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4-Chlorostyrene

4-Chlorostyrene Structure
4-Chlorostyrene structure
CAS No.
1073-67-2
Chemical Name:
4-Chlorostyrene
Synonyms
1-Chloro-4-vinylbenzene;P-CHLOROSTYRENE;para-chlorostyrene;4-Chlorostyrene, stabilized, 99%;ARBA-020;orostyrene;p-Chlorstyrol;CHLOROSTYRENE-4;p-chloro-styren;4-CHLOROSTYRENE
CBNumber:
CB0240404
Molecular Formula:
C8H7Cl
Molecular Weight:
138.59
MDL Number:
MFCD00000632
MOL File:
1073-67-2.mol
MSDS File:
SDS
Last updated:2023-12-24 21:24:35
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4-Chlorostyrene Properties

Melting point -16 °C
Boiling point 192 °C(lit.)
Density 1.155 g/mL at 25 °C(lit.)
vapor pressure 0.68 mm Hg ( 20 °C)
refractive index n20/D 1.565(lit.)
Flash point 140 °F
storage temp. 2-8°C
form Liquid
Specific Gravity 1.155
color Clear colorless to slightly yellow
Water Solubility Immiscible with water.
BRN 1098859
CAS DataBase Reference 1073-67-2(CAS DataBase Reference)
FDA UNII T0J05U220F
NIST Chemistry Reference Benzene, 1-chloro-4-ethenyl-(1073-67-2)
EPA Substance Registry System Benzene, 1-chloro-4-ethenyl- (1073-67-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H315-H411
Precautionary statements  P264-P273-P280-P302+P352-P332+P313-P362+P364
Hazard Codes  Xi,F
Risk Statements  36/37/38
Safety Statements  23-24/25-37/39-26-36
RIDADR  1993
WGK Germany  3
RTECS  CZ0533000
TSCA  T
HazardClass  3
PackingGroup  III
HS Code  29036990
Toxicity LD50 orally in Rabbit: 5200 mg/kg
NFPA 704
2
2 0

4-Chlorostyrene price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich C71203 4-Chlorostyrene 97%, contains 500ppm 4- 1073-67-2 10g $110 2024-03-01 Buy
Sigma-Aldrich C71203 4-Chlorostyrene 97%, contains 500ppm 4- 1073-67-2 50g $411 2024-03-01 Buy
Sigma-Aldrich 8.02458 4-Chlorostyrene (stabilised with 4-tert-butylpyrocatechol) for synthesis 1073-67-2 10ml $106 2024-03-01 Buy
TCI Chemical C0290 4-Chlorostyrene (stabilized with TBC) >98.0%(GC) 1073-67-2 10mL $26 2024-03-01 Buy
TCI Chemical C0290 4-Chlorostyrene (stabilized with TBC) >98.0%(GC) 1073-67-2 25mL $50 2024-03-01 Buy
Product number Packaging Price Buy
C71203 10g $110 Buy
C71203 50g $411 Buy
8.02458 10ml $106 Buy
C0290 10mL $26 Buy
C0290 25mL $50 Buy

4-Chlorostyrene Chemical Properties,Uses,Production

Chemical Properties

clear colourless to slightly yellow liquid. The side chain of p-chlorostyrene is a C=C double bond, so its chemical properties are more active. The compound can polymerize slowly at room temperature, and a polymerization inhibitor (stabilizer) can be added for storage.

Uses

4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.

Uses

4-Chlorostyrene was used in the following studies:
Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.

Preparation

Synthesis of 4-chlorostyrene: carry out catalytic dehydration reaction by 4-chlorophenethylalcohol at 280°C, the used catalyst is a modified aluminum silicate catalyst, and the yield is 80%.

Synthesis Reference(s)

p-Chlorostyrene is commercially produced as a monomer from p-chloroethylbenzene by an oxidation technique. It is also produced as a mixture with o-chlorostyrene.
Journal of the American Chemical Society, 69, p. 852, 1947 DOI: 10.1021/ja01196a033
Tetrahedron Letters, 31, p. 5061, 1990 DOI: 10.1016/S0040-4039(00)97806-7

General Description

4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).

4-Chlorostyrene synthesis

1779-49-3
104-88-1
1073-67-2
Synthesis of 4-Chlorostyrene from Methyltriphenylphosphonium bromide and 4-Chlorobenzaldehyde

4-Chlorostyrene Preparation Products And Raw materials

Raw materials

3-Buten-2-one, 4-(4-chlorophenyl)-, (3E)- 2-(4-CHLOROPHENYL)OXIRANE 1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE 4-Chlorocinnamic acid 4-Chlorobenzyl bromide
4-Chlorobenzyl chloride Benzeneethanesulfonylazide, 4-chloro- 6-Chloroindole 5H-Cyclopenta[b]pyridine, 4-chloro-6,7-dihydro- 6-CHLORO-2,3-DIHYDRO-1H-INDOLE

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Preparation Products

3-[2-chloro-2-(4-chlorophenyl)ethenyl]-2，2-dimethyl cyclopropane carboxylic acid 4-Chlorophenethylamine DIPHENYL(P-VINYLPHENYL)PHOSPHINE P-TRIMETHYLSILYL STYRENE 3-(4-Chlorophenyl)propan-1-ol

