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(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

CAS No.
24388-23-6
Chemical Name:
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
Synonyms
4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane;Pinacol phenylboronate;Phenylboronic acid pinacol ester 97%;M7121;Phenylpinacolborane;(Pinacolboryl)benzene;PHENYL-BORONIC ACID PINACOL ESTER;Benzeneboronic acid, pinacol ester;Phenylboronic acid pinacol ester, 97%,;(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-
CBNumber:
CB0459079
Molecular Formula:
C12H17BO2
Molecular Weight:
204.07
MDL Number:
MFCD00966985
MOL File:
24388-23-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Properties

Melting point 27-31 °C(lit.)
Boiling point 130°C/20mmHg(lit.)
Density 0.99±0.1 g/cm3(Predicted)
Flash point 225 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to lump
color White to Almost white
InChIKey KKLCYBZPQDOFQK-UHFFFAOYSA-N
CAS DataBase Reference 24388-23-6(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  29319090

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 647098 Phenylboronic acid pinacol ester 97% 24388-23-6 5g $86.4 2024-03-01 Buy
Sigma-Aldrich 647098 Phenylboronic acid pinacol ester 97% 24388-23-6 10g $105 2024-03-01 Buy
TCI Chemical P1855 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >98.0%(GC) 24388-23-6 5g $46 2024-03-01 Buy
TCI Chemical P1855 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >98.0%(GC) 24388-23-6 25g $135 2024-03-01 Buy
Sigma-Aldrich 647098 Phenylboronic acid pinacol ester 97% 24388-23-6 50g $272 2024-03-01 Buy
Product number Packaging Price Buy
647098 5g $86.4 Buy
647098 10g $105 Buy
P1855 5g $46 Buy
P1855 25g $135 Buy
647098 50g $272 Buy

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Chemical Properties,Uses,Production

Chemical Properties

White to light yellow crystal

Uses

suzuki reaction

Uses

Phenylboronic acid pinacol ester can be used:

  • To prepare sulfinamide derivatives by reacting with diethylaminosulfur trifluoride (DAST) and potassium phenyltrifluoroborate.
  • As a substrate in the study of Suzuki–Miyaura coupling of various aryl iodides over SiliaCat?Pd(0).

Synthesis Reference(s)

The Journal of Organic Chemistry, 60, p. 7508, 1995 DOI: 10.1021/jo00128a024

General Description

Phenylboronic acid, pinacol ester, also known as boronate ester, is generally used in metal-catalyzed C-C bond formation reactions like Suzuki–Miyaura?reaction.

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View Lastest Price from (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE pictures 2022-09-14 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
24388-23-6
US $0.00-0.00 / KG 1KG 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE pictures 2021-08-12 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
24388-23-6
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE pictures 2021-07-13 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
24388-23-6
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Phenylpinacolborane 1,3,2-Dioxaborolane,4,4,5,5-tetraMethyl-2-phenyl- (Pinacolboryl)benzene cyclic tetramethylethylene ester benzeneboronic acid PHENYL-BORONIC ACID PINACOL ESTER Benzeneboronic acid, pinacol ester (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)- 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene Phenylboronic Acid Pinacol Ester 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane> M7121 (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborola 24388-23-6 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Phenylboronic acid pinacol ester, 97%, Pinacol phenylboronate Phenylboronic acid pinacol ester 97% 4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 24388-23-6 C12H17BNO2 Aryl Boronic Acids and Derivatives Boronate Esters Organometallic Reagents