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Trityl tetrakis(pentafluorophenyl)borate

CAS No.
136040-19-2
Chemical Name:
Trityl tetrakis(pentafluorophenyl)borate
Synonyms
Tritylium Tetrakis(pentafluorophenyl)borate;Triphenylcarbenium Tetrakis(pentafluorophenyl)borate;TriphenylMethyliuM Tetrakis(pentafluorophenyl)borate;ium tetrakis(perfL;TRITYL(TETRAPENTAFLUOROPHENYL)BORATE;Trityltetrakis(pentafluorophenyl)borat;TRITYL TETRAKIS(PENTAFLUOROPHENYL)BORATE;TRITYL(TETRAPENTAFLUOROPHENYL)BORATE 98+%;Trityltetra(pentafluorophenyl)borate,min.98%;Trityl tetrakis(pentafluorophenyl)borate,97%
CBNumber:
CB0441676
Molecular Formula:
C43H15BF20
Molecular Weight:
922.37
MDL Number:
MFCD03426981
MOL File:
136040-19-2.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:36

Trityl tetrakis(pentafluorophenyl)borate Properties

Melting point 180-185℃
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility soluble in CH2Cl2, MeOH, and acetone
form Powder
color Yellow to mustard
Stability hygroscopic
CAS DataBase Reference 136040-19-2
EPA Substance Registry System Methylium, triphenyl-, tetrakis(pentafluorophenyl)borate(1-) (136040-19-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07
Signal word  Warning
Hazard statements  H302-H312-H314-H318-H332
Precautionary statements  P260h-P301+P330+P331-P303+P361+P353-P305+P351+P338-P405-P501a
Hazard Codes  Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  36/37/39-26-22
TSCA  Yes
HazardClass  8
HS Code  29319000
NFPA 704
0
2 0

Trityl tetrakis(pentafluorophenyl)borate price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical T2863 Triphenylmethylium Tetrakis(pentafluorophenyl)borate >98.0%(T) 136040-19-2 1g $197 2024-03-01 Buy
TCI Chemical T2863 Triphenylmethylium Tetrakis(pentafluorophenyl)borate >98.0%(T) 136040-19-2 5g $683 2024-03-01 Buy
Alfa Aesar H36154 Triphenylcarbenium tetrakis(pentafluorophenyl)borate 97% 136040-19-2 1g $182 2024-03-01 Buy
Alfa Aesar H36154 Triphenylcarbenium tetrakis(pentafluorophenyl)borate 97% 136040-19-2 5g $763 2023-06-20 Buy
Strem Chemicals 05-5000 Trityltetra(pentafluorophenyl)borate, min. 97% 136040-19-2 250mg $63 2024-03-01 Buy
Product number Packaging Price Buy
T2863 1g $197 Buy
T2863 5g $683 Buy
H36154 1g $182 Buy
H36154 5g $763 Buy
05-5000 250mg $63 Buy

Trityl tetrakis(pentafluorophenyl)borate Chemical Properties,Uses,Production

Synthesis

A round-bottom flask was charged with K[B(C6F5)4] (0.720 g, 1 mmole) and Ph3CCl (0.280g, 1 mmole) in an argon glove box. The solids were dissolved in dichloromethane (~100 mL), and the reaction mixture was allowed to stir under an argon atmosphere. The solution became yellow-orange immediately. After stirring for 1 h, the solution was then filtered through Celite to remove KCl. The solvent volume was reduced to ~10 mL on a rotary evaporator to give a dark red oil. Addition of pentane resulted in yellow precipitate and a red oil. With sonication, the oil dispersed to give only yellow precipitate. The solid was isolated by filtration and dried in vacuo. Alternatively, the crude filtrate could be layered with pentane, and over the course of days to hours. Crystalline product formed. Isolated yield: 0.703 grams, 76%. 

Chemical Properties

Yellow to mustard colored powder

Uses

Used as a pharmaceutical intermediate.

Synthesis

trityl tetrakis(pentafluorophenyl)borate is prepared by mixing LiB(C6F5)4 and trityl chloride in hexane and refluxing overnight. It is prepared also by one-pot procedure starting from bromopentafluorobenzene.

Solubility in organics

soluble in CH2Cl2, MeOH, and acetone, but its yellow color disappears because these solvents coordinate to the trityl salt.

Trityl tetrakis(pentafluorophenyl)borate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 129)Suppliers
Supplier Tel Email Country ProdList Advantage
WUXI HONOR SHINE CHEMICAL CO.,LTD
0510-83593312 +8613665125081 sales@honorshinechem.com China 61 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15932 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9346 55
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 10248 58
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd.
0431-80514535 13634302652 Extension@chemextension.com CHINA 967 58
HaBo Hong Kong Co., Limited.
+86-25-18512596065 info@habotech.com CHINA 933 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58

View Lastest Price from Trityl tetrakis(pentafluorophenyl)borate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Trityl tetrakis(pentafluorophenyl)borate pictures 2023-08-02 Trityl tetrakis(pentafluorophenyl)borate
136040-19-2
US $0.00 / g 5g 98% 50000000 WUXI HONOR SHINE CHEMICAL CO.,LTD
Trityl tetrakis(pentafluorophenyl)borate pictures 2023-03-09 Trityl tetrakis(pentafluorophenyl)borate
136040-19-2
US $0.00-0.00 / kg 1kg 98%-99% 1000kg LY Global chemicals co.,ltd .
Trityl tetrakis(pentafluorophenyl)borate pictures 2022-03-21 Trityl tetrakis(pentafluorophenyl)borate
136040-19-2
US $6.00 / KG 1KG 99% 100KG Hong Kong Tiansheng New Material Trading Co., Ltd
Triphenylmethylium tetrakis(perfluorophenyl)borate TRITYL TETRAKIS(PENTAFLUOROPHENYL)BORATE TRITYL(TETRAPENTAFLUOROPHENYL)BORATE 98+% Trityltetrakis(pentafluorophenyl)borat TRITYL(TETRAPENTAFLUOROPHENYL)BORATE TRIPHENYLMETHYLCARBENIUM TETRAKIS(PENTAFLUOROPHENYL)BORATE Trityltetra(pentafluorophenyl)borate,min.98% METHYLIUM,TRIPHENYL-,TETRAKIS(PENTAFLUOROPHENYL)BORATE(1-) Trityltetra(pentafluorophenyl)borate, min. 98% Trityl tetrakis(pentafluorophenyl)borate,97% Triphenylmethyl tetrakis-(pentafluorophenyl)-borate Triphenylcarbenium Tetrakis(pentafluorophenyl)borate Tritylium Tetrakis(pentafluorophenyl)borate Methylium, triphenyl-, tetrakis(2,3,4,5,6-p entafluorophenyl)borate(1-) (1:1) ium tetrakis(perfL Triphenylmethylium tetrakis(pentafluorophenyl)borate(1-) Tritylium Tetrakis(pentafluorophenyl)borate Triphenylcarbenium Tetrakis(pentafluorophenyl)borate TriphenylMethyliuM Tetrakis(pentafluorophenyl)borate 136040-19-2 C43H15F20B C6H53CC6F54B C24BF20C19H15 C43H15BF20 C43H16BF20 organofluorine compounds