4-Chlorostyrene Suppliers

Global( 341)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Yanxi Chemical Co., Ltd. 		+8617531190177 peter@yan-xi.com China 5993 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Anqing Chico Pharmaceutical Co., Ltd. 		15380796838 chloewu@chicopharm.cn CHINA 341 58
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Zhejiang ZETian Fine Chemicals Co. LTD 		18957127338 stella@zetchem.com China 2141 58
Hebei Guanlang Biotechnology Co., Ltd. 		+86-19930503282 alice@crovellbio.com China 8823 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Supplier Advantage
Hebei Yanxi Chemical Co., Ltd. 		58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Anqing Chico Pharmaceutical Co., Ltd. 		58
career henan chemical co 		58
Zhejiang ZETian Fine Chemicals Co. LTD 		58
Hebei Guanlang Biotechnology Co., Ltd. 		58
Chongqing Chemdad Co., Ltd 		58

View Lastest Price from 4-Chlorostyrene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Chlorostyrene pictures 2023-12-24 4-Chlorostyrene
1073-67-2
 US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
4-Chlorostyrene pictures 2023-09-28 4-Chlorostyrene
1073-67-2
 US $50.00-10.00 / kg 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
4-Chlorostyrene pictures 2023-09-06 4-Chlorostyrene
1073-67-2
 US $0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
  • 4-Chlorostyrene pictures
  • 4-Chlorostyrene
    1073-67-2
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
  • 4-Chlorostyrene pictures
  • 4-Chlorostyrene
    1073-67-2
  • US $50.00-10.00 / kg
  • 0.99
  • Hebei Yanxi Chemical Co., Ltd.
  • 4-Chlorostyrene pictures
  • 4-Chlorostyrene
    1073-67-2
  • US $0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.

4-Chlorostyrene Spectrum

4-Chlorostyrene(1073-67-2)MS4-Chlorostyrene(1073-67-2)1HNMR4-Chlorostyrene(1073-67-2)13CNMR4-Chlorostyrene(1073-67-2)IR14-Chlorostyrene(1073-67-2)Raman

1073-67-2(4-Chlorostyrene)Related Search:

OCTACHLOROSTYRENE Styrene Vinylbenzyl chloride 4-Chlorobenzyl cyanide 4-CHLOROPHENETOLE
4-Chlorophenoxyacetic acid 4-Chlorophenylacetic acid 4'-Chloroacetophenone 4-CHLOROBENZOYLACETONITRILE 3,4-DICHLOROSTYRENE
meta-chlorostyren 3,4-Dichlorocinnamic acid 4,4'-Dichlorochalcone TRANS-2,4-DICHLOROCINNAMIC ACID POLY(3-CHLOROSTYRENE),3-CHLOROSTYRENE POLYMER
(R)-4-CHLOROSTYRENE OXIDE 4-CHLOROSTYRENE RESIN,POLY(4-CHLOROSTYRENE), AVERAGE MW CA. 75 ,000 (GPC),POLY(4-CHLOROSTYRENE) o-Chlorobenzylidene malononitrile

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CHLOROSTYRENE-4 4-CHLOROSTYRENE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL 4-CHLOROSTYRENE Stabilised with 0.1% 4-tert-butylcatechol p-chloro-styren Styrene, p-chloro- styrene,p-chloro- 4-CHLOROSTYRENE 4-VINYLCHLOROBENZENE (4-Chlorophenyl)ethene 4-Chloro-1-ethenylbenzen p-Chlorovinylbenzene p-Vinylphenyl chloride 4-Chlorostyrene, 99%, stabilized 1-Ethenyl-4-chlorobenzene 4-Chloro-1-vinylbenzene 4-Vinylphenyl chloride 4-CHLOROSTYRENE, 99%, STAB. 4-Chlorostyrene (stabilized with TBC) 1-Ethenyl-4-chlorobenzol 4-Chlorostyrene, 99%, stab. with 0.1% 4-tert-butylcatechol 1-chloro-4-ethenyl-benzen 1-chloro-4-ethenylbenzene 4-chloro-styren Benzene, 4-chloro-1-ethenyl- benzene,1-chloro-4-ethenyl- Parachlorostyrene 4-Chlorostyrene, Stab. 1-Chloro-4-vinylbenzene, 1-Chloro-4-ethenylbenzene 4-Chlorostyrene, stabilized, 99% 10GR 4-CHLOROSTYRENE (STABILISED WITH 4-TERT- 4-Chlorostyrene, 98%, stabilized with 0.1% TBC 4-Chlorostyrene, stabilized with 0.1% TBC 4-chloro-1-ethenylbenzene Chlorobenzene ethylene P-chlorobenzene ethylene 4-Chlorostyrene, 98%, stabilized with TBC p-Chlorostyrene, 99% (Inhibited) ARBA-020 p-Chlorstyrol 4-Chlorostyrene - stabilised with 4-tert-butylcatechol orostyrene 4-Chlorostyrene (stabilized with TBC)> 4-Chlorostyrene ISO 9001：2015 REACH 4-chloropacking 4-Chlorostyrene (stabilizer 0.1% tert.-butylcatechol) 4-Chlorostyrene, stabilized, 99% P-CHLOROSTYRENE 1-Chloro-4-vinylbenzene para-chlorostyrene 1-Chloro-4-vinylbenzene[N/A 1073-67-2 1063-67-2 H2CCHC6H4Cl ClC6H4CHCH2 HALOGEN Alkenyl Building Blocks Halogenated Hydrocarbons