4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane
- CAS No.
- 870004-04-9
- Chemical Name:
- 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane
- Synonyms
- 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 2-(4-ethenylphenyl)-4,4,5,5-tetramethyl-;4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane,97%(stabilized with TBC)
- CBNumber:
- CB03042425
- Molecular Formula:
- C14H19BO2
- Molecular Weight:
- 230.11
- MDL Number:
- MFCD18733870
- MOL File:
- 870004-04-9.mol
| Boiling point | 323.5±21.0 °C(Predicted) |
|---|---|
| Density | 0.98±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| solubility | Chloroform (Sparingly), Hexane (Very Slightly) |
| form | Oil to Low-Melting Solid |
| color | White to Brown |
| Stability | Hygroscopic |
| InChI | InChI=1S/C14H19BO2/c1-6-11-7-9-12(10-8-11)15-16-13(2,3)14(4,5)17-15/h6-10H,1H2,2-5H3 |
| InChIKey | ONBKTEDYJFZZCU-UHFFFAOYSA-N |
| SMILES | O1C(C)(C)C(C)(C)OB1C1=CC=C(C=C)C=C1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319 |
| Precautionary statements | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 |
| HS Code | 2931900090 |
4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane price More Price(18)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | T4061 | 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane min. 95.0 % | 870004-04-9 | 1G | $134 | 2025-07-31 | Buy |
| TCI Chemical | T4061 | 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane min. 95.0 % | 870004-04-9 | 5G | $457 | 2025-07-31 | Buy |
| TRC | B124673 | 2-(4-ethenylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | 870004-04-9 | 1g | $145 | 2021-12-16 | Buy |
| Apolloscientific | OR310973 | (4-Vinylphenyl)boronicacidpinacolester | 870004-04-9 | 1g | $87 | 2021-12-16 | Buy |
| AK Scientific | 0436DB | 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane | 870004-04-9 | 250mg | $91 | 2021-12-16 | Buy |
4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane Chemical Properties,Uses,Production
Synthesis
76-09-5
2156-04-9
870004-04-9
General methodology: synthesis of 4,4,5,5-tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane (4a). In anhydrous THF (50 mL), 4-vinylphenylboronic acid (3a, 1.00 g, 6.76 mmol), pinacol (802 mg, 6.80 mmol) and a small amount of magnesium sulfate desiccant were added and the reaction was stirred for 2 h at room temperature. After completion of the reaction, the solid impurities were removed by filtration, and the filtrate was concentrated under reduced pressure to afford the target product 4a (1.55 g, quantitative yield) as a colorless liquid. The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 7.76 (d, 2H, J = 8.0 Hz), 7.40 (d, 2H, J = 8.0 Hz), 6.72 (dd, 1H, J1 = 11.0 Hz, J2 = 17.6 Hz), 5.81 (d, 1H, J = 17.6 Hz), 5.29 (d, 1H, J = 11.0 Hz), 1.81 (d, 1H, J = 11.0 Hz), 1.29 (d, 1H, J = 11.0 Hz). 11.0 Hz), 1.34 (s, 12H).13C NMR (100 MHz, CDCl3) data: δ 140.2, 136.9, 135.0 (2C), 125.5 (2C), 114.9, 83.8 (2C), 24.9 (4C). The measured value of m/z 253.1384 by high-resolution mass spectrometry (HRMS-ES) is consistent with the calculated value [C14H19B2Na]+ 253.1376.
References
[1] Tetrahedron Letters, 2013, vol. 54, # 10, p. 1211 - 1217
[2] Journal of Organic Chemistry, 2016, vol. 81, # 17, p. 8050 - 8060
[3] Journal of the American Chemical Society, 2007, vol. 129, # 34, p. 10348 - 10349
[4] Angewandte Chemie - International Edition, 2018, vol. 57, # 31, p. 9785 - 9789
[5] Angew. Chem., 2018, vol. 130, # 31, p. 9933 - 9937,5
4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane Preparation Products And Raw materials
Raw materials
Preparation Products
4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29855 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8829 | 58 |
| Nextpeptide Inc | +86-0571-81612335 +8613336028439 | sales@nextpeptide.com | China | 19908 | 58 |
| SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8618662433356 | 3899766280@qq.com | China | 26362 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Compound Net Biotechnology Inc. | +8615303909093 | sales@compound-net.com | China | 2914 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39927 | 58 |
View Lastest Price from 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane
870004-04-9
|
US $1.00 / KG | 1KG | 97%-99% | 1kg;5kg;100kg | Career Henan Chemical Co |
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- 4,4,5,5-Tetramethyl-2-(4-vinylphenyl)-1,3,2-dioxaborolane
870004-04-9
- US $1.00 / KG
- 97%-99%
- Career Henan Chemical Co
