ChemicalBook >> CAS DataBase List >>Lithium triisobutylhydroborate

Lithium triisobutylhydroborate

Lithium triisobutylhydroborate structure

CAS No.: 38721-52-7

Chemical Name:: Lithium triisobutylhydroborate

Synonyms: L-selectride;LITHIUM TRI-SEC-BUTYLBOROHYDRIDE;lithium tri-sec-butylborohydride solution;Lithium tri-sec-butylhydridoborate, 1.0M solution in THF, packaged under Argon in resealable ChemSealTM bottles;1.0MinTHF;L-SELECTRIDE(R);Lithium tri-sec;1.0MsolutioninTHF;ithium tri-sec-butyL;l-selectride solution

CBNumber:: CB0349017

Molecular Formula:: C12H28B.Li

Molecular Weight:: 190.1

MDL Number:: MFCD00011708

MOL File:: 38721-52-7.mol

MSDS File:: SDS

Last updated:2023-12-29 16:38:43

Request For Quotation

Lithium triisobutylhydroborate Properties

Density	0.89 g/mL at 25 °C
Flash point	1 °F
storage temp.	Flammables area
solubility	Miscible with tetrahydrofuran.
form	Liquid
color	Colorless to yellow
Water Solubility	reacts
Sensitive	Moisture Sensitive
BRN	4007327
InChIKey	ACJKNTZKEFMEAK-UHFFFAOYSA-N
CAS DataBase Reference	38721-52-7(CAS DataBase Reference)
FDA UNII	J471N7T23N
EPA Substance Registry System	Borate(1-), hydrotris(1-methylpropyl)-, lithium, (T-4)- (38721-52-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H318-H225-H250-H260-H314-H335-H351
Precautionary statements	P310-P370+P378i-P402+P404-P210-P231+P232-P280-P305+P351+P338-P370+P378-P422
Hazard Codes	F,C
Risk Statements	11-14/15-17-34-35-19-40-37
Safety Statements	16-26-36/37/39-43-45-7/8-30
RIDADR	UN 3394 4.2/PG 1
WGK Germany	1
F	10
TSCA	Yes
HazardClass	4.3
PackingGroup	II
HS Code	29319090

Lithium triisobutylhydroborate price More Price(10)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	178497	L-Selectride? solution 1.0M in THF	38721-52-7	8l	$2090	2024-03-01	Buy
Alfa Aesar	043034	Lithium tri-sec-butylborohydride, 1.0M solution in THF, packaged under Argon in resealable ChemSeal? bottles	38721-52-7	100ml	$82	2024-03-01	Buy
Alfa Aesar	043034	Lithium tri-sec-butylborohydride, 1.0M solution in THF, packaged under Argon in resealable ChemSeal? bottles	38721-52-7	500ml	$332	2024-03-01	Buy
Strem Chemicals	03-1400	Lithium triisobutylhydroborate	38721-52-7	100g	$77	2024-03-01	Buy
Strem Chemicals	03-1400	Lithium triisobutylhydroborate	38721-52-7	500g	$308	2024-03-01	Buy

Product number	Packaging	Price	Buy
178497	8l	$2090	Buy
043034	100ml	$82	Buy
043034	500ml	$332	Buy
03-1400	100g	$77	Buy
03-1400	500g	$308	Buy

Lithium triisobutylhydroborate Chemical Properties,Uses,Production

Description

Lithium tri-sec-butylborohydride, commercially available as a one molar solution in tetrahydrofuran. It is widely used as a mild and strong reducing agent with high stereoselectivity in organic synthesis.

Features

Lithium tri-sec-butylborohydride is a new type of hydride reducing agent, which has the characteristics of strong reducing ability and high regio- and stereoselectivity.

Preparation

Lithium triisobutylhydroborate can be prepared by:In a 3000ml three-necked flask, add 1000ml of 1mol/L tri-sec-butylboron tetrahydrofuran solution, add 1000ml of 1mol/L triethylenediamine tetrahydrofuran solution simultaneously, introduce nitrogen to start stirring, put the mixture of the two in an ice-water bath After cooling to 0° C., 1000 ml of a 1 mol/L lithium aluminum hydride solution in tetrahydrofuran was slowly added dropwise to the above mixed solution with a constant pressure funnel for about 10 hours.

Physical properties

clear colourless solution

Uses

Lithium triisobutylhydroborate is used as a reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions.

Uses

L-Selectride Solution is a reducing agent which is used in the preparation of oxygen heterocycles. Used also as a reactant in the synthesis of novel bicicyclo[3.1.0]hexane analags which may prove useful in the treatment of depression.

Lithium triisobutylhydroborate Preparation Products And Raw materials

Raw materials

Preparation Products

Lithium triisobutylhydroborate Suppliers

Global( 178)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Cangzhou Lingang Xingchen Chemical Co.,Ltd.	+8613820956817	sales1@daofuchem.com	China	6	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	6710	58
Hangzhou ICH Biofarm Co., Ltd	+undefined8613073685410	sales@ichemie.com	China	985	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8823	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58

Supplier	Advantage
Cangzhou Lingang Xingchen Chemical Co.,Ltd.	58
Hebei Mojin Biotechnology Co., Ltd	58
Shanghai UCHEM Inc.	58
Hangzhou ICH Biofarm Co., Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Hebei Guanlang Biotechnology Co., Ltd.	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58

View Lastest Price from Lithium triisobutylhydroborate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-02-23	Lithium triisobutylhydroborate 38721-52-7	US $120.00 / g	1g	1M solution in THF	25kg	Shanghai UCHEM Inc.
2024-01-08	Lithium tri-sec-butylborohydride 38721-52-7	US $0.00-0.00 / kg	100kg	1±0.02M in THF	100 tons	Cangzhou Lingang Xingchen Chemical Co.,Ltd.
2023-11-01	Lithium Tri-sec-butylborohydride 38721-52-7	US $0.00 / kg	200kg	99%	plenty of stock	Hangzhou ICH Biofarm Co., Ltd

Lithium triisobutylhydroborate
38721-52-7
US $120.00 / g
1M solution in THF
Shanghai UCHEM Inc.

