ChemicalBook >> CAS DataBase List >>4,4'-Thiobis(6-tert-butyl-m-cresol)

4,4'-Thiobis(6-tert-butyl-m-cresol)

CAS No.
96-69-5
Chemical Name:
4,4'-Thiobis(6-tert-butyl-m-cresol)
Synonyms
Santonox;Rutenol;Sumilizer WX-R;Antioxidant 300;AN 300;AO-300;usafb-15;nocrac300;USAF B-15;yoshinoxs
CBNumber:
CB0722795
Molecular Formula:
C22H30O2S
Molecular Weight:
358.54
MDL Number:
MFCD00026287
MOL File:
96-69-5.mol
MSDS File:
SDS
Last updated:2023-10-13 18:16:27

4,4'-Thiobis(6-tert-butyl-m-cresol) Properties

Melting point 160-165 °C
Boiling point 460.94°C (rough estimate)
Density 1.06~1.12g/cm3
vapor pressure 0.001Pa at 20℃
refractive index 1.5200 (estimate)
Flash point 215 °C
storage temp. Store below +30°C.
solubility DMSO (Slightly), Methanol (Slightly)
pka 10.76±0.36(Predicted)
form Fine white to gray powder.
color White to Off-White
Water Solubility <0.01 g/100 mL at 18 ºC
Stability Stable under recommended storage conditions., Stable Under Recommended Storage C
InChIKