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4-Bromophenoxybenzene

CAS No.
101-55-3
Chemical Name:
4-Bromophenoxybenzene
Synonyms
1-Bromo-4-phenoxybenzene;4-BROMODIPHENYL ETHER;pbde 3;P-BROMDIPHENYL ETHER;BDE No 3 solution;4-bromo-diphenylethe;p-phenoxybromobenzene;4-BROMODIPHENYL OXIDE;4-bromophenoxybenzene;P-BROMODIPHENYL ETHER
CBNumber:
CB0252643
Molecular Formula:
C12H9BrO
Molecular Weight:
249.1
MDL Number:
MFCD00000094
MOL File:
101-55-3.mol
MSDS File:
SDS
Last updated:2024-03-14 15:18:25

4-Bromophenoxybenzene Properties

Melting point 18 °C (lit.)
Boiling point 305 °C (lit.)
Density 1.423 g/mL at 25 °C (lit.)
vapor pressure 1.94 x 10-3 mmHg at 25 °C (subcooled liquid, Tittlemier et al., 2002)
refractive index n20/D 1.607(lit.)
Flash point >230 °F
storage temp. 2-8°C
solubility Soluble in ether (Weast, 1986) and many other solvents including 1,4-dioxane, benzene, and toluene.
form Liquid
color Colorless to Almost colorless
BRN 1308972
Henry's Law Constant 2.27 at 25 °C (integrated gas-stripping method, GC, Lau et al., 2006)
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey JDUYPUMQALQRCN-UHFFFAOYSA-N
CAS DataBase Reference 101-55-3(CAS DataBase Reference)
FDA UNII N19SE3QCFN
NIST Chemistry Reference Benzene, 1-bromo-4-phenoxy-(101-55-3)
EPA Substance Registry System p-Bromophenyl phenyl ether (101-55-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H302-H317-H318-H410
Precautionary statements  P273-P280-P301+P312+P330-P302+P352-P305+P351+P338+P310
Hazard Codes  N,Xn,F
Risk Statements  50/53-67-65-38-11-43-41-22
Safety Statements  60-61-62-36/37/39-26-33-29-16-9
RIDADR  UN 3082 9/PG 3
WGK Germany  3
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29093090
Toxicity LC50 (24-h) for Daphnia magna 0.46 mg/L (LeBlanc, 1980).
NFPA 704
1
2 0

4-Bromophenoxybenzene price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B65209 4-Bromodiphenyl ether 99% 101-55-3 25g $137 2024-03-01 Buy
TCI Chemical B0637 4-Bromodiphenyl Ether >98.0%(GC) 101-55-3 25g $46 2024-03-01 Buy
TCI Chemical B0637 4-Bromodiphenyl Ether >98.0%(GC) 101-55-3 500g $500 2024-03-01 Buy
Alfa Aesar L01473 4-Bromodiphenyl ether, 99% 101-55-3 25g $48.4 2023-06-20 Buy
Alfa Aesar L01473 4-Bromodiphenyl ether, 99% 101-55-3 100g $145 2023-06-20 Buy
Product number Packaging Price Buy
B65209 25g $137 Buy
B0637 25g $46 Buy
B0637 500g $500 Buy
L01473 25g $48.4 Buy
L01473 100g $145 Buy

4-Bromophenoxybenzene Chemical Properties,Uses,Production

Description

4-Bromophenyl phenyl ether is a brominateddiphenylether and a liquid at common ambient temperatures.Molecular weight=249.10; Boiling point=310.14 ℃;Specific gravity (H2O:1)=1.449 (1.4208 at 20 ℃);Freezing/Melting point=18.72℃; Vapor pressure 50.0015 mmHg at 20℃; Flash point=.110℃. HazardIdentification (based on NFPA-704 M Rating System):Health 1, Flammability 1, Reactivity 0. Poor solubility inwater; solubility=4.8 mg/L at 25℃.

Chemical Properties

light yellow liquid

Definition

ChEBI: An aromatic ether that is diphenyl ether substituted at position 4 by a bromo group.

General Description

Liquid. Freezing point 18°C. Density 1.423 g / cm3. Insoluble or slightly soluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Bromophenoxybenzene oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164].

