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Esfenvalerate

CAS No.
66230-04-4
Chemical Name:
Esfenvalerate
Synonyms
ASANA;s1844;S 1844;s-1844;aalpha;Halmark;oms3023;asanaxl;HALLMARK;FORALPHA
CBNumber:
CB0231185
Molecular Formula:
C25H22ClNO3
Molecular Weight:
419.91
MDL Number:
MFCD00203302
MOL File:
66230-04-4.mol
MSDS File:
SDS
Last updated:2023-09-20 16:43:00

Esfenvalerate Properties

Melting point 59°C
Boiling point 151-167°C
alpha D25 -15.0° (c = 2.0 in CH3OH)
Density d2323 1.163
vapor pressure 2×10-7 Pa (25 °C)
refractive index 1.6500 (estimate)
storage temp. 0-6°C
solubility DMSO : 100 mg/mL (238.15 mM; Need ultrasonic)
Water Solubility 0.002 mg l-1 (25 °C)
BRN 4275674
LogP 6.220
CAS DataBase Reference 66230-04-4(CAS DataBase Reference)
FDA UNII 7F07OXM0PP
NIST Chemistry Reference Benzeneacetic acid, 4-chloro-«alpha»-(1-methylethyl)-, cyano (3-phenoxyphenyl)methyl ester,(s-(r*,r*))-(66230-04-4)
Pesticides Freedom of Information Act (FOIA) Esfenvalerate
EPA Substance Registry System Esfenvalerate (66230-04-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS09
Signal word  Danger
Hazard statements  H301+H331-H317-H410
Precautionary statements  P273-P280-P301+P310+P330-P302+P352-P304+P340+P311
Hazard Codes  T;N,N,T
Risk Statements  23/25-43-50/53
Safety Statements  24-36/37/39-45-60-61
RIDADR  UN 2811
WGK Germany  3
RTECS  CY1576367
HazardClass  6.1(b)
PackingGroup  III
HS Code  29269090
Toxicity LC50 (96-hour) for fathead minnows 0.69 mg/L (Worthing and Hance, 1991); acute oral LD50 for rats 75 mg/kg (Hartley and Kidd, 1987).

Esfenvalerate price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 46277 Esfenvalerate PESTANAL?, analytical standard 66230-04-4 100mg $86.8 2024-03-01 Buy
TRC E658900 Esfenvalerate 66230-04-4 10g $580 2021-12-16 Buy
AHH API-1321 Esfenvalerate 98% 66230-04-4 5g $560 2021-12-16 Buy
Product number Packaging Price Buy
46277 100mg $86.8 Buy
E658900 10g $580 Buy
API-1321 5g $560 Buy

Esfenvalerate Chemical Properties,Uses,Production

Description

Esfenvalerate is a synthetic pyrethoid insecticide – a class of pesticides originating from the chrysanthemum flower, which disrupt sodium channels. It has replaced fenvalerate, a less effective and more chronically toxic enantiomer. It can be used for general pest control, including spiders, fleas, scorpions, moths, beetles, etc. It is frequently applied on vegetable, nut, and non-crop products, often in combination with other active ingredients such as carbamate compounds and organophosphates. Product labels containing esfenvalerate include Sumi-Alpha, Hounddog, Sven, Asana, and Esfenvalerate 5EC, manufactured variously by BASF, Greencrop, and Standon.

Sources

http://pmep.cce.cornell.edu/profiles/extoxnet/dienochlor-glyphosate/esfenvalerate-ext.html
https://en.wikipedia.org/wiki/Esfenvalerate
https://www.domyown.com/esfenvalerate-c-114_374.html
https://en.wikipedia.org/wiki/Pyrethroid
https://www.sciencedirect.com/topics/agricultural-and-biological-sciences/esfenvalerate
https://sitem.herts.ac.uk/aeru/ppdb/en/Reports/269.htm

Chemical Properties

Viscous yellow or amber liquid or white or amber crystalline solid.

