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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)

CAS No.
309735-86-2
Chemical Name:
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)
Synonyms
NH2ME2][(RUCL((S)-TOLBINAP))2(U-CL)3;(S)-[(RuCl (T-BINAP))2(μ-Cl)3[NH2Me2];[NH2ME2][(RUCL((S)-TOLBINAP))2(Μ-CL)3];[NH2Me2][[RuCl((S)-tolbinap)]2(mu-Cl)3];Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]dir;Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(di-p-tolylphosphino)-1,1μ-binaphthyl]diruthenate(II);DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL((;[1-[2-(bis-p-tolylphosphanyl)-1-naphthyl]-2-naphthyl]-bis(p-tolyl )phosphane, dichlororuthenium, N-methylmethanamine, hydrochloride;DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-tolbinap)}2(μ-Cl)3]
CBNumber:
CB01181090
Molecular Formula:
2C48H40P2.C2H7N.Cl.Cl3Ru2.ClH
Molecular Weight:
1783.08
MDL Number:
MFCD09753034
MOL File:
309735-86-2.mol
Last updated:2023-06-08 17:06:34

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Properties

Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color brown
Sensitive air sensitive
CAS DataBase Reference 309735-86-2

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Warning
Hazard statements  H228
Precautionary statements  P210
Hazard Codes  F
Risk Statements  11
RIDADR  UN 1325 4.1/PG 3
WGK Germany  3
HS Code  2843.90.0000

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 693146 (S)-[(RuCl(T-BINAP))2(μ-Cl)3[NH2Me2] 309735-86-2 100mg $29.4 2023-01-07 Buy
Sigma-Aldrich 693146 (S)-[(RuCl(T-BINAP))2(μ-Cl)3[NH2Me2] 309735-86-2 500mg $100 2023-01-07 Buy
TCI Chemical N1018 [NH2Me2][(RuCl((S)-tolbinap))2(μ-Cl)3] 309735-86-2 200mg $45 2024-03-01 Buy
TCI Chemical N1018 [NH2Me2][(RuCl((S)-tolbinap))2(μ-Cl)3] 309735-86-2 1g $149 2024-03-01 Buy
Strem Chemicals 44-0513 Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-tolbinap)}2(μ-Cl)3] 309735-86-2 250mg $53 2024-03-01 Buy
Product number Packaging Price Buy
693146 100mg $29.4 Buy
693146 500mg $100 Buy
N1018 200mg $45 Buy
N1018 1g $149 Buy
44-0513 250mg $53 Buy

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Chemical Properties,Uses,Production

Uses

Catalyst system for asymmetric hydrogenation.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 26)Suppliers
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Hubei Jusheng Technology Co.,Ltd.
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Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) (S)-[(RuCl (T-BINAP))2(μ-Cl)3[NH2Me2] Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(di-p-tolylphosphino)-1,1μ-binaphthyl]diruthenate(II) Dimethylammoniumdichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((S)-tolbinap)}2(μ- Cl)3] DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-tolbinap)}2(μ-Cl)3] [NH2Me2][[RuCl((S)-tolbinap)]2(mu-Cl)3] [NH2ME2][(RUCL((S)-TOLBINAP))2(Μ-CL)3] DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL(( Ruthenate(1-), bis[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine-κP]]tri-μ-chlorodichlorodi-, hydrogen, compd. with N-methylmethanamine (1:1) (9CI) [1-[2-(bis-p-tolylphosphanyl)-1-naphthyl]-2-naphthyl]-bis(p-tolyl )phosphane, dichlororuthenium, N-methylmethanamine, hydrochloride Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-tolbinap)}2(mu-Cl)3] Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]dir NH2ME2][(RUCL((S)-TOLBINAP))2(U-CL)3 309735-86-2 CH32NH2C96H80Cl5P4Ru2 Ru