ChemicalBook >> CAS DataBase List >>(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh

CAS No.
521272-85-5
Chemical Name:
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh
Synonyms
(R,R)-NORPHOS-Rh;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh;(1Z,5Z)-cycloocta-1,5-diene:[(1S,2R,3R,4R)-2-diphenylphosphanyl-3-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane:rhodium:tetrafluoroborate;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-
cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
CBNumber:
CB01180967
Molecular Formula:
C31H28P2.C8H12.BF4.Rh
Molecular Weight:
760.406
MDL Number:
MFCD09839137
MOL File:
521272-85-5.mol
Last updated:2023-05-04 15:13:56

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Properties

form Powder
color red-orange
Sensitive air sensitive
CAS DataBase Reference 521272-85-5

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H315
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 45-0184 (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh 521272-85-5 100mg $129 2024-03-01 Buy
Strem Chemicals 45-0184 (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh 521272-85-5 500mg $512 2024-03-01 Buy
American Custom Chemicals Corporation OGM0000054 (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE 95.00% 521272-85-5 5MG $504.87 2021-12-16 Buy
Arctom AS442837 (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98% 521272-85-5 50mg $124 2021-12-16 Buy
Arctom AS442837 (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate 98% 521272-85-5 100mg $219 2021-12-16 Buy
Product number Packaging Price Buy
45-0184 100mg $129 Buy
45-0184 500mg $512 Buy
OGM0000054 5MG $504.87 Buy
AS442837 50mg $124 Buy
AS442837 100mg $219 Buy

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Chemical Properties,Uses,Production

Reactions

Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.  Reactions of 521272-85-5

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Preparation Products And Raw materials

Raw materials

Preparation Products

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh Suppliers

Global( 4)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9171 60
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-
cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
(1Z,5Z)-cycloocta-1,5-diene:[(1S,2R,3R,4R)-2-diphenylphosphanyl-3-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane:rhodium:tetrafluoroborate (R,R)-NORPHOS-Rh (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 521272-85-5 RhC8H12C31H28P2BF4 C39H40BF4P2Rh organometallic complex