ChemicalBook >> CAS DataBase List >>Bromocyclohexane
Bromocyclohexane
- CAS No.
- 108-85-0
- Chemical Name:
- Bromocyclohexane
- Synonyms
- CYCLOHEXYL BROMIDE;Cyclohexylbromid;Bromocylohexane;BROMOCYCLOHEXANE;bromo-cyclohexan;BroMocyclohexance;Cyclohexane,bromo-;1-Bromocyclohexane;Cyelohexyl bromide;Bromocyclohexane>
- CBNumber:
- CB0234782
- Molecular Formula:
- C6H11Br
- Molecular Weight:
- 163.06
- MDL Number:
- MFCD00003819
- MOL File:
- 108-85-0.mol
- MSDS File:
- SDS
Last updated:2024-04-25 13:42:50
| Melting point | -57°C |
|---|---|
| Boiling point | 166-167 °C (lit.) |
| Density | 1.324 g/mL at 25 °C (lit.) |
| vapor density | 5.62 (vs air) |
| refractive index |
n |
| Flash point | 145 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride. |
| form | Liquid |
| color | Clear colorless to light yellow |
| Specific Gravity | approximate 1.33 (20℃) |
| Odor | Unpleasant Odor |
| Water Solubility | insoluble |
| Sensitive | Air & Light Sensitive |
| Merck | 14,2730 |
| BRN | 1098373 |
| Dielectric constant | 7.9（25℃） |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. |
| InChIKey | AQNQQHJNRPDOQV-UHFFFAOYSA-N |
| CAS DataBase Reference | 108-85-0(CAS DataBase Reference) |
| FDA UNII | YA0UMS4RNY |
| NIST Chemistry Reference | Cyclohexane, bromo-(108-85-0) |
| EPA Substance Registry System | Cyclohexane, bromo- (108-85-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335-H227 | |||||||||
| Precautionary statements | P210-P280-P403+P235-P501-P210e-P261-P280a-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 36/37/38-20-18-52 | |||||||||
| Safety Statements | 23-24/25-37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | GU7171700 | |||||||||
| F | 8 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29035990 | |||||||||
| NFPA 704 |
|
Bromocyclohexane price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 135194 | Bromocyclohexane 98% | 108-85-0 | 5g | $23 | 2024-03-01 | Buy |
| Sigma-Aldrich | 135194 | Bromocyclohexane 98% | 108-85-0 | 1kg | $178 | 2024-03-01 | Buy |
| TCI Chemical | B0581 | Bromocyclohexane >98.0%(GC) | 108-85-0 | 25g | $18 | 2024-03-01 | Buy |
| TCI Chemical | B0581 | Bromocyclohexane >98.0%(GC) | 108-85-0 | 100g | $30 | 2024-03-01 | Buy |
| Alfa Aesar | A11593 | Bromocyclohexane, 98% | 108-85-0 | 100g | $27.65 | 2024-03-01 | Buy |
Bromocyclohexane Chemical Properties,Uses,Production
Chemical Properties
colourless liquid
Uses
Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.
Preparation
Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.
Synthesis Reference(s)
Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020
General Description
Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.
Purification Methods
Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]
Bromocyclohexane Preparation Products And Raw materials
Raw materials
Preparation Products
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
1-Cyclohexylpiperazine
Bis(tricyclohexylphosphine)palladium(II) Dichloride
1,1'-Bis(di-tert-butylphosphino)ferrocene
2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl
2-(Dicyclohexylphosphino)biphenyl
Tricyclohexyl phosphine
IODOCYCLOHEXANE
Cyclohexylamine
1,1-Dibromocyclohexane
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Global( 379)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
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| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7786 | 58 |
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| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
View Lastest Price from Bromocyclohexane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-25 | Bromocyclohexane
108-85-0
|
US $10.00 / kg | 1kg | 99.8% | 10000ton | Ouhuang Engineering Materials (Hubei) Co., Ltd | |
 |
2024-03-12 | Bromocyclohexane
108-85-0
|
US $50.00 / kg | 1kg | 99.9（%） | 30 tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2023-12-26 | Bromocyclohexane
108-85-0
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
-
- Bromocyclohexane
108-85-0
- US $10.00 / kg
- 99.8%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
-
- Bromocyclohexane
108-85-0
- US $50.00 / kg
- 99.9（%）
- Hebei Yanxi Chemical Co., Ltd.
-
- Bromocyclohexane
108-85-0
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
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108-85-0
-CH2CH24CHBr
6H11Br
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