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Methyl 3-(bromomethyl)benzoate

Methyl 3-(bromomethyl)benzoate structure

CAS No.: 1129-28-8

Chemical Name:: Methyl 3-(bromomethyl)benzoate

Synonyms: TIMTEC-BB SBB005793;METHYL ALPHA-BROMO-M-TOLUATE;M-CARBOMETHOXYBENZYL BROMIDE;3-CARBOMETHOXYBENZYL BROMIDE;Methyl 3-(bromomethyl)benzoat;METHYL 3-(BROMOMETHYL)BENZOATE;Methyle3-(bromomethyl)benzoate;Methyl 3-aMino-4-fluorobezoate;Methyl m-(Bromomethyl)benzoate;3-(BROMOMETHYL)PHENYLACETICACID

CBNumber:: CB0331184

Molecular Formula:: C9H9BrO2

Molecular Weight:: 229.07

MDL Number:: MFCD00051437

MOL File:: 1129-28-8.mol

MSDS File:: SDS

Last updated:2026-01-13 11:13:02

Product description	Number	Pack Size	Price
Methyl 3-(bromomethyl)benzoate 97%	648116	5g	$58.2
Methyl 3-(bromomethyl)benzoate 97%	648116	25g	$261
Methyl 3-(Bromomethyl)benzoate >97.0%(GC)	B2224	5g	$47
Methyl 3-(Bromomethyl)benzoate >97.0%(GC)	B2224	25g	$142
Methyl 3-(Bromomethyl)benzoate	M294015	1g	$50
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Methyl 3-(bromomethyl)benzoate Properties

Melting point	46-47 °C(lit.)
Boiling point	112-114 °C3 mm Hg(lit.)
Density	1,47 g/cm³
Flash point	115°C/0.8mm
storage temp.	2-8°C
form	Crystals or Crystalline Powder
color	White
Water Solubility	Slightly soluble in water.
BRN	638569
InChI	InChI=1S/C9H9BrO2/c1-12-9(11)8-4-2-3-7(5-8)6-10/h2-5H,6H2,1H3
InChIKey	YUHSMQQNPRLEEJ-UHFFFAOYSA-N
SMILES	C(OC)(=O)C1=CC=CC(CBr)=C1
CAS DataBase Reference	1129-28-8(CAS DataBase Reference)
NIST Chemistry Reference	Methyl 3-bromomethylbenzoate(1129-28-8)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H302-H314-H317

Precautionary statements

P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338

PPE

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Codes

C,Xi

Risk Statements

22-34-43

Safety Statements

26-36/37/39-45

RIDADR

UN 3261 8/PG 2

WGK Germany

Hazard Note

Irritant/Corrosive

HazardClass

PackingGroup

III

HS Code

29163990

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Acute Tox. 4 Oral
Skin Corr. 1B
Skin Sens. 1

Limited Quantities

1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

NFPA 704

	0
3		0

Methyl 3-(bromomethyl)benzoate price More Price(29)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	648116	Methyl 3-(bromomethyl)benzoate 97%	1129-28-8	5g	$58.2	2026-03-19	Buy
Sigma-Aldrich	648116	Methyl 3-(bromomethyl)benzoate 97%	1129-28-8	25g	$261	2026-03-19	Buy
TCI Chemical	B2224	Methyl 3-(Bromomethyl)benzoate >97.0%(GC)	1129-28-8	5g	$47	2026-03-19	Buy
TCI Chemical	B2224	Methyl 3-(Bromomethyl)benzoate >97.0%(GC)	1129-28-8	25g	$142	2026-03-19	Buy
TRC	M294015	Methyl 3-(Bromomethyl)benzoate	1129-28-8	1g	$50	2021-12-16	Buy

Product number	Packaging	Price	Buy
648116	5g	$58.2	Buy
648116	25g	$261	Buy
B2224	5g	$47	Buy
B2224	25g	$142	Buy
M294015	1g	$50	Buy

Methyl 3-(bromomethyl)benzoate Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder or crystals

Uses

Methyl 3-(bromomethyl)benzoate is used in organic synthesis of other chemicals.

Synthesis

99-36-5

1129-28-8

General procedure for the synthesis of methyl 3-bromomethylbenzoate from methyl m-methylbenzoate: 30 mL of carbon tetrachloride (CCl4) and 7.9 g of methyl m-methylbenzoate were added to a dry 100 mL three-necked flask, and after dissolution, 0.23 g of AIBN (azobisisobutyronitrile) and 9.36 g of NBS (N-bromosuccinimide) were sequentially added in three additions (with an interval of about 2-3 hours). The reaction system was heated to 70°C and the color of the reaction solution was observed to change gradually from yellow to orange and finally to white. The reaction was monitored by TLC (eluent: cyclohexane/ethyl acetate = 5:1) until the reaction was almost complete. At the end of the reaction, the resulting succinimide and unreacted N-bromosuccinimide were removed by filtration. The filtrate was rotary evaporated to give 11.5 g of a yellow oily product, methyl 3-bromomethylbenzoate, in 95% yield.

