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Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

CAS No.
1445085-92-6
Chemical Name:
Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Synonyms
t-BuDavePhos Pd G3;t-BuDavePhos Palladacycle Gen.3;Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)...;Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato[2-(di-t-butylphosphino)-2''-(N,N-dimethylamino)-1,1''-biphenyl](2''-amino-1,1''-biphenyl-2-yl)palladium(II) dichloromethane adduct;Methanesulfonato[2-(di-t-butylphosphino)-2''-(N,N-dimethylamino)-1,1''-biphenyl](2''-amino-1,1''-biphenyl-2-yl)palladium(II) dichloromethane adduct;Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct,[t-BuDavePhos Palladacycle Gen. 3];METHANESULFONATO[2-(DI-T-BUTYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[T-BUDAVEPHOSPALLADACYCLEGEN.3]
CBNumber:
CB03052897
Molecular Formula:
C35H45N2O3PPdS
Molecular Weight:
711.21
MDL Number:
MOL File:
1445085-92-6.mol
Last updated:2023-04-23 13:52:06

Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Properties

form Powder
color green-yellow
CAS DataBase Reference 1445085-92-6

Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 46-2135 Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuDavePhos Palladacycle Gen. 3] 1445085-92-6 250mg $80 2024-03-01 Buy
Strem Chemicals 46-2135 Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuDavePhos Palladacycle Gen. 3] 1445085-92-6 1g $239 2024-03-01 Buy
Strem Chemicals 46-2135 Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [t-BuDavePhos Palladacycle Gen. 3] 1445085-92-6 5g $958 2024-03-01 Buy
Product number Packaging Price Buy
46-2135 250mg $80 Buy
46-2135 1g $239 Buy
46-2135 5g $958 Buy

Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Chemical Properties,Uses,Production

Reaction

  1. Palladium precatalyst for Suzuki-Miyaura coupling reactions.
  2. Palladium precatalyst for arylation reactions of primary amines, secondary amines, primary amides, phenols, alcohols, tert-butyl acetate.
  3. Palladium precatalyst for fluorination reactions
Reactions of 1445085-92-6_1
Reactions of 1445085-92-6_2

Uses

tBuDavePhos Pd G3 has been used as a precatalyst for the Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids. It may also be used for a variety of C-C and C-N cross-coupling reactions.

General Description

tBuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. tBuDavePhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

90-41-5
1445085-92-6
Synthesis of Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) from 2-Aminobiphenyl

Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Preparation Products And Raw materials

Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Suppliers

Global( 41)Suppliers
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Zhuoer Chemical Co., Ltd
02120970332; +8613524231522 sales@zhuoerchem.com China 3015 58
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 399 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418684 +8618949823763 sales@tnjchem.com China 25363 58
LEAP CHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 24738 58
Aladdin Scientific
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BeiJing Hwrk Chemicals Limted 0757-86329057 18501085097 sales3.gd@hwrkchemical.com China 7583 55
Nanjin Cynthia chemicals Technology Co.,Ltd 0550-5618439 15951861180 cynthiachem@163.com China 335 62
WuHan Taiyukaishang Chemical Co., Ltd. 027-87680032 18963957250 355723431@qq.com China 108 55
Sinocompound Catalysts Co., Ltd. 0512-67216630 18962121273; sales@sinocompound.com China 273 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) METHANESULFONATO[2-(DI-T-BUTYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[T-BUDAVEPHOSPALLADACYCLEGEN.3] t-BuDavePhos Palladacycle Gen.3 t-BuDavePhos Pd G3 Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct,[t-BuDavePhos Palladacycle Gen. 3] Methanesulfonato[2-(di-t-butylphosphino)-2''-(N,N-dimethylamino)-1,1''-biphenyl](2''-amino-1,1''-biphenyl-2-yl)palladium(II) dichloromethane adduct Methanesulfonato2-Di-t-butylphosphino-2'-(N,N-dimethylamino)... Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato[2-(di-t-butylphosphino)-2''-(N,N-dimethylamino)-1,1''-biphenyl](2''-amino-1,1''-biphenyl-2-yl)palladium(II) dichloromethane adduct Methanesulfonato[2-(di-t-butylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1445085-92-6 C35H45N2O3PPdS