ChemicalBook >> CAS DataBase List >>(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

CAS No.
129648-07-3
Chemical Name:
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
Synonyms
ano)ethane;(R,R)-ME-BPE;Bisdimethylphospholanoethane;(+)-1,2-Bis((2R,5R)-2,5-dimethyL;(+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane;1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane;1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane;(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE;(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane;(+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95%
CBNumber:
CB0683443
Molecular Formula:
C14H28P2
Molecular Weight:
258.32
MDL Number:
MFCD01073770
MOL File:
129648-07-3.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Properties

alpha +263° ±3° (c 1, hexane)
Boiling point 64-67 °C 0.06 mm Hg
Density 0.940 g/mL at 25 °C
refractive index n20/D 1.534
form liquid
color colorless to pale-yellow
Sensitive Air Sensitive
CAS DataBase Reference 129648-07-3
FDA UNII 1LS1AFH1F1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H250-H252-H315-H319-H335
Precautionary statements  P210-P222-P305+P351+P338-P405-P422a-P501a
Hazard Codes  F
Risk Statements  11-17
Safety Statements  24/25
RIDADR  UN 2845 4.2/PG 1
WGK Germany  3
HazardClass  4.2
HS Code  29310099
NFPA 704
4
2 0

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B5985 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane 129648-07-3 100MG $132 2024-03-01 Buy
TCI Chemical B5985 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane 129648-07-3 500MG $552 2024-03-01 Buy
Alfa Aesar H60071 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane, 97+% 129648-07-3 250mg $86.8 2021-12-16 Buy
Alfa Aesar H60071 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane, 97+% 129648-07-3 1g $325 2021-12-16 Buy
Strem Chemicals 15-0104 (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane, 98+% (R,R)-Me-BPE 129648-07-3 100mg $75 2024-03-01 Buy
Product number Packaging Price Buy
B5985 100MG $132 Buy
B5985 500MG $552 Buy
H60071 250mg $86.8 Buy
H60071 1g $325 Buy
15-0104 100mg $75 Buy

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Chemical Properties,Uses,Production

Reactions

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 129648-07-3

Chemical Properties

Clear colorless oily liquid

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Suppliers

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(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE (R,R)-ME-BPE Bisdimethylphospholanoethane (+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane, Kanata purity (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane,95% 1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ethane, 97+% (+)-1,2-Bis((2R,5R)-2,5-diMethylphospholano)ethane (R,R)-Me-BPE (+)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]ethane, 97% (R,R-Me-BPE) 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]ethane 1,2-Bis[(2R,5R)-2,5-dimethylphospholan-1-yl]ethane ano)ethane Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-dimethyl-, (2R,2'R,5R,5'R)- (+)-1,2-Bis((2R,5R)-2,5-dimethyL (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane (+)-1,2-Bis[(2R,5R)-2,5-dimethyphospholano]ethane 129648-07-3 C14H28P2 organophosphine ligand