ChemicalBook >> CAS DataBase List >>4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- CAS No.
- 161265-03-8
- Chemical Name:
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- Synonyms
- XANT PHOS;(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane);9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE;Dimethylbisdiphenylphosphinoxanthene;[5-(diphenylphosphanyl)-9,9-diMethyl-9H-xanthen-4-yl]diphenylphosphane;Bis(diphenylphosphino)-9,9-diMethylxanthene;4,5-Bis(diphenylphosphino)-9,9;4,5-Bis(diphenylphosphino)-9,9-dimethyl;4,5-BIS(DIPHENYLPHOSPHINO)-9,9-DIMETHYLX;9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, XANTPHOS
- CBNumber:
- CB0141028
- Molecular Formula:
- C39H32OP2
- Molecular Weight:
- 578.62
- MDL Number:
- MFCD00233866
- MOL File:
- 161265-03-8.mol
- MSDS File:
- SDS
Last updated:2024-04-08 17:36:13
| Melting point | 224-228 °C(lit.) |
|---|---|
| Boiling point | 665.7±55.0 °C(Predicted) |
| Flash point | 450℃ |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Soluble in organic solvents. |
| form | Crystals |
| color | White to light yellow |
| InChIKey | CXNIUSPIQKWYAI-UHFFFAOYSA-N |
| CAS DataBase Reference | 161265-03-8(CAS DataBase Reference) |
| FDA UNII | NMU72MOG9B |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 37-20/22 | |||||||||
| Safety Statements | 37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 526460 | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 97% | 161265-03-8 | 1g | $66.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 526460 | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 97% | 161265-03-8 | 5g | $189 | 2024-03-01 | Buy |
| TCI Chemical | B2709 | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene >98.0%(HPLC) | 161265-03-8 | 1g | $57 | 2024-03-01 | Buy |
| TCI Chemical | B2709 | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene >98.0%(HPLC) | 161265-03-8 | 5g | $169 | 2024-03-01 | Buy |
| Alfa Aesar | H26241 | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene, 97% | 161265-03-8 | 1g | $83.3 | 2024-03-01 | Buy |
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Chemical Properties,Uses,Production
Application
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene is an organophosphorus compound derived from the heterocycle xanthene. It is used as a bidentate ligand and is noteworthy for having a particularly wide bite angle. Such ligands are useful in the hydroformylation of alkenes.
Chemical Properties
White to light yellow crystals
Uses
1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-phosphine is an organophosphorus compound derived from the heterocycle xanthene. It is used as a bidentate ligand and is noteworthy for having a particularly wide bite angle. Such ligands are useful in the hydroformylation of alkenes.
Uses
4,5-Bis(diphenylphosphino)-9, 9-dimethylxanthene is used as a bidentate ligand, which finds application in hydroformylation of alkenes.
Uses
suzuki reaction
Reactions
- Ligand used for the hydroformylation of alkenes.
- Ligand used in the intermolecular coupling of amides and hydrazones with aryl halides.
- Ligand used in the intermolecular coupling of amides with aryl halides or triflates.
- Ligand used in the coupling of heteroarylamines and aryl halides.
- Ligand used in the hydrophosphinylation of alkenes and alkynes.
- Ligand used for the Au(I)-catalyzed dehydrogenative silation of alcohols.
- Ligand used for the sulfinylation of aryl iodides.
- Ligand used for the Pd-catalyzed carbonylation reaction of aryl bromides and amines.
- Ligand used for the Ni-cataltzed alkynylcyanation of alkynes.
- Ligand used for the Pd-catalyzed N-arylation of 3-amino-1H-pyrazole.
- Ligand used for the Rh-catalyzed dehydrogenation borylation of cyclic alkenes.
- Ligand used for the Pd-catalyzed intermolecular coupling of H-Phosphonate diesters with benzyl halides.
- Ligand used for the Pd-catalyzed one pot synthesis of 4-aryl-1H-1,2,3-triazoles.
- Ligand used for the Pd-catalyzed intermolecular addition of formamides to alkynes.
- Ligand used for the Pd-catalyzed decarboxylative couplings of 2-(2-azaaryl)acetates with aryl halides and triflates.
- Ligand used for the Pd-catalyzed benzylic arylation of 2-methyl azaarenes
- Ligand used for the Pd-catalyzed α-arylation of heteroaromatic ketones.
- Ligand used for the Pd-catalyzed direct alkynlation of both azoles and azolines.
- Ligand used for the Cu-catalyzed intermolecular coupling of alkynes with aryl iodides.
- Ligand used for the Pd-catalyzed ene-type reaction of aldehydes with 1,3-diene.
- Ligand used for the Ru-catalyzed intermolecular addition of 2-phenylbenzoic acid onto unactivated olefins.
- Ligand used for the Pd/Cu-catalyzed direct arylation of heteroarenes.
- Ligand used for the Pd-catalyzed reaction of propargyl-substituted malonate esters with aryl halides.
- Ligand used for the Pd-catalyzed decarboxylative coupling of tertiary cyanoacetate salts with aryl halides and triflates.
- Ligand used for the Pd-catalyzed hydroesterification of alkynes.
- Ligand used for the Cu-catalyzed arylation of arylboronic acids with aldehydes.
- Ligand used for the Ru-catalyzed oxidative synthesis of heterocycles from alcohols.
- Ligand used for the Rh-catalyzed borylation of nitriles.
- Ligand used in the Pd-catalyzed α-arylation of benzylic phosphine oxides.
- Ligand used in the Pd-Catalyzed Oxidative Coupling of Enamides and Alkynes.
- Ligand used in the Pd-catalyzed difunctionalization of enol ethers to amino acetals with aminals and alcohols.