Uses

Esfenvalerate is the most potent insecticidal isomer of Fenvalerate (F279450), a pyrethroid insecticide used to control insects from food crops, animal feed and cotton products.

Uses

Insecticide.

Uses

Esfenvalerate possesses a broad range of insecticidal activity and it is used on cotton, fruit, vegetables and other crops.

Definition

ChEBI: Esfenvalerate is a fenvalerate. It has a role as a pyrethroid ester insecticide and an agrochemical.

Agricultural Uses

Insecticide: A U.S. EPA restricted Use Pesticide (RUP). Esfenvalerate is a synthetic insecticide used to control a wide range of pests such as moths, flies, beetles, and other insects. It is used on vegetable crops (soya beans, sugar cane), tree fruit, cotton, maize, sorghum and nut crops, and non-crop lands. It also is used on a wide variety of household pests. It is usually mixed with a wide variety of other types of pesticides such as carbamate compounds or organophosphates and has the naturally occurring compound fenvalerate for use in the U.S. Esfenvalerate is almost identical to fenvalerate. Much of the data for fenvalerate is applicable to the pesticide esfenvalerate because the two compounds contain the same components. The only differences in the two products are the relative proportions of the four separate constituents (isomers). Esfenvalerate has become the preferred compound because it requires lower application rates than fenvalerate, is less chronically toxic, and is a more powerful insecticide.

Trade name

AMERICARE®; ASANA®; ASANA-XL®; ASANA® DPX-YB656-84; ENFORCER®; EVERCIDE®; HALMARK®; OMS-3023®; S-1844®; S-5602 ALPHA®; SUMI-ALFA®; SUMI-ALPHA®; SS-PYDRIN®; SUMICIDIN A-ALPHA®

Potential Exposure

Esfenvalerate is a synthetic pyrethroid Insecticide used to control wide range of pests such as moths, flies, beetles, and other insects. It is used on vegetable crops (soya beans, sugar cane), tree fruit, cotton, maize, sorghum and nut crops, and noncrop lands. It also isused on a wide variety of household pests. It is usually mixed with a wide variety of other types of pesticides such as carbamate compounds or organophosphates and has the naturally occurring compound fenvalerate for use in the United States Esfenvalerate is almost identical to fenvalerate. Much of the data for fenvalerate is applicable to the pesticide esfenvalerate (E:0207) because the two compounds contain the same components. The only differences in the two products are the relative proportions of the four separate constituents (isomers). Esfenvalerate has become the preferred compound because it requires lower applications rates than fenvalerate, is less chronically toxic, and is a more powerful insecticide. A United States Environmental Protection Agency Restricted Use Pesticide (RUP). Incompatibilities: Oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); strong acids. Moisture may cause hydrolysis/ decomposition.

Environmental Fate

Chemical/Physical. May hydrolyze in aqueous solutions forming acetic acid and other compounds.

Metabolic pathway

Esfenvalerate is the 2SαS-isomer of fenvalerate (which is racemic). It possesses some small differences in physical properties when compared with the racemate. Overall, the degradation and metabolism of the two compounds are very similar. Reference should be made to the fenvalerate entry. An important exception, which is discussed fully in the latter entry, is that esfenvalerate does not form the cholesterol ester conjugate that has been shown to be responsible for granulomatous changes in several tissues on repeated dosing of fenvalerate.

Shipping

UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN3352 Pyrethroid pesticide, liquid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Degradation

Esfenvalerate is hydrolysed in aqueous alkali to its constituent acid and alcohol; the latter decomposes to 3-phenoxybenzaldehyde and cyanide ion as described for fenvalerate and cypermethrin. Photodecomposition occurs as for fenvalerate.

Incompatibilities

Oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); strong acids. Moisture may cause hydrolysis/ decomposition.

