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Methyl 2-bromo-2-methylpropionate

Methyl 2-bromo-2-methylpropionate structure

CAS No.: 23426-63-3

Chemical Name:: Methyl 2-bromo-2-methylpropionate

Synonyms: methyl 2-bromo-2-methylpropanoate;Methyl α-broMo-;methyl a-bromobutyrate;METHYL 2-BROMOISOBUTYRATE;METHYL A-BROMOISOBUTYRATE;Methyl α-bromoisobutyrate;Methyl Alpha-Bromobutyrate;METHYL ALPHA-BROMOISOBUTYRATE;METHYL-2-BROMO-ISOBUTYRIC ACID;α-BroMoisobutyrate Methyl ester

CBNumber:: CB0263289

Molecular Formula:: C5H9BrO2

Molecular Weight:: 181.03

MDL Number:: MFCD00017854

MOL File:: 23426-63-3.mol

MSDS File:: SDS

Last updated:2024-03-28 13:39:29

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Methyl 2-bromo-2-methylpropionate Properties

Boiling point	52 °C(Press: 19 Torr)
Density	1.399 g/mL at 20 °C(lit.)
refractive index	n20/D 1.451
Flash point	49 °C
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Oil
color	Colourless
BRN	1209484
InChIKey	PQUSVJVVRXWKDG-UHFFFAOYSA-N
CAS DataBase Reference	23426-63-3(CAS DataBase Reference)
FDA UNII	8SA4292KBM

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02
Signal word	Warning
Hazard statements	H226
Precautionary statements	P210-P233-P240-P241-P242-P243
Hazard Codes	Xi
Risk Statements	10-36/37/38
Safety Statements	26-36
RIDADR	UN 2929 6.1/PG 2
WGK Germany	3
F	19
HS Code	29159000

Methyl 2-bromo-2-methylpropionate price More Price(16)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	17457	Methyl α-bromoisobutyrate ≥99.0% (GC)	23426-63-3	100ml	$54.3	2024-03-01	Buy
TRC	M296495	Methyl2-Bromo-2-methylpropanoate	23426-63-3	5g	$60	2021-12-16	Buy
SynQuest Laboratories	2123-9-06	Methyl 2-bromo-2-methylpropionate 99%	23426-63-3	100g	$70	2021-12-16	Buy
AK Scientific	F509	Methyl2-bromoisobutyrate	23426-63-3	100g	$79	2021-12-16	Buy
Oakwood	235671	Methyl 2-bromo-2-methylpropanoate	23426-63-3	1g	$9	2021-12-16	Buy

Product number	Packaging	Price	Buy
17457	100ml	$54.3	Buy
M296495	5g	$60	Buy
2123-9-06	100g	$70	Buy
F509	100g	$79	Buy
235671	1g	$9	Buy

Methyl 2-bromo-2-methylpropionate Chemical Properties,Uses,Production

Synthesis

Bromoisobutyric acid (4.17 g, 25 mmol) was dissolved in a solution of concentrated sulfuric acid (0.75 mL) and methanol (50 mL) and stirred under reflux for 2 h. The solution was then cooled to room temperature and concentrated under vacuum. The residue was dissolved in diethyl ether and washed with 10% aqueous sodium bicarbonate, washed with brine, dried under magnesium sulfate, and concentrated again under vacuum. A colorless oil was obtained (4.2 g, 23 mmol, 93% yield) 1H NMR (300 MHz, CDCl3) δ(ppm): 3.78 (s, 3H), 1.93 (s, 6H)
Methyl 2-bromo-2-methylpropionate

Uses

Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with a methyl end group

Application

Methyl 2-bromo-2-methylpropionate can be used as a free radical initiator to participate in polymerization reactions.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 3684, 1978 DOI: 10.1021/jo00413a009

Methyl 2-bromo-2-methylpropionate synthesis

Synthesis of Methyl 2-bromo-2-methylpropionate from Methanol and 2-Bromo-2-methylpropionic acid

Methyl 2-bromo-2-methylpropionate Preparation Products And Raw materials

Raw materials

1-Propene, 1,1-dimethoxy-2-methyl- Methyl 4-bromo-2,2-dimethylbutanoate 2-Bromoisobutyryl Bromide 2-Bromoisobutyrylchloride Carbon tetrachloride

2-Bromo-2-methylpropionic acid Methanol Dimethyl 2,2'-azobis(2-methylpropionate) Isobutyric acid 1,2-Dibromoethane

Methyl isobutyrate

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Preparation Products

methyl 2-methyl-2-(3-methyl-4-nitro-1H-pyrazol-1-yl)propanoate 6-bromo-2,2-dimethyl-4H-benzo[1,4]oxazin-3-one

