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(-)-Camphanic acid chloride

(-)-Camphanic acid chloride
(-)-Camphanic acid chloride
CAS No.
39637-74-6
Chemical Name:
(-)-Camphanic acid chloride
Synonyms
(+)-(1R,4S)-camphani;(-)-CAMPHANIC CHLORIDE;(-)-Camphanoyl chloride;(1S)-(-)CAMPHANYL CHLORIDE;(-)-CAMPHANIC ACID CHLORIDE;(1S)-(-)-CAMPHANIC CHLORIDE;(S)-(-)-1-CAMPHANYL CHLORIDE;(1S)-(-)-CAMPHANOYL CHLORIDE;(1S)-(-)-Camphanicchloride,95%;(1S,4R)-(-)-Camphanic chloride
CBNumber:
CB0352910
Molecular Formula:
C10H13ClO3
Formula Weight:
216.66
MOL File:
39637-74-6.mol

(-)-Camphanic acid chloride Properties

Melting point:
71-73 °C(lit.)
alpha 
-18 º (c=2, CCl4)
Boiling point:
310.92°C (rough estimate)
Density 
1.2072 (rough estimate)
refractive index 
1.5390 (estimate)
storage temp. 
−20°C
form 
Powder
color 
Yellow to orange-brown
optical activity
[α]23/D 18°, c = 2 in carbon tetrachloride
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
BRN 
3590860
CAS DataBase Reference
39637-74-6(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  C,Xi
Risk Statements  34-29
Safety Statements  26-36/37/39-45-8-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10-21
HazardClass  8
PackingGroup  II
HS Code  29322090
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
Precautionary statements:
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P390 Absorb spillage to prevent material damage.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P501 Dispose of contents/container to..…

(-)-Camphanic acid chloride price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 21287 (1S)-(?)-Camphanic chloride for chiral derivatization, ≥98.0% 39637-74-6 5g-f $233 2018-11-13 Buy
Sigma-Aldrich 21287 (1S)-(?)-Camphanic chloride for chiral derivatization, ≥98.0% 39637-74-6 25g-f $920 2018-11-13 Buy
TCI Chemical C1022 (-)-Camphanic Chloride >97.0%(T) 39637-74-6 1g $42 2018-11-22 Buy
TCI Chemical C1022 (-)-Camphanic Chloride >97.0%(T) 39637-74-6 5g $146 2018-11-22 Buy
Alfa Aesar L14148 (1S)-(-)-Camphanic chloride, 95% 39637-74-6 1g $39.8 2018-11-13 Buy

(-)-Camphanic acid chloride Chemical Properties,Uses,Production

Chemical Properties

Off-White Powder

Uses

An optically active resolving agent

Purification Methods

It is soluble in toluene (50g/100mL at 0o) and crystallises from pet ether (b 40-60o). It sublimes at 70o/5mm, Store it dry at 0o, max (CCl4) 1805s and 1780m cm-1. Armarego et al. J Chem Soc, Perkin Trans I 2229 1976, Gerlach Helv Chim Acta 51 1587 1968, Gerlach Helv Chim Acta 68 1815 1985, Beilstein 18/8 V 101.]

(-)-Camphanic acid chloride Preparation Products And Raw materials

Raw materials

Preparation Products


(-)-Camphanic acid chloride Suppliers

Global( 141)Suppliers
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Capot Chemical Co.,Ltd.
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INTATRADE GmbH +49 3493/605464
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(-)-Camphanic acid chloride Spectrum


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