobenzenesulfonic PPDOSA P-Phenylene-Diamine-2-Sulfonic Acid PPDSA (2,5-Diaminobenzenesulfonic acid) 2 5-DIAMNIOBENZENESULFONIC ACID (PPDOSA) PARA PHENYLENE DIAMINE ORTHO SULFONIC ACID Ortho sulfonic acid para phenylenediamine 88-45-9 SO3HC6H3NH22 H2N2C6H3SO3H C6H7N2O3S Sulfonic/Sulfinic Acids Sulfur Compounds Organic Building Blocks Building Blocks Organic Building Blocks Sulfonic/Sulfinic Acids Sulfur Compounds Intermediates of Dyes and Pigments Building Blocks Chemical Synthesis Organic Building Blocks Sulfonic/Sulfinic Acids Sulfur Compounds