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1,1'-Thiocarbonyldiimidazole

1,1'-Thiocarbonyldiimidazole Structure
1,1'-Thiocarbonyldiimidazole structure
CAS No.
6160-65-2
Chemical Name:
1,1'-Thiocarbonyldiimidazole
Synonyms
TCDI;Di(1H-imidazol-1-yl)methanethione;1,1-THIOCARBONYLDIIMIDAZOLE;Thiocarbonyl diimidazole;bis(1H-imidazol-2-yl)methanethione;DiiMidaz;diimidazoL;1,1'-THIOCARBONYL;1,1'-Thiocarbonyldii;Thiocarbonylbisimidazole
CBNumber:
CB0280138
Molecular Formula:
C7H6N4S
Molecular Weight:
178.21
MDL Number:
MFCD00005289
MOL File:
6160-65-2.mol
MSDS File:
SDS
Last updated:2023-12-08 08:51:25
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1,1'-Thiocarbonyldiimidazole Properties

Melting point 98-102 °C(lit.)
Boiling point 342°C (rough estimate)
Density 1.3046 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. 2-8°C
solubility Soluble in terahydrofuran, toluene and dichloromethane.
pka 1.96±0.10(Predicted)
form Powder
color Bright yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
BRN 609349
Stability Stable, but air and moisture sensitive. Incompatible with strong oxidizing agents, strong acids.
InChIKey RAFNCPHFRHZCPS-UHFFFAOYSA-N
CAS DataBase Reference 6160-65-2(CAS DataBase Reference)
FDA UNII H8A75XB5AY

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  22-34
Safety Statements  22-24/25-45-36/37/39-26
WGK Germany  3
F  9-21
Hazard Note  Irritant/Keep Cold/Moisture Sensitive
HS Code  29332900
NFPA 704
1
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1,1'-Thiocarbonyldiimidazole price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 156051 1,1′-Thiocarbonyldiimidazole technical grade, 90% 6160-65-2 5g $58.3 2024-03-01 Buy
Sigma-Aldrich 156051 1,1′-Thiocarbonyldiimidazole technical grade, 90% 6160-65-2 10g $110 2024-03-01 Buy
TCI Chemical C1376 1,1'-Thiocarbonyldiimidazole >95.0%(GC)(T) 6160-65-2 5g $146 2024-03-01 Buy
TCI Chemical C1376 1,1'-Thiocarbonyldiimidazole >95.0%(GC)(T) 6160-65-2 25g $508 2024-03-01 Buy
Alfa Aesar B22008 1,1'-Thiocarbonyldiimidazole, tech 90% 6160-65-2 10g $105 2024-03-01 Buy
Product number Packaging Price Buy
156051 5g $58.3 Buy
156051 10g $110 Buy
C1376 5g $146 Buy
C1376 25g $508 Buy
B22008 10g $105 Buy

1,1'-Thiocarbonyldiimidazole Chemical Properties,Uses,Production

Chemical Properties

yellow powder

Application

1,1′-Thiocarbonyldiimidazole (TCDI) is generally used as a reagent to carry out the deoxygenation of vicinal diols by forming cyclic thionocarbonate in Corey-Winter alkene synthesis.
It is used as a reagent in the enantioselective total synthesis of (+)-hapalindole Q, 12-epi-fischerindole U and welwitindolinone A.
It is also used in the preparation of trithiocarbonates, xanthates, and dithiocarbamates as chain transfer agents for the reversible addition fragmentation chain transfer and macromolecular design (RAFT/ MADIX) polymerization.

Uses

1,1’Thiocarbonyldiimidazole can be used to deoxygenate carboxylic monosaccharide analogues.

Uses

1,1'-Thiocarbonyldiimidazole is used as a reagent for the deoxygenation of alcohols with tributyltin hydride and diols with lithium aluminum hydride. It is also used to deoxygenate carboxylic monosaccharide analogues. Further, it is a useful reagent involved in biochemical synthesis. In addition to this, it is used to prepare 1-[bis-(4-methoxy-phenyl)-methyl]-1H-imidazole by reacting with 4,4'-dimethoxy-benzhydrol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 337, 1978 DOI: 10.1021/jo00396a035

Purification Methods

It forms yellow crystals on recrystallisation from tetrahydrofuran or by sublimation at 10-3torr (bath temperature 70-80o). It is hydrolysed by H2O and should be stored dry. [Staab & Walther Justus Liebigs Ann Chem 657 98 1962; Pullukat et al. Tetrahedron Lett 1953 1967, Hanessian et al. Can J Chem 65 1859 1987, Rajanbabu et al. J Am Chem Soc 111 1759 1989.] Thiochrome {2,7-dimethyl-5H -thiachromine-8-ethanol; 3,8-dimethyl-2-hydroxyethyl-5H -