Lithium tri-sec-butylborohydride
38721-52-7
US $0.00-0.00 / kg
1±0.02M in THF
Cangzhou Lingang Xingchen Chemical Co.,Ltd.

Lithium Tri-sec-butylborohydride
38721-52-7
US $0.00 / kg
99%
Hangzhou ICH Biofarm Co., Ltd

38721-52-7(Lithium triisobutylhydroborate)Related Search:

SODIUM TRI-SEC-BUTYLBOROHYDRIDE Rivaroxaban Lithium Aluminum Hydride Sodium cyanoborohydride Lithium chloride

Tetramethylammonium borohydride Tributyltin Hydride Sodium triacetoxyborohydride Tetrabutylammonium borohydride Potassium borohydride

Lithium Sodium borohydride Lithium borohydride LITHIUM TRISIAMYLBOROHYDRIDE Lithium hydride

LITHIUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONYL HYDRIDE LITHIUM HYDRIDO(9-BBN-NOPOL BENZYL ETHER ADDUCT) LITHIUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONYL HYDRIDE

1of4

LITHIUM TRI-S-BUTYLHYDROBORATE LITHIUM TRI-SEC-BUTYLHYDRIDOBORATE LITHIUM TRIISOBUTYLHYDROBORATE L-SELECTRIDE(R) l-selectride solution (beta-4)-borate(1-hydrotris(1-methylpropyl)-lithium LITHIUM TRI-SEC-BUTYLBOROHYDRIDE, 1M IN THF Lithium tri-sec-butylborohydride1M solution in THFAcroSeal§3 Lithium tri-sec-butylhydridoborate, 1.0M solution in THF, packaged under Argon in resealable ChemSeal^t bottles LITHIUM TRI-SEC-BUTYLBOROHYDRIDE IN TETRAHYDROGURAN Lithium Tri-sec-butylborohydride (21% in Tetrahydrofuran, ca. 1.0mol/L) L-Selectride(R) solution Lithium tri-sec-butylborohydride, 1.0M solution in THF, pa ckaged under Argon in resealable ChemSealTM bottles Lithium tri-sec-butylborohydride, 1.0M in THF Lithium tri-sec-butylborohydride, 1.0M solution in THF, pa ckaged under Argon in resealable ChemSeal^t bottles LithiuM Tri-sec-butylborohydride (L-selectride), 1M in THF Lithium Tri-sec-butylborohydride (L-selectride), 1.0M in THF Lithium tri-sec-butylborohydride, 1M solution in THF, AcroSeal Lithium tri-sec-butylborohydride, 1M solution in THF Borate(1-), hydrotris(1-methylpropyl)-, lithium, (T-4)- lithium tri-sec-butylhydridoborate, 1.0m in thf lithium tri-sec-butylhydridoborate, 1.0m solution in thf, packaged under argon in resealable chemseal hiuM triisobutylhydroborate LithiuM tri-sec-butylborohydride, 1.0 M solution in THF LithiuM tri-sec-butylborohydride, 1.0 M solution in THF, J&Kseal(bottle) lithium,(beta-4)-borate(1-hydrotris(1-methylpropyl)- lithiumtri-sec-butylborohydride,calselect?li, lithiumtri-sec-butylborohydride,calselect?li,intetrahydrofuran lithium tri-sec-butylhydroborate Lithiumbutylborohydride Lithium tri-sec-butylborohydride, in tetrahydrofuran, 1M solution LITHIUM TRI-SEC-BUTYLBOROHYDRIDE SOL. LITHIUM TRI-SEC-BUTYLBOROHYDRIDE SOL., 1 M IN THF A 800 ML L-SELECTRIDE, 1.0M SOLUTION IN TETRAHYDR OFURAN 1.0MinTHF 1.0MsolutioninTHF Borate(1-),hydrotris(1-Methylpropyl)-, lithiuM (1:1), (T-4)- LithiuM tri-sec-butylborohydride, 1.0 M solution in THF, SpcSeal Lithium Tri-sec-butylborohydride (ca. 21% in Tetrahydrofuran, ca. 1.0mol/L) Lithium Tri-sec-Butylborohydride in THF Lithium tri-sec ithium tri-sec-butyL Lithium tri-sec-butylhydrohydride L-Selectride Solution (1.0M in THF) Lithium triisobutylhydroborate ISO 9001：2015 REACH Lithium trisobutylborohydride boron(3+) lithium(1+) tris(butan-2-ide) hydride L-selectride lithium tri-sec-butylborohydride solution Lithium tri-sec-butylhydridoborate, 1.0M solution in THF, packaged under Argon in resealable ChemSealTM bottles LITHIUM TRI-SEC-BUTYLBOROHYDRIDE Tributyllithium borohydride 38721-52-7 88721-52-7 C12H28BLi LiBCHCH3C2H53H C12H28LiN LiCHCH3CH2CH33BH