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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

CAS No.
145214-59-1
Chemical Name:
(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms
SL-A108-2;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine);(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine);(S)-2,2'-Bis(di-2-furylphosphino)-6,6'-dimethoxy-1,1'- biphenyl;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2''-Bis(di-2-furanylphosphino)-6,6''-dimethoxy-1,1''-biphenyl;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;[2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane;Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-di-2-furanyl-
CBNumber:
CB01180987
Molecular Formula:
C30H24O6P2
Molecular Weight:
542.46
MDL Number:
MFCD09753004
MOL File:
145214-59-1.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Properties

Boiling point 587.5±50.0 °C(Predicted)
form Powder
color off-white
Stability store cold
CAS DataBase Reference 145214-59-1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3
HS Code  29321900

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 29515 (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine) ≥97%, optical purity ee: ≥99% 145214-59-1 1g $659 2023-06-20 Buy
Strem Chemicals 15-0113 (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 145214-59-1 100mg $96 2024-03-01 Buy
Strem Chemicals 15-0113 (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 145214-59-1 500mg $355 2024-03-01 Buy
Sigma-Aldrich 29515 (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine) ≥97%, optical purity ee: ≥99% 145214-59-1 100mg $101 2023-01-07 Buy
Sigma-Aldrich 29515 (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine) ≥97%, optical purity ee: ≥99% 145214-59-1 500mg $479 2023-01-07 Buy
Product number Packaging Price Buy
29515 1g $659 Buy
15-0113 100mg $96 Buy
15-0113 500mg $355 Buy
29515 100mg $101 Buy
29515 500mg $479 Buy

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Uses,Production

Reaction

In many respects the catalytic profile of the MeO-BIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Stereocontrol in palladium-catalyzed propargylic substitutions: kinetc resolution to give enantioenriched 1,5-enynes and propargyl acetates.
Study of enantioselective catalysis of nitroso-Diels-Alder reaction on solid support. Reactions of 145214-59-1

Chemical Properties

White powder

Uses

Atropisomeric MeOBIPHEP ligands

General Description

sold in collaboration with Solvias AG

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

Global( 25)Suppliers
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Suzhou Origin Specialty Chemicals Co., Ltd.
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Aladdin Scientific
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Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
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145214-59-1((S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%)Related Search:

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine) (S)-2-Furyl-MeOBIPHEP, SL-A108-2, (S)-(-)-2,2μ-Bis(di-2-furylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl (S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97% (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl SL-A108-2 (S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) >=97%, optical purity ee: >=99% [2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-di-2-furanyl- (S)-2,2'-Bis(di-2-furylphosphino)-6,6'-dimethoxy-1,1'- biphenyl (S)-(-)-2,2''-Bis(di-2-furanylphosphino)-6,6''-dimethoxy-1,1''-biphenyl (S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) 145214-59-1 C30H24O6P2 Chiral Phosphine MeOBIPHEP Series