1,1'-Thiocarbonyldiimidazole Preparation Products And Raw materials

Raw materials

Preparation Products

1-Methyl-2-imidazolidinethione 3-PHENYLPROPYL ISOTHIOCYANATE (S)-4-PHENYL-1,3-OXAZOLIDINE-2-THIONE bis(benzylsulfanyl)methanethione 4-Isothiocyanatobenzene-1-sulfonamide
4,4-DIMETHYL-2-OXAZOLIDINONE Di-o-tolythiourea 3-CHLOROPHENYL ISOTHIOCYANATE 4-(TRIFLUOROMETHYL)PHENYL ISOTHIOCYANATE NAPHTHALENE, 1-CYCLOPROPYL-4-ISOTHIOCYANATO-
3-CHLORO-4-FLUOROPHENYL ISOTHIOCYANATE 1,2,4-Triazolo[4,3-b]pyridazine-6-carboxylic acid, 2,3-dihydro-3-thioxo-, methyl ester N-(1H-INDAZOL-6-YL)THIOUREA 1H-Imidazole-1-carbothioic acid, O-propyl ester Benzene, 1-fluoro-4-(2-isothiocyanatoethyl)-
Dimorpholino thioketone

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1,1'-Thiocarbonyldiimidazole Suppliers

Global( 470)Suppliers
Supplier Tel Email Country ProdList Advantage
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58
CHANGZHOU HARVECHEM LTD
+86-0519-88784888 +8613906120163 inquiry@harvechem.com China 245 58
Shanghai Famo Biotech Co Ltd
+86-36680037 +86-18550473860 mayan@famobiotech.com;sales@famobiotech.com China 503 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Zjartschem 		+86-571-8723 8903 jocelynpan@zjarts.com jocelynpan@zjarts.com CHINA 993 58
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Supplier Advantage
CD Chemical Group Limited
58
CHANGZHOU HARVECHEM LTD
58
Shanghai Famo Biotech Co Ltd
58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
Zjartschem 		58
career henan chemical co 		58

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View Lastest Price from 1,1'-Thiocarbonyldiimidazole manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,1'-Thiocarbonyldiimidazole pictures 2023-09-06 1,1'-Thiocarbonyldiimidazole
6160-65-2
 US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Thiocarbonyldiimidazole pictures 2023-03-06 Thiocarbonyldiimidazole
6160-65-2
 US $2.00 / Kg/Bag 10g 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
1,1'-Thiocarbonyldiimidazole pictures 2022-10-11 1,1'-Thiocarbonyldiimidazole
6160-65-2
 US $1.00 / kg 1kg 99% 5000 Ton Hebei Duling International Trade Co. LTD

1,1'-Thiocarbonyldiimidazole Spectrum

1,1'-Thiocarbonyldiimidazole(6160-65-2)MS1,1'-Thiocarbonyldiimidazole(6160-65-2)1HNMR1,1'-Thiocarbonyldiimidazole(6160-65-2)13CNMR1,1'-Thiocarbonyldiimidazole(6160-65-2)IR11,1'-Thiocarbonyldiimidazole(6160-65-2)IR21,1'-Thiocarbonyldiimidazole(6160-65-2)Raman

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1,1'-Thiocarbonyldiimidazole

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N,N'-THIOCARBONYLDIIMIDAZOLE 1,1'-thiocarbonylbis(imidazole) 1,1'-THIOCARBONYLDIIMIDAZOLE 1-(1H-IMidazol-1-ylcarbothioyl)-1H-iMidazole DiiMidaz 1,1'-CARBONOTHIOYLBIS-1H-IMIDAZOLE N, N - sulfur carbonyl iMidazole 1,1'-Thiocarbonyldiimidazole >=95.0% (S) 1,1'-Thiocarbonyldiimidazole technical grade, 90% 1,1'-Thiocarbonyldiimidazole, technical, 90% 1,1'-THIOCARBONYLDIIMIDAZOLE, TECH., 90% N,N'-THIOCARBONYLDIIMIDAZOLE(TCDI) 1,1,-ThiocarbonyldiimidazoleTech90% 1,1'-Thiocarbonyldiimidazole,95% 1H-Imidazole, 1,1-carbonothioylbis- N,N’-Thiocarboryldiimidazole 1,1''-THIOCARBONYLDIIMIDAZOLE (TCDI) Bis(1H-imidazole-1-yl) thioketone Bis(1-imidazolyl) thioketone Di(imidazol-1-yl)methanethione Thiocarbonylbisimidazole 1,1'-Thiocarbonyldiimidazole,90%,tech. 1.1'-Thiocarbonyldiimidazole 100mg [6160-65-2] 1,1'-Thiocarbonyldiimidazole, tech 90% 1,1'-Thiocarbonyldii N'-ThiocarbonyldiiMidazole(TCDI) 1,1'-Thiocarbonyldi(1H-imidazole) 90% 1,1'-THIOCARBONYL diimidazoL 1,1'-Thiocarbonyldiimidazole > Methanethione, di-1H-imidazol-1-yl- 1,1'-Thicarbonyldiimidazole TIANFU-CHEM 6160-65-2 1,1'-Thiocarbonyldiimidazole TCDI 1,1-THIOCARBONYLDIIMIDAZOLE Thiocarbonyl diimidazole Di(1H-imidazol-1-yl)methanethione bis(1H-imidazol-2-yl)methanethione THEOCARBONYL DIIMIDAZOLE 1,1'-Thiocarbonyldiimidazole 6160-65-2 228-183-4 Building Blocks Carbonyldiimidazole Derivatives Synthetic Reagents Imidazoles Coupling Heterocyclic Building Blocks Carbonyldiimidazole Derivatives Coupling Synthetic Reagents Carbonyldiimidazole DerivativesBuilding Blocks Heterocyclic Building Blocks Imidazoles