Waste Disposal

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers

39515-51-0
66230-04-4
Synthesis of Esfenvalerate from 3-Phenoxybenzaldehyde
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View Lastest Price from Esfenvalerate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Esfenvalerate pictures 2023-07-29 Esfenvalerate
66230-04-4
US $0.00 / KG 1KG 90%、5%EC 200MT Weifang Yuanye Biotechnology Co., Ltd
Esfenvalerate pictures 2023-01-31 Esfenvalerate
66230-04-4
US $100.00 / KG 1KG 99% 5000kg/week Hebei Mojin Biotechnology Co., Ltd
Esfenvalerate pictures 2021-08-12 Esfenvalerate
66230-04-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
  • Esfenvalerate pictures
  • Esfenvalerate
    66230-04-4
  • US $0.00 / KG
  • 90%、5%EC
  • Weifang Yuanye Biotechnology Co., Ltd
  • Esfenvalerate pictures
  • Esfenvalerate
    66230-04-4
  • US $100.00 / KG
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd
  • Esfenvalerate pictures
  • Esfenvalerate
    66230-04-4
  • US $15.00-10.00 / KG
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd

Esfenvalerate Spectrum

ASANA ASANA (TM) HALLMARK FERTIALPHA FORALPHA ESFENVALERATE Cyano-3-phenoxybenzyl (S)-2-(4-chlorophenyl)-3-methylbutyrate AMICIDIN SUPER esfenvalerare SUMI-ALFA SUMI-ALPHA (s-(r*,r*))-hyleste (S)-.alpha.-Cyano-3-phenoxybenzyl-(S)-2-(4-chlorophenyl)-3-methylbutyricester Fenvalerate alpha Fenvalerate.alpha. fenvalerateaalpha fenvaleratealpha Halmark OMS 3023 oms3023 S 1844 S 5602 A alpha s1844 s-1844 ESFENVALERATE PESTANAL, 100 MG ASANA, 100MG, NEAT esfenvalarete Benzeneacetic acid, 4-chloro-.alpha.-(1-methylethyl)-, (S)-cyano(3-phenoxyphenyl)methyl ester, (.alpha.S)- esfenvalerate (bsi,iso) Esfenvalerate,100ug/ml (S)-α-cyano-3-phenoxybenzyl-(S)-2-(4-chlorophenyl)-3-methylbutyrate esfenvalerate esfenvalerate - fenvalerate alpha Fenvalerate-U (S)-A-CYANO-3-PHENOXY BENZYL-(S)-2-(4-CHLOROPHENYL)-3-METHYL-BUTYRATE Asana (TM) 100mg [66230-04-4] S-fenvalerate (S)-α-cyano-3-phenoxybenzyl(S)-2-(4-chlorophenyl)-3-methylbutyrate (S)-(S)-cyano(3-phenoxyphenyl)Methyl 2-(4-chlorophenyl)-3-Methylbutanoate Benzeneaceticacid, 4-chloro-a-(1-Methylethyl)-, (S)-cyano(3-phenoxyphenyl)Methylester, (aS)- (S)-alpha-Cyano-3-phenoxybenzyl(S)-2-(4-chlorophenyl)-3-methylbutyrate (S,S)-Isomer [s-(r*,r*]-cyano(3-phenoxyphenyl)methyl4-chloro-2-(1-methylethyl)benzeneacetat 4-chloro-alpha-(1-methylethyl)-benzeneaceticacicyano(3-phenoxyphenyl)met aalpha Asana xl asanaxl Benzeneaceticacid,4-chloro-.alpha.-(1-methylethyl)-,cyano(3-phenoxyphenyl)-methylester,(S-(R*,R*)) Cyano(3-phenoxyphenyl)methyl 2-(4-chlorophenyl)-3-methylbutanoate Fenvalerate A alpha s5602aalpha s-5602alpha s-5620aalpha Sumicidin A alpha sumicidinaalpha Esfenvalerate in n-Hexane Esfenvalerate Solution in Hexane Esfenvalerate Solution, 1000ppm A-Fenvalerate