- Ligand used in the Pd-catalyzed alkoxycarbonylation of α-chloroketones.
Synthesis of 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene from Acetone and (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
Global( 540)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 402 | 58 |
| Puyang Huicheng Electronic Materials Co., Ltd. | +86-0393-+86-0393-8910800 +8615839383373 | info@huichengchem.com | China | 516 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 6710 | 58 |
| airuikechemical co., ltd. | +undefined86-15315557071 | sales02@airuikechemical.com | China | 994 | 58 |
| hebei hongtan Biotechnology Co., Ltd | +86-86-1913198-3935 +8617331935328 | sales03@chemcn.cn | China | 951 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Beijing Cooperate Pharmaceutical Co.,Ltd | 010-60279497 | sales01@cooperate-pharm.com | CHINA | 1811 | 55 |
Related articles
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- Xantphos is an organophosphorus compound derived from the heterocycle xanthene. It is used as a bidentate diphosphine ligand a....
- Aug 17，2020
View Lastest Price from 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-22 | 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
161265-03-8
|
US $80.00 / kg | 1kg | 99% | 1000 | hebei hongtan Biotechnology Co., Ltd | |
 |
2024-04-08 | xant phos
161265-03-8
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. | |
 |
2024-02-23 | 4, 5-Bis(diphenylphosphino)-9,9-dimethylxanthene
161265-03-8
|
US $34.00-108.00 / g | 25g | 0.99 | 100kg | Shanghai UCHEM Inc. |
-
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
161265-03-8
- US $80.00 / kg
- 99%
- hebei hongtan Biotechnology Co., Ltd
-
- xant phos
161265-03-8
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
-
- 4, 5-Bis(diphenylphosphino)-9,9-dimethylxanthene
161265-03-8
- US $34.00-108.00 / g
- 0.99
- Shanghai UCHEM Inc.
161265-03-8(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)Related Search:
4,5-BIS-DIPHENYLPHOSPHANYL-9,9-DIMETHYL-9H-XANTHENE
4,5-BIS(DIPHENYLPHOSPHINO)-9,9-DIMETHYLXANTHENE
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene,min.98%XANTPHOS
9,9-DiMethyl-4,5-bis(diphenylphosphiNA)xanthene
Phosphine, (9,9-diMethyl-9H-xanthene-4,5-diyl)bis[diphenyl- (9CI)
9,9-DiMethyl-4,5-bis(diphenylp
Xantphos, (9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane)
4,5-Bis(diphenylphosphino)-9,9-diMethylxanthene 97%
4,5-Bis(diphenylphosphino)-9,9-diMethylxanthene, 97+%
DiMethylbisdiphenylphosphinoxanthene SynonyMs 9,9-DiMethyl-4,5-bis(diphenylphosphino)xanthene
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene,98% XantPhos
4,5- two -9,9- two methyl oxygen hetero
Xantphos 97%
(2,3-dimethyl-9H-xanthene-1,9-diyl)bis(diphenylphosphine)
4,5-Bis(diphenylphosphino)-9,9-dimethyl-xanthene, Dimethylbisdiphenylphosphinoxanthene
4,5-Bis(diphenylphosphino)-9,9-dimethyl xanthenes
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthenes
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene 99%
9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE99%
9,9-Dimethyl m-4,5-bis(Diphenylphosphino)xanthene
4,5-Bis(diphenylphospheno)-9,9-dimethyl
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene ,98%
9,9-dimethyl-4,5-bis(diphenylphosphino)-9H-xanthene
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene,98%
4,5-Bis(diphenylphospheno)-9,9-dimethylxanthene
9,10a-dihydro-9,9-dimethyl-4,5-bis(diphenylphosphino)-8aH-xanthene
Dimethylbisdiphenylphosphinoxanthene,98%
4,5-Bis (diphenylphosphino )-9,9-dimethylxanthene（Xantphos）
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, 99% XANTPHOS
4,5-Bis(diphenylphosphino)-9,9-dimethyl-9H-xanthene
9,9-DiMethyl-4,5-bis(diphenylphosphino)xanthene, 98% 1GR
9,9-DiMethyl-4,5-bis(diphenylphosphino)xanthene, 98% 25GR
9,9-DiMethyl-4,5-bis(diphenylphosphino)xanthene, 98% 5GR
5-bis(diphenylphosphino)-9H-xanthene
9-diMethyl-4
98% XantPhos
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
4,5-Bis(diphenylphosphino)-9,9-dimethyl Xantphos
Xantphos / 9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene
Xantphos, 4,5-Bis(diphenylphosphino)-9,9-diMethylxanthene
4,5-Bis(diphenyL
phosphino)-9,9-dimethyL
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene >
1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-phosphine
Phosphine, 1,1'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-
4,5-Bis(diphenylphosphino)-9,9-dimethylxantane (Xantphos)
XantPhos (4,5-Bis(Diphenylphosphino)-9,9-Dimethylxanthine) extrapure, 98%
XANT PHOS
(9,9-DIMETHYL-9H-XANTHENE-4,5-DIYL)BIS[DIPHENYL PHOSPHINE]
4,5-BIS(DIPHENYLPHOSPHINO)-9,9-DIMETHYLX
Bis(diphenylphosphino)-9,9-diMethylxanthene
(5-diphenylphosphanyl-9,9-dimethylxanthen-4-yl)-diphenylphosphane
4,5-Bis(diphenylphosphino)-9,9-dimethyl
9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE
Dimethylbisdiphenylphosphinoxanthene
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, XANTPHOS
4,5-Bis(diphenylphosphino)-9,9
[5-(diphenylphosphanyl)-9,9-diMethyl-9H-xanthen-4-yl]diphenylphosphane