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Dibenzo-18-crown-6

CAS No.
14187-32-7
Chemical Name:
Dibenzo-18-crown-6
Synonyms
DB18C6;ibenzo-18-crown-6;6,7,9,10,17,18,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecine;crown18;Crown 18;crown-18;Dibenzocrown;DIBENZO-18-CROWN-6;Dibenzo-18-crown-8;Tin(II) Ionophore I
CBNumber:
CB0436113
Molecular Formula:
C20H24O6
Molecular Weight:
360.4
MDL Number:
MFCD00005098
MOL File:
14187-32-7.mol
MSDS File:
SDS
Last updated:2024-03-19 13:53:49

Dibenzo-18-crown-6 Properties

Melting point 162-164 °C (lit.)
Boiling point 380-384 °C (679 mmHg)
Density 1.1801 (rough estimate)
refractive index 1.5200 (estimate)
Flash point 380-384°C/679mm
storage temp. Store below +30°C.
solubility 0.007g/l
form Fluffy Powder
color White to slightly beige
Water Solubility sparingly soluble
Sensitive air sensitive
λmax 277nm(CH2Cl2)(lit.)
Merck 14,2602
BRN 1162153
InChIKey YSSSPARMOAYJTE-UHFFFAOYSA-N
CAS DataBase Reference 14187-32-7(CAS DataBase Reference)
FDA UNII 0A7W45JCS9
NIST Chemistry Reference Dibenzo-18-crown-6(14187-32-7)
EPA Substance Registry System Dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin, 6,7,9,10,17,18,20,21-octahydro- (14187-32-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H315-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P305+P351+P338+P337+P313
Hazard Codes  Xi,Xn
Risk Statements  36-36/37/38-20/21/22
Safety Statements  26-37/39-36
WGK Germany  2
RTECS  HP5386000
Hazard Note  Irritant
TSCA  Yes
HS Code  29329995
Toxicity LD50 orally in Rabbit: 2600 mg/kg
NFPA 704
1
2 0

Dibenzo-18-crown-6 price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.11731 Crown ether/Dibenzo-18-crown-6 for synthesis 14187-32-7 5G $36.8 2024-03-01 Buy
Sigma-Aldrich 158399 Dibenzo-18-crown-6 98% 14187-32-7 2.5g $18.78 2024-03-01 Buy
Sigma-Aldrich 8.11731 Crown ether/Dibenzo-18-crown-6 for synthesis 14187-32-7 50g $245 2024-03-01 Buy
Sigma-Aldrich 158399 Dibenzo-18-crown-6 98% 14187-32-7 10g $65.8 2024-03-01 Buy
TCI Chemical D1533 Dibenzo-18-crown 6-Ether >99.0%(GC) 14187-32-7 5g $16 2024-03-01 Buy
Product number Packaging Price Buy
8.11731 5G $36.8 Buy
158399 2.5g $18.78 Buy
8.11731 50g $245 Buy
158399 10g $65.8 Buy
D1533 5g $16 Buy

Dibenzo-18-crown-6 Chemical Properties,Uses,Production

Chemical Properties

white to slightly beige fluffy powder

Uses

Crown ether/Dibenzo-18-crown-6 for synthesis. CAS 14187-32-7, molar mass 360.41 g/mol.

Uses

Dibenzo-18-crown-6, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is an important organic intermediate.

Definition

ChEBI: Dibenzo-18-crown-6 is a crown ether that is 18-crown-6 ortho-fused to two benzene rings at positions 8-9 and 17-18. It has a role as a phase-transfer catalyst. It is a member of benzenes and a crown ether.

Purification Methods

Crystallise it from *benzene, n-heptane or toluene and dry it under vacuum at room temperature for several days. [Szezygiel J Phys Chem 91 1252 1987, V.gtle ed. Top Corr Chem (Host Guest Complex Chemistry) 98 1981.]

