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Cupric nitrate trihydrate

Description Reference
Cupric nitrate trihydrate
Cupric nitrate trihydrate structure
CAS No.
10031-43-3
Chemical Name:
Cupric nitrate trihydrate
Synonyms
Gerhardite;Copper(Ⅱ)nitrate;CUPRIC NITRATE 3H2O;COPPER (II) NITRATE;Copper(Ii)NitrateAr;COPPER(II) NITRATE 3H2O;Copper nitrate solution;CUPRIC NITRATE, HYDRATE;COPPER NITRATE, HYDROUS;CUPRIC NITRATE 3-HYDRATE
CBNumber:
CB0400536
Molecular Formula:
CuH6N2O9
Formula Weight:
241.6
MOL File:
10031-43-3.mol

Cupric nitrate trihydrate Properties

Melting point:
114 °C
Boiling point:
170°C
Density 
2,32 g/cm3
storage temp. 
0-6°C
solubility 
2670g/l
form 
Fine Powder
Specific Gravity
2.32
color 
Cream to brown
PH
3-4 (50g/l, H2O, 20℃)
Water Solubility 
soluble
Stability:
Stable. Strong oxidant - may ignite combustible material. Moisture sensitive. Incompatible with anhydrides, ammonia, amides, cyanides.
CAS DataBase Reference
10031-43-3(CAS DataBase Reference)
NIST Chemistry Reference
Copper dinitrate(10031-43-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  O,C,Xn,N
Risk Statements  8-22-34-36/38-50/53-41-38
Safety Statements  17-26-36/37/39-45-37/39-61-60-39
RIDADR  UN 3085 5.1/PG 2
WGK Germany  2
RTECS  GL7875000
3
HazardClass  5.1
PackingGroup  II
HS Code  28342930
Toxicity LD50 orally in Rabbit: 940 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3
Danger
Warning
P210, P220, P221P280, P370+P378,P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P220 Keep/Store away from clothing/…/combustible materials.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Cupric nitrate trihydrate price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 61194 Copper(II) nitrate trihydrate puriss. p.a., 99-104% 10031-43-3 100g $74.4 2018-11-13 Buy
Sigma-Aldrich 61194 Copper(II) nitrate trihydrate puriss. p.a., 99-104% 10031-43-3 500g $285 2018-11-13 Buy
Strem Chemicals 93-2939 Copper(II) nitrate trihydrate, 99.5% 10031-43-3 1kg $81 2018-11-13 Buy
Strem Chemicals 93-2939 Copper(II) nitrate trihydrate, 99.5% 10031-43-3 250g $25 2018-11-13 Buy
Sigma-Aldrich 61197 Copper(II) nitrate trihydrate purum p.a., 98.0-103% (RT) 10031-43-3 250g $52.8 2018-11-13 Buy

Cupric nitrate trihydrate Chemical Properties,Uses,Production

Description

Cupric nitrate is the cupric salt of nitrate. Cupric nitrate has various applications: a major application is its conversion to copper oxide, a powerful catalyst organic chemistry. It can also be used in textiles and polishing agents of other metals. It can also be used to demonstrate chemical voltaic cell reactions in schools. During organic synthesis, it can be combined with acetic anhydride to be used as an effective reagent for nitration of aromatic compounds. Its hydrate form can catalyze oxidative coupling of 2, 6-dimethylphenol to produce a polymer which is an important engineering material. Its tri-hydrate form can catalyze the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates. Its pentahydrate form may be used in the preparation of novel coordination polymers. It also has applications in medicine, as an insecticide, in chemical analysis, in making light sensitive papers.

Reference

https://en.wikipedia.org/wiki/Copper(II)_nitrate
https://www.sigmaaldrich.com/catalog/product/aldrich/229636?lang=en&region=US
https://www.sigmaaldrich.com/catalog/product/sigald/61194?lang=en&region=US
https://www.sigmaaldrich.com/catalog/product/sigald/223395?lang=en&region=US
https://cameochemicals.noaa.gov/chemical/3023

Chemical Properties

Hygroscopic blue crystal with an order of nitric a

Uses

Analytical Reagent

Purification Methods

Crystallise it from weak aqueous HNO3 (0.5mL/g) by cooling from room temperature. The anhydrous salt can be prepared by dissolving copper metal in a 1:1 mixture of liquid NO2 and ethyl acetate and purified by sublimation [Evans et al. J Chem Soc, Faraday Trans 1 75 1023 1979]. The hexahydrate dehydrates to the trihydrate at 26o, and the anhydrous salt sublimes between 150 and 225o, but melts at 255-256o and is deliquescent.

Cupric nitrate trihydrate Preparation Products And Raw materials

Raw materials

Preparation Products


Cupric nitrate trihydrate Suppliers

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Cupric nitrate trihydrate Spectrum


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