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Ammonium hydrogen difluoride

Ammonium hydrogen difluoride
Ammonium hydrogen difluoride structure
CAS No.
1341-49-7
Chemical Name:
Ammonium hydrogen difluoride
Synonyms
NH4HF2;Flammon;ETCHING POWDER;Ammonium difluoride;AMONIUM BI FLUORIDE;AMMONIUM BIFLUORIDE;acidammoniumfluoride;ammoniumhydrofluoride;AMMONIUM ACID FLUORIDE;AmmoniumBifluoridePure
CBNumber:
CB0273686
Molecular Formula:
F2H5N
Formula Weight:
57.04
MOL File:
1341-49-7.mol

Ammonium hydrogen difluoride Properties

Melting point:
125 °C(lit.)
Boiling point:
230 °C
Density 
1,5 g/cm3
vapor pressure 
1 hPa (20 °C)
Flash point:
238°C
storage temp. 
Store at room temperature.
solubility 
630g/l
form 
Solid
color 
White
Specific Gravity
1.5
PH
2 (5.7g/l, H2O, 20℃)
Water Solubility 
630 g/L (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,498
Stability:
hygroscopic
InChIKey
KVBCYCWRDBDGBG-UHFFFAOYSA-N
CAS DataBase Reference
1341-49-7(CAS DataBase Reference)
EPA Substance Registry System
Ammonium fluoride ((NH4)(HF2))(1341-49-7)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,C
Risk Statements  25-34
Safety Statements  22-26-37-45-36/37/39
RIDADR  UN 1727 8/PG 2
WGK Germany  1
RTECS  BQ9200000
3-9
Hazard Note  Toxic/Corrosive/Hygroscopic
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  28261910
Hazardous Substances Data 1341-49-7(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Ammonium hydrogen difluoride price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 224820 Ammonium hydrogen difluoride reagent grade, 95% 1341-49-7 25g $46.5 2018-11-20 Buy
Sigma-Aldrich 224820 Ammonium hydrogen difluoride reagent grade, 95% 1341-49-7 2.5kg $200 2018-11-20 Buy
Alfa Aesar 014660 Ammonium hydrogen fluoride, tech. 95% 1341-49-7 2kg $103 2018-11-16 Buy
Alfa Aesar 014660 Ammonium hydrogen fluoride, tech. 95% 1341-49-7 500g $41.8 2018-11-16 Buy
Strem Chemicals 93-0205 Ammonium hydrogen fluoride, min. 96% (contains 3-4% NH4F) 1341-49-7 2kg $85 2018-11-13 Buy

Ammonium hydrogen difluoride Chemical Properties,Uses,Production

Chemical Properties

white scales or flakes, also referred to asammonium hydrogen fluoride, anunonium difluoride and anunonium acid fluoride.

Chemical Properties

Ammonium bifluoride.

Uses

In manufacture of Mg and Mg alloys; in brightening of Al; for purifying and cleansing various parts of beer-dispensing apparatus, tubes, etc., sterilizing dairy and other food equipment; in glass and porcelain industries; as mordant for aluminum; as a "sour" in laundering cloth. In lab production of HF.

General Description

Ammonium bifluoride solution is the white crystalline solid dissolved in water. Ammonium hydrogen difluoride is corrosive to metals and tissue. Ammonium hydrogen difluoride is used in ceramics.

Air & Water Reactions

Dissolves in water and forms a weak solution of hydrofluoric acid.

Reactivity Profile

AMMONIUM BIFLUORIDE reacts violently with bases. In presence of moisture will corrode glass, cement, and most metals. Flammable hydrogen gas may collect in enclosed spaces. Do not use steel, nickel, or aluminum containers [USCG, 1999].

Hazard

Corrosive to skin.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

Caustic poison and strong irritant by all routes. See also HYDROFLUORIC ACID. When heated to decomposition it emits very toxic fumes of F-, NO,, and NH3.

Potential Exposure

It is used as a sterilizer, in dairy and brewery operations; in the ceramic, glass, and electroplating industries; as a laundry sour.

First aid

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.

Shipping

Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. In the presence of moisture corrodes concrete, metals, glass.

Waste Disposal

May be buried in a specially designated chemical landfill. Aqueous wastes may be reacted with an excess of lime followed by lagooning and either recovery or land disposal of the separated calcium fluoride.

Ammonium hydrogen difluoride Preparation Products And Raw materials

Raw materials

Preparation Products


Ammonium hydrogen difluoride Suppliers

Global( 282)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22043 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20786 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20243 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19997 58
Shanghai Mintchem Development Co., Ltd 021 6845 0923
0086 20 8234 8082 fluorine@tatichem.com China 38 68
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40395 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30291 84
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44187 61

View Lastest Price from Ammonium hydrogen difluoride manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-20 Ammonium hydrogen difluoride
1341-49-7
US $1.00 / kg 1kg 95%-99% 100kg career henan chemical co

Ammonium hydrogen difluoride Spectrum


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