Fire Hazard

Combustible.

Potential Exposure

Very little information on 4-bromophenyl phenyl ether exists. It is prepared by brominatingdiphenyl ether with Br2 at 95-100℃ in carbontetrachloride.[US EPA, 1986] 4-Bromophenyl phenyl ether hasbeen identified in raw water, in drinking water, and in riverwater.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Environmental Fate

Biological. Using settled domestic wastewater inoculum, 4-bromophenyl phenyl ether (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981).
Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 303, 112, 41, and 15 mg/g, respectively (Dobbs and Cohen, 1980).

storage

Color Code—Green: General storage may be used.Store away from heat, flames, or oxidizing materials; etherstend to peroxidize when exposed to air formingunstable peroxides that may detonate with extreme violence.

Shipping

The name of this material is not on the DOT listof materials for label and packaging standards. However,based on regulations, it may be classified as anEnvironmentally hazardous substances, liquid, n.o.s. It fallsin Hazard Class 9 and Packing Group III.[20, 21]

591-50-4
106-41-2
101-55-3
Synthesis of 4-Bromophenoxybenzene from Iodobenzene and 4-Bromophenol
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View Lastest Price from 4-Bromophenoxybenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Bromophenoxybenzene pictures 2024-03-29 4-Bromophenoxybenzene
101-55-3
US $0.00 / KG 10g 99.5% 10TON S Zhejiang Free Trade Zone Violet Trade Co., Ltd.
4-Bromophenoxybenzene pictures 2024-01-23 4-Bromophenoxybenzene
101-55-3
US $0.00 / KG 1KG 98% 150KG /month Shanghai Daken Advanced Materials Co.,Ltd
4-Bromophenoxybenzene pictures 2023-11-13 4-Bromophenoxybenzene
101-55-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
4-BROMOPHENYL PHENYL ETHER 4-bromophenoxybenzene 4-BROMODIPHENYL OXIDE p-phenoxybromobenzene p-Phenoxyphenyl bromide P-BROMODIPHENYL ETHER P-BROMOPHENYL PHENYL ETHER 1-BROMO-4-PHENOXY-BENZENE (4-BROMOPHENYL PHENYL ETHER) 4-bromo-1-phenoxy-benzene p-Bromodiphenyl ether? 4-Bromophenoxybenzene P-BROMDIPHENYL ETHER pbde 3 4-PHENOXYBROMOBENZENE MONOBROMODIPHENYLETHER PARA-BROMODIPHENYLETHER Bromophenyl phenyl ether, 4- 4-Bromodiphenyl ether solution, PBDE 3 BDE No 3 solution 4-Bromodiphenyl ether,50 μL/mL in Isooctane 4-Bromophenyl phenyl ether 1g [101-55-3] 4-Bromodiphenyl ether,4-Bromophenyl phenyl ether 4-Bromodiphenyl ester 1-bromo-4-phenoxy-benzen 4-bromo-diphenylethe benzene,1-bromo-4-phenoxy- Diphenyl ether, 4-bromo- diphenyl,4-bromo-ethe Ether, 4-bromophenyl phenyl Ether, p-bromophenyl phenyl ether,4-bromophenylphenyl ether,p-bromophenylphenyl p-(Phenoxy)bromobenzene p-Bromophenoxybenzene p-Bromphenyl phenyl ether Phenyl ether, 4-bromo- phenyl(4-bromophenyl)ether 11 -Bromo-4-phenoxybenzene 4-Bromophenyl phenyl ether @5.0 mg/mL in MeOH 4-Bromodiphenyl Ether > 4-Bromophenyl Phenyl Ether @100 μg/mL in MeOH 4-Bromodiphenylether Solution, 100μg/mL PBDE 3(4-Bromodiphenyl Ether) 4-BROMODIPHENYL ETHER 1-Bromo-4-phenoxybenzene 18-ISOPROPYLCYCLOHEXANONE 101-55-3 C12H6BrO BrC6H4OC6H5 Oxygen Compounds Organic Building Blocks Ethers Building Blocks Alcohol& Phenol& Ethers API intermediates Biphenyl & Diphenyl ether