References

[1] Organic and Biomolecular Chemistry, 2003, vol. 1, # 14, p. 2506 - 2511
[2] Patent: CN106146413, 2016, A. Location in patent: Paragraph 0027; 0028
[3] European Journal of Medicinal Chemistry, 2009, vol. 44, # 1, p. 7 - 17
[4] Molecules, 2016, vol. 21, # 12,
[5] Patent: WO2018/169777, 2018, A1. Location in patent: Paragraph 0227

Methyl 3-(bromomethyl)benzoate Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Carbon tetrachloride Methyl 3-methylbenzoate Petroleum ether 60-80 AR 2.5LT

3-HYDROXYMETHYL-BENZOIC ACID METHYL ESTER Methanol 3-(broMoMethyl)benzoyl chloride 3-(BROMOMETHYL)BENZOIC ACID AIBN

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METHYL 3-((PIPERIDIN-4-YL)METHYL)BENZOATE 3-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID Methyl 3-(aminomethyl)benzoate hydrochloride DI-TERT-BUTYL HYDRAZODICARBOXYLATE Methyl 3-[(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl]benzoate

Methyl 3-[4-(tert-butoxycarbonylamino)piperidin-1-yl]methylbenzoate Methyl 3-[(3-Formylphenoxy)methyl]benzoate METHYL 3-(1H-1,2,4-TRIAZOL-1-YLMETHYL)BENZOATE methyl 3-((diethoxyphosphoryl)methyl)benzoate

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Methyl 3-(bromomethyl)benzoate Suppliers

Global( 288)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8738	58
Shaanxi Dideu Medichem Co. Ltd	+8617392709771	1097@dideu.com	China	3996	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3009	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Speranza Chemical Co., Ltd.	+86-86-075521030354 +8618688942810	sophieliu@speranzachem.com	China	923	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29820	58
Win-Win Chemical CO., Limited	0086-577-64498589	sales@win-winchemical.com	CHINA	998	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
Shaanxi Dideu Medichem Co. Ltd	58
Capot Chemical Co.,Ltd.	60
Nanjing ChemLin Chemical Industry Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Speranza Chemical Co., Ltd.	55
career henan chemical co	58
Win-Win Chemical CO., Limited	58
Changzhou Ansciep Chemical Co., Ltd.	58
Alchem Pharmtech,Inc.	58

View Lastest Price from Methyl 3-(bromomethyl)benzoate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-03-20	Methyl 3-(bromomethyl)benzoate 1129-28-8	US $10.00 / KG	1KG	99%	5tons	Hebei Chuanghai Biotechnology Co., Ltd
2025-12-24	Methyl 3-(bromomethyl)benzoate 1129-28-8	US $0.10 / KG	1KG	98.0%	10	Shaanxi Dideu Medichem Co. Ltd
2025-12-24	Methyl 3-(bromomethyl)benzoate 1129-28-8	US $0.00-0.00 / KG	1KG	99.0%	1000MT	Shaanxi Dideu Medichem Co. Ltd

Methyl 3-(bromomethyl)benzoate
1129-28-8
US $10.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

Methyl 3-(bromomethyl)benzoate
1129-28-8
US $0.10 / KG
98.0%
Shaanxi Dideu Medichem Co. Ltd

Methyl 3-(bromomethyl)benzoate
1129-28-8
US $0.00-0.00 / KG
99.0%
Shaanxi Dideu Medichem Co. Ltd

Methyl 3-(bromomethyl)benzoate Spectrum

Methyl 3-(bromomethyl)benzoate(1129-28-8)MS Methyl 3-(bromomethyl)benzoate(1129-28-8)¹HNMR Methyl 3-(bromomethyl)benzoate(1129-28-8)IR1 Methyl 3-(bromomethyl)benzoate(1129-28-8)IR2

1129-28-8(Methyl 3-(bromomethyl)benzoate)Related Search:

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Methyle3-(bromomethyl)benzoate TIMTEC-BB SBB005793 METHYL 3-(BROMOMETHYL)BENZOATE M-CARBOMETHOXYBENZYL BROMIDE METHYL ALPHA-BROMO-M-TOLUATE ALPHA-BROMO-M-TOLUIC ACID METHYL ESTER 3-(BROMOMETHYL)BENZOIC ACID METHYL ESTER 3-CARBOMETHOXYBENZYL BROMIDE Methyl 3-(bromomethyl)benzoat 3-(BROMOMETHYL)PHENYLACETICACID Methyl 3-(bromomethyl)benzoate ,97% Methyl 3-(bromomethyl)benzoate,95% Methyl 3-aMino-4-fluorobezoate Methyl 3-(broMoMethyl)benzoate, 95% 5GR 3-(Bromomethyl)benzoic Acid Methyl Ester alpha-Bromo-m-toluic Acid Methyl Ester Methyl alpha-Bromo-m-toluate Benzoic acid, 3-(broMoMethyl)-, Methyl ester Methyl m-(Bromomethyl)benzoate Methyl 3-(Bromomethyl)benzoate > Methyl 3-(bromomethyl)phenylacetate 1129-28-8 1129-28-2 Esters Organic Building Blocks Building Blocks Carbonyl Compounds BENZYL HALIDE C8 to C9 Building Blocks C8 to C9 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Esters Phenyls & Phenyl-Het Aromatic Halides (substituted)