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1,2-DIFLUOROTETRACHLOROETHANE

CAS No.
76-12-0
Chemical Name:
1,2-DIFLUOROTETRACHLOROETHANE
Synonyms
f112;r112;F-112;FC-112;cfc112;ucon112;cfc-112;Fron112;freon112;Ucon 112
CBNumber:
CB0274986
Molecular Formula:
C2Cl4F2
Molecular Weight:
203.83
MDL Number:
MFCD00039322
MOL File:
76-12-0.mol
MSDS File:
SDS
Last updated:2023-05-04 15:15:08

1,2-DIFLUOROTETRACHLOROETHANE Properties

Melting point 24°C
Boiling point 92,8°C
Density 1,634 g/cm3
vapor pressure 45.8 at 25 °C (Boublik et al., 1984)
refractive index 1.413
solubility Soluble in alcohol, chloroform, and ether (Weast, 1986). Miscible in many halogenated hydrocarbons, e.g., chloroform, caterbon tetrachloride, etc.
form Colorless solid or liquid
Water Solubility 120 mg/L at 25 °C (Du Pont, 1966)
Henry's Law Constant 0.102(atm?m3/mol) at 25 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits NIOSH REL: TWA 500 ppm (4,170 mg/m3), IDLH 2,000 ppm; OSHA PEL: TWA 500 ppm (adopted).
CAS DataBase Reference 76-12-0(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII H155PU1V8F
EPA Substance Registry System CFC-112 (76-12-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Danger
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P330-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
Hazard Note  Irritant
Toxicity LD50 (inhalation) for mice 123 gm/m3/2-h (quoted, RTECS, 1985).
IDLA 2,000 ppm

1,2-DIFLUOROTETRACHLOROETHANE Chemical Properties,Uses,Production

Chemical Properties

Colorless liquids or solids with slight ethereal odor.

Chemical Properties

White solid or colorless liquid; slightly camphor-like odor when concentrated. Insoluble in water; soluble in alcohol. Nonflammable.

Physical properties

Clear, colorless liquid or solid with a faint, ethereal or camphor-like odor. Evaporates quickly when spilled.

Uses

As a refrigerant; solvent extractant; as a blowing or foaming agent.

Uses

Degreasing solvent.

General Description

Colorless low-melting solid or liquid with a slight ethereal odor. Mp: 26.5°C; bp: 92.5°C. Density (of liquid): 1.64 g cm-3 at 30°C. Used as a refrigerant, a solvent extractant, and in dry cleaning.

Reactivity Profile

1,2-DIFLUOROTETRACHLOROETHANE is non-flammable. Incompatible with active metals such as potassium, sodium, beryllium, powdered aluminum, zinc, magnesium, and calcium. Reacts with acids.

Hazard

Toxic by inhalation.

Health Hazard

At high concentrations, 1,1,2,2- tetrachloro-1,2-difluoroethane affects the nervous system and causes pulmonary edema in animals; it is expected that severe exposure in humans will produce the same effects. There are no reports of adverse effects in humans.

Safety Profile

A poison by inhalation. Moderately toxic by ingestion. A sktn and eye irritant. When heated to decomposition it emits toxic fumes of Fand Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.

Potential Exposure

Possible risk of forming tumors, Primary irritant (w/o allergic reaction).

Shipping

UN1078 Refrigerant gases, n.o.s., Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas, Technical Name Required

Incompatibilities

Acids and chemically active metals, such as potassium, beryllium, powdered aluminum; zinc, calcium, magnesium, and sodium.

1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE 1,2-DIFLUOROTETRACHLOROETHANE TETRACHLORO-1,2-DIFLUOROETHANE SYM-DIFLUOROTETRACHLOROETHANE 1,1,2,2-Tetrachlor-1,2-difluorethan 1,1,2,2-tetrachloro-1,2-difluoro-ethan 1,1,2,2-Tetrachlorodifluoroethane 1,2-difluoro-1,1,2,2-tetrachloro-ethan 1,2-Difluoro-1,1,2,2-tetrachloroethane FC-112 ucon112 Chlorofluorocarbon-112 (CFC-112) Tetrachlorodifluoroethane (R112) 1,2-Difluorotetrachloroethane (FC-112) SYM-DIFLUOROTETRACHLOROETHANE 7% 1,2-Difluorotetrachloroethane(FC-112)90% 1,2-difluoro-1,1,2,2-tetrachloro-ethane cfc112 cfc-112 CFCl2CFCl2 daiflon112 daiflons2 Difluorotetrachloroethane Ethane, 1,2-difluoro-1,1,2,2-tetrachloro- ethane,1,1,2,2-tetrachloro-1,2-difluoro- f112 F-112 fluorocarbon112 Freon 112 Freon R 112 freon112 freonr112 freonR-112 Fron112 Genetron 112 genetron112 Halocarbon 112 halocarbon112 r112 Refrigerant 112 refrigerant112 refrigerent112 s-Tetrachlorodifluoroethane sym-Tetrachlorodifluoroethane tetrachlorodifluoroethane Ucon 112 76-12-0 28606-74-5 76120 CFC refrigerants Industrial/Fine Chemicals