120-80-9
111-44-4
14187-32-7
Synthesis of Dibenzo-18-crown-6 from Catechol and 2,2'-Dichlorodiethyl ether
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View Lastest Price from Dibenzo-18-crown-6 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dibenzo-18-crown-6 pictures 2024-04-26 Dibenzo-18-crown-6
14187-32-7
US $30.00 / kg 1kg 99% 2000kg hebei hongtan Biotechnology Co., Ltd
Dibenzo-18-crown-6  pictures 2023-05-18 Dibenzo-18-crown-6
14187-32-7
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
Dibenzo-18-crown-6 pictures 2023-05-18 Dibenzo-18-crown-6
14187-32-7
US $9.00 / KG 1KG 99.9 1 ton Hebei Guanlang Biotechnology Co,.LTD
CROWN ETHER/DIBENZO-18-CROWN-6 DIBENZO-18-CROWN-6 dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin,6,7,9,10,17,18,20,21-octahyd dibenzo[bk][1,4,7,10,13,16]hexaoxacyclooctadecane Dibenzocrown Diphenyl-18-crown-6-polyether k](1,4,7,10,13,16)hexaoxacyclooctadecin,6,7,9,10,17,18,20,21-octahydro-Dibenzo[b 6,7,9,10,12,13,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclo-octadecin Dibenzocrownminwhitepowder dibenzo[a,j]-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene 2,3,11,12-Dibenzo-1,4,7,10,13,16-Hexaoxacyclooctad Tin(II) Ionophore I DIBENZO-18-CROWN-6(6,7,9,10,17,18,20,21-OCTAHYDRODIBENZO) 6,7,9,10,17,18,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16] hexaoxacyclooctadecene Crown ether/Dibenzo-18-crown-6 for synthesis DIBENZO-18-CROWN 6-ETHER 2,3,11,12-DIBENZO-1,4,7,10,13,16-HEXAOXACYCLOOCTADECA-2,11-DIENE 6,7,9,10,17,18,20,21-OCTAHYDRODIBENZO 6,7,9,10,17,18,20,21-OCTAHYDRODIBENZO[B,K][1,4,7,10,13,16]HEXAOXACY-CLOOCTADECENE CROWN ETHER/DIBENZO-18-CROWN-6 FOR SYNTH Dibenzo-18-crown-6 Dibenzo-18-crown-6 ,98% Dibenzo-18-crown-6, 98% 10GR Dibenzo-18-crown-6, 98% 50GR Dibenzo-18-crown-6, 6,7,9,10,17,18,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecene, 2,3,11,12-Dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene 6,7,9,10,17,18,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecene, 2,3,11,12-Dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene Dibenzo-18-crown-6, min. 98% 2,2'-[Oxybis(ethyleneoxy)]-[1,1'-[oxybis(ethyleneoxy)]bisbenzene] 2,2'-[Oxybis(ethyleneoxy)][1,1'-[oxybis(ethyleneoxy)]bisbenzene] Diabenzo-18-crown-6 Dibenzo-18-crown-6 ,97% Dibenzo-18-crown-6,2,3,11,12-Dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene, 6,7,9,10,17,18,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecene 2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene,dibenzo-18-crown-6 6,7,9,10,17,18,20,21-octahydrodibenzo(b,k)(1,4,7,10,13,16)hexaoxacyclooctade 6,7,9,10,17,18,20,21-OCTAHYDRODIBENZO(b,k)(1,4,7,10,13,16)HEXAOXACYCLOOCTADECIN Crown 18 crown18 crown-18 Dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecane Dibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin, 6,7,9,10,17,18,20,21-octahydro- 1,4,7,14,17,20-HEXAOXA-[7.7]ORTHOCYCLOPHANE Dibenzo-18-crown-6, 98+% Dibenzo-18-crown-6,min.98% 1,4,7,14,17,20-HEXAOXA[7.7]ORTHOCYCLOPHANE
DIBENZO-18-CROWN-6
Diphenyl and - 18 - crown ether - 6 Dibenzo-18-crown-6 98% dibenzanthrance-18-crown-6 6,7,9,10,12,13,15,16-Octahydrodibenzo[b,e][1,4,7,10,13,16]hexaoxacyclooctadecine Dibenzo-18-crown6-Ether> Dibenzo-18-crown-6, 98%, reagent grade Dibenzo[a,j]-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-dien 6,7,9,10,17,18,20,21-Octahydrodibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecine DB18C6 ibenzo-18-crown-6 Dibenzo-18-crown-8 Dibenzo-18-crown-ether-6 2,5,8,15,18,21-hexaoxatricyclo[20.4.0.0?,1?]hexacosa-1(26),9,11,13,22,24-hexaene 14187-32-7