(-)-Camphanic acid chloride
- CAS No.
- 39637-74-6
- Chemical Name:
- (-)-Camphanic acid chloride
- Synonyms
- (+)-(1R,4S)-camphani;(-)-CAMPHANIC CHLORIDE;(-)-Camphanic Chloride;(-)-Camphanoyl chloride;(1S)-(-)CAMPHANYL CHLORIDE;(-)-Camphanic Chloride >(-)-CAMPHANIC ACID CHLORIDE;(1S)-(-)-CAMPHANIC CHLORIDE;(1S)-(-)-CAMPHANOYL CHLORIDE;(S)-(-)-1-CAMPHANYL CHLORIDE
- CBNumber:
- CB0352910
- Molecular Formula:
- C10H13ClO3
- Molecular Weight:
- 216.66
- MDL Number:
- MFCD00135626
- MOL File:
- 39637-74-6.mol
- MSDS File:
- SDS
Melting point | 71-73 °C(lit.) |
---|---|
alpha | -18 º (c=2, CCl4) |
Boiling point | 310.92°C (rough estimate) |
Density | 1.2072 (rough estimate) |
refractive index | 1.5390 (estimate) |
storage temp. | 2-8°C |
solubility | soluble in Dichloromethane, Ether, Ethyl Acetate, Methanol |
form | Powder |
color | Yellow to orange-brown |
optical activity | [α]23/D 18°, c = 2 in carbon tetrachloride |
Water Solubility | decomposes |
Sensitive | Moisture Sensitive |
BRN | 3590860 |
InChIKey | PAXWODJTHKJQDZ-RGURZIINSA-N |
CAS DataBase Reference | 39637-74-6(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C,Xi | |||||||||
Risk Statements | 34-29 | |||||||||
Safety Statements | 26-36/37/39-45-8-27 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-21 | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29322090 | |||||||||
NFPA 704 |
|
(-)-Camphanic acid chloride price More Price(38)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 21287 | (1S)-(−)-Camphanic chloride for chiral derivatization, LiChropur?, ≥98.0% | 39637-74-6 | 5G | $274 | 2022-05-15 | Buy |
Sigma-Aldrich | 21287 | (1S)-(−)-Camphanic chloride for chiral derivatization, LiChropur?, ≥98.0% | 39637-74-6 | 25g | $1080 | 2022-05-15 | Buy |
TCI Chemical | C1022 | (-)-Camphanic Chloride >97.0%(T) | 39637-74-6 | 1g | $86 | 2024-03-01 | Buy |
TCI Chemical | C1022 | (-)-Camphanic Chloride >97.0%(T) | 39637-74-6 | 5g | $251 | 2024-03-01 | Buy |
Alfa Aesar | L14148 | (1S)-(-)-Camphanic chloride, 95% | 39637-74-6 | 1g | $41.65 | 2024-03-01 | Buy |
(-)-Camphanic acid chloride Chemical Properties,Uses,Production
Chemical Properties
Off-White Powder
Uses
(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Uses
An optically active resolving agent
Uses
(1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.
General Description
(1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride.
Purification Methods
It is soluble in toluene (50g/100mL at 0o) and crystallises from pet ether (b 40-60o). It sublimes at 70o/5mm, Store it dry at 0o, max (CCl4) 1805s and 1780m cm-1. Armarego et al. J Chem Soc, Perkin Trans I 2229 1976, Gerlach Helv Chim Acta 51 1587 1968, Gerlach Helv Chim Acta 68 1815 1985, Beilstein 18/8 V 101.]
(-)-Camphanic acid chloride Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12446 | 58 |
Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 10991 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8820 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | info@konochemical.com | China | 2995 | 58 |
View Lastest Price from (-)-Camphanic acid chloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-08-28 | (-)-Camphanic acid chloride
39637-74-6
|
US $1.00 / kg | 1kg | 99% | 50000kg/month | Zibo Hangyu Biotechnology Development Co., Ltd | ||
2023-08-18 | (-)-Camphanic acid chloride
39637-74-6
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | ||
2023-05-04 | Camphanic acid chloride
39637-74-6
|
US $48.00-40.00 / KG | 1KG | 99% | 20tons | Guangzhou Sunton Biotechnology Co., Ltd. |
- (-)-Camphanic acid chloride
39637-74-6
- US $1.00 / kg
- 99%
- Zibo Hangyu Biotechnology Development Co., Ltd
- (-)-Camphanic acid chloride
39637-74-6
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
- Camphanic acid chloride
39637-74-6
- US $48.00-40.00 / KG
- 99%
- Guangzhou Sunton Biotechnology Co., Ltd.
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