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METHYL ISOCYANOACETATE

CAS No.
39687-95-1
Chemical Name:
METHYL ISOCYANOACETATE
Synonyms
ROXA-015;METHYL ISOCYANOACETATE;Methyl isocyanoformate;Methyl 2-isocyanoacetate;Methyl Isocyanoacetate >Methyl Isocyanoacetate,>97%;2-Oxo-2-methoxyethyl isocyanide;ISOCYANOACETIC ACID METHYL ESTER;(2-Oxo-2-methoxyethyl) isocyanide;39687-95-1 METHYL ISOCYANOACETATE
CBNumber:
CB0700977
Molecular Formula:
C4H5NO2
Formula Weight:
99.09
MOL File:
39687-95-1.mol
MSDS File:
SDS

METHYL ISOCYANOACETATE Properties

Boiling point
75-76 °C10 mm Hg(lit.)
Density
1.09 g/mL at 25 °C(lit.)
refractive index
n20/D 1.417(lit.)
Flash point
193 °F
storage temp.
2-8°C
form
Liquid
color
Clear yellow to brown
Water Solubility
Miscible with organic solvents. Slightly miscible with water.
BRN
3537963
CAS DataBase Reference
39687-95-1(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07,GHS06
Signal word  Danger
Hazard statements  H227-H302-H312-H318-H331-H302+H312+H332-H314
Precautionary statements  P280-P305+P351+P338-P310-P210e-P260h-P303+P361+P353-P405-P501a
Hazard Codes  C
Risk Statements  20/21/22-34
Safety Statements  26-36/37/39-45
RIDADR  UN 2922 8/PG 2
WGK Germany  3
8-9-32-13-19
HazardClass  8
PackingGroup  II
HS Code  29291090

METHYL ISOCYANOACETATE price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 238880 Methyl isocyanoacetate technical grade, 95% 39687-95-1 1g $56.5 2022-05-15 Buy
Sigma-Aldrich 238880 Methyl isocyanoacetate technical grade, 95% 39687-95-1 5g $145 2022-05-15 Buy
TCI Chemical M2549 Methyl Isocyanoacetate >97.0%(GC) 39687-95-1 1g $39 2022-04-27 Buy
TCI Chemical M2549 Methyl Isocyanoacetate >97.0%(GC) 39687-95-1 5g $133 2022-04-27 Buy
Alfa Aesar H31069 Methyl isocyanoacetate, 95% 39687-95-1 5g $88.3 2021-12-16 Buy
Product number Packaging Price Buy
238880 1g $56.5 Buy
238880 5g $145 Buy
M2549 1g $39 Buy
M2549 5g $133 Buy
H31069 5g $88.3 Buy

METHYL ISOCYANOACETATE Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Uses

Methyl isocyanoacetate is used in the copper-catalyzed, diastereoselective synthesis of oxazolines. It is involved in the direct aldol reaction with carbonyl compounds to prepare corresponding oxazoline by using catechol-copper network catalyst. Further, it is also involved in four-component Ugi condensation reaction. It undergoes asymmetric aldol reaction with fluorinated benzaldehyde using gold(I) as a catalyst.

Uses

Methyl isocyanoacetate has been used in the copper-catalyzed, diastereoselective synthesis of oxazolines.

General Description

Methyl isocyanoacetate undergoes direct aldol reaction with carbonyl compounds in the presence of solid-phase catechol-copper network catalyst to yield corresponding oxazolines. It also participates in four-component Ugi condensation reaction.

3154-54-9
39687-95-1
Synthesis of METHYL ISOCYANOACETATE from N-FORMYLGLYCINE METHYL ESTER

METHYL ISOCYANOACETATE Preparation Products And Raw materials

METHYL ISOCYANOACETATE Suppliers

Global( 117)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
0371-55170693 info@tianfuchem.com China 22022 55
Zhejiang ZETian Fine Chemicals Co. LTD
18957127338 stella@zetchem.com China 2010 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47500 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-87569262 +8618192671955 1017@dideu.com China 3981 58
Zhuozhou Wenxi import and Export Co., Ltd
+8613111626072 zzwenxi@126.com CHINA 13187 58
Zhengzhou Alfa Chemical Co.,Ltd
+86-18530059196 18530059196 sale1@alfachem.cn China 14266 58
Hubei Ipure Biology Co., Ltd
+8618062405514 ada@ipurechemical.com China 10352 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com CHINA 34618 58
HONG KONG IPURE BIOLOGY CO.,LIMITED
86 18062405514 18062405514 ada@ipurechemical.com CHINA 3475 58
Shaanxi Dideu Medichem Co. Ltd
29-89586680 +8618192503167 1005@dideu.com China 9938 58

View Lastest Price from METHYL ISOCYANOACETATE manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-08-12 METHYL ISOCYANOACETATE
39687-95-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2020-01-05 Methyl isocyanoacetate
39687-95-1
US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd
Methyl isocyanoacetate, technical grade Methyl isocyanoacetate, 95%, tech. (2-Oxo-2-methoxyethyl) isocyanide 2-Isocyanoacetic acid methyl ester 2-Oxo-2-methoxyethyl isocyanide Methyl 2-isocyanoacetate Methyl isocyanoacetate, tech., 95% 5GR Acetic acid, 2-isocyano-, Methyl ester ISOCYANOACETIC ACID METHYL ESTER METHYL ISOCYANOACETATE METHYL ISOCYANOACETATE, TECH., 95% Methyl isocyanoformate ROXA-015 Methyl isocyanoacetate, 95%, for synthesis Methyl Isocyanoacetate > Methyl Isocyanoacetate,>97% METHYL ISOCYANOACETATE ISO 9001:2015 REACH 39687-95-1 METHYL ISOCYANOACETATE 39687-95-1 CNCH2COOCH3 ISOCYANATE Building Blocks Organic Building Blocks Isocyanides Nitrogen Compounds straight chain compounds Naphthyridine,Quinoline Isocyanides Nitrogen Compounds Organic Building Blocks Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks pharmacetical