Methyl 2-bromo-2-methylpropionate Suppliers

Global( 302)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Yunao International Trade Co., Ltd	+8617621705551	asdf@shanghaihg.cn	China	265	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
Shanxi Naipu Import and Export Co.,Ltd	+86-13734021967 +8613734021967	kaia@neputrading.com	China	1011	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58

Supplier	Advantage
Shanghai Yunao International Trade Co., Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
Shanxi Naipu Import and Export Co.,Ltd	58
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58

What is Methyl 2-bromo-2-methylpropionate?
Methyl 2-bromo-2-methylpropionate can be used as a free radical initiator to participate in polymerization reactions. With cur....
Nov 22，2021

View Lastest Price from Methyl 2-bromo-2-methylpropionate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-25	Methyl 2-bromo-2-methylpropionate 23426-63-3	US $0.00 / KG	1KG	≥99%	200mt/year	Jinan Finer Chemical Co., Ltd
2024-03-28	Methyl 2-bromo-2-methylpropionate 23426-63-3	US $20.00 / kg	1kg	99.8%	1000tons	Wuhan Boyuan Import & Export Co., LTD
2023-09-06	Methyl 2-bromoisobutyrate 23426-63-3	US $0.00 / kg	1kg	0.99	1MT/M	Hebei Yanxi Chemical Co., Ltd.

Methyl 2-bromo-2-methylpropionate
23426-63-3
US $0.00 / KG
≥99%
Jinan Finer Chemical Co., Ltd

Methyl 2-bromo-2-methylpropionate
23426-63-3
US $20.00 / kg
99.8%
Wuhan Boyuan Import & Export Co., LTD

Methyl 2-bromoisobutyrate
23426-63-3
US $0.00 / kg
0.99
Hebei Yanxi Chemical Co., Ltd.

Methyl 2-bromo-2-methylpropionate Spectrum

Methyl 2-bromo-2-methylpropionate(23426-63-3)MS Methyl 2-bromo-2-methylpropionate(23426-63-3)IR1

23426-63-3(Methyl 2-bromo-2-methylpropionate)Related Search:

Methyl bromoacetate Isobutyric acid Methyl 4-chlorobutyrate METSULFURON METHYL 2-Bromobutyric acid methyl ester

Bromocyclopentane Thiophanate-methyl Methyl 2-hydroxyisobutyrate Kresoxim-methyl 2-Bromo-2-methylpropionic acid

Methyl butyrate 1-Bromobutane Methyl acrylate Phenoxyethyl isobutyrate Methylparaben

1-Bromododecane Methyl isobutyrate Methyl (R)-(-)-3-hydroxybutyrate

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Methyl Alpha-Bromobutyrate METHYL ALPHA-BROMOISOBUTYRATE methyl a-bromobutyrate METHYL A-BROMOISOBUTYRATE METHYL 2-BROMOISOBUTYRATE METHYL-2-BROMO-ISOBUTYRIC ACID METHYL 2-BROMO-2-METHYLPROPIONATE alpha-Bromoisobutyric acid methyl ester 2-BROMO-2-METHYLPROPIONIC ACID METHYL ESTER 2-BROMOISOBUTYRIC ACID METHYL ESTER 2-Bromo-2-methylpropanoic acid methyl ester 2-Methyl-2-bromopropionic acid methyl ester α-Bromoisobutyric acid methyl ester 2-Bromo-2-methylpropionate methyl ester methyl 2-bromo-2-methyl-propanoate Methyl α-broMo- α-BroMoisobutyrate Methyl ester Methyl alpha-broMoisobutyrate >=99.0% (GC) Methyl α-bromoisobutyrate Methyl 2-bromo-2-methylpropiote Methyl-2-brom-2-methylpropionat Methyl 2-bromoisobutyrate Liquid Alpha - methyl bromoisobutyrate Propanoic acid, 2-bromo-2-methyl-, methyl ester 2-bromo-2-methyl-, methyl ester Propionicacid, Methyl 2-bromo-2-methylpropionate ISO 9001：2015 REACH Methyl 2-bromo-2-methylpropionat Methyl α-bromoisobutyrate methyl 2-bromo-2-methylpropanoate 23426-63-3 23426-63-6 23436-63-3 C3H6BrCOOCH3 CH32CBrCOOCH3 C5H9BrO2 Esters Organic Building Blocks Building Blocks Carbonyl Compounds C2 to C5 ATRP ATRP Initiators Building Blocks C2 to C5 Carbonyl Compounds Chemical Synthesis Esters Materials Science Organic Building Blocks Polymer Science Reagents for Controlled Radical Polymerization Reagents for Polymerization Acids and Derivatives bc0001