1-(2-BROMOETHYL)-4-FLUOROBENZENE
- CAS No.
- 332-42-3
- Chemical Name:
- 1-(2-BROMOETHYL)-4-FLUOROBENZENE
- Synonyms
- 4-FLUOROPHENETHYL BROMIDE;4-Fluorophenylethyl broMide;4-Fluorophenethyl bromide,97%;4-Fluorophenethyl bromide 97%;2-(4-FLUOROPHENYL)ETHYL BROMIDE;4-FLUORO-1-(2-BROMOETHYL)BENZENE;1-BROMO-2-(4-FLUOROPHENYL)ETHANE;1-FLUORO-4-(2-BROMOETHYL)BENZENE;4-(2-BroMoethyl)-1-fluorobenzene;1-(2-BROMOETHYL)-4-FLUOROBENZENE
- CBNumber:
- CB0280259
- Molecular Formula:
- C8H8BrF
- Molecular Weight:
- 203.05
- MDL Number:
- MFCD03844794
- MOL File:
- 332-42-3.mol
- MSDS File:
- SDS
| Boiling point | 100-104 °C15 mm Hg(lit.) |
|---|---|
| Density | 1.4498 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 200 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | Liquid or Low Melting Solid |
| color | Clear colorless to light yellow or white to pale yellow |
| CAS DataBase Reference | 332-42-3(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H411 | |||||||||
| Precautionary statements | P264-P270-P273-P301+P312-P391-P501 | |||||||||
| Hazard Codes | Xn,N | |||||||||
| Risk Statements | 22-51/53 | |||||||||
| Safety Statements | 61 | |||||||||
| RIDADR | UN 3082 9 / PGIII | |||||||||
| WGK Germany | 2 | |||||||||
| HS Code | 29039990 | |||||||||
| NFPA 704 |
|
1-(2-BROMOETHYL)-4-FLUOROBENZENE price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 652008 | 4-Fluorophenethyl bromide 97% | 332-42-3 | 5g | $73.5 | 2023-01-07 | Buy |
| TCI Chemical | F0431 | 2-(4-Fluorophenyl)ethyl Bromide >95.0%(GC) | 332-42-3 | 1g | $35 | 2025-07-31 | Buy |
| TCI Chemical | F0431 | 2-(4-Fluorophenyl)ethyl Bromide >95.0%(GC) | 332-42-3 | 5g | $116 | 2025-07-31 | Buy |
| TRC | F595340 | 4-Fluorophenethyl bromide | 332-42-3 | 1g | $130 | 2021-12-16 | Buy |
| SynQuest Laboratories | 1700-B-41 | 1-Bromo-2-(4-fluorophenyl)ethane 97% | 332-42-3 | 100g | $200 | 2021-12-16 | Buy |
1-(2-BROMOETHYL)-4-FLUOROBENZENE Chemical Properties,Uses,Production
Chemical Properties
Clear slightly yellow liquid
Uses
An intermediate in the production of protein A mimetics, serotonin antagonists, and other CNS agents
Synthesis
7589-27-7
332-42-3
Preparative Example 1 Synthesis of 4-fluorophenethyl bromide: Triphenylphosphine (222 g) and N-bromosuccinimide (151 g) were sequentially added to a solution of 4-fluorophenylethanol (100 g) in dichloromethane (1 L) under cooling conditions in an ice bath and the reaction was carried out with continuous stirring for 1 hour. Upon completion of the reaction, the resulting solution was concentrated under reduced pressure and the precipitated crystals were subsequently filtered. The filtrate was further concentrated to afford the target product 4-fluorobromoethylbenzene (133 g) as a colorless oil (yield: 92%). The product was characterized by 1H-NMR (400 MHz, CDCl3): δ (ppm) 3.14 (2H, t, J = 8 Hz), 3.54 (2H, t, J = 8 Hz), 6.98-7.03 (2H, m), 7.15-7.18 (2H, m).
References
[1] Journal of Organic Chemistry, 2006, vol. 71, # 18, p. 7035 - 7044
[2] Tetrahedron Asymmetry, 2001, vol. 12, # 4, p. 585 - 596
[3] Patent: US2002/19531, 2002, A1
[4] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 8, p. 2989 - 3002
[5] Patent: EP2508526, 2012, A1. Location in patent: Page/Page column 48
1-(2-BROMOETHYL)-4-FLUOROBENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20202 | 58 |
| Capot Chemical Co.,Ltd. | +8613336195806 | sales@capot.com | China | 29731 | 60 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Shanghai Worldyang Chemical Co.,Ltd. | +86-021-56795779 +8613651600618 | sales@worldyachem.com | China | 1382 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49733 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29804 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10035 | 58 |
View Lastest Price from 1-(2-BROMOETHYL)-4-FLUOROBENZENE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-12-26 | 1-(2-BROMOETHYL)-4-FLUOROBENZENE
332-42-3
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2021-08-12 | 1-(2-BROMOETHYL)-4-FLUOROBENZENE
332-42-3
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2021-07-02 | 2-(4-Fluorophenyl)ethyl Bromide
332-42-3
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
-
- 1-(2-BROMOETHYL)-4-FLUOROBENZENE
332-42-3
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 1-(2-BROMOETHYL)-4-FLUOROBENZENE
332-42-3
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- 2-(4-Fluorophenyl)ethyl Bromide
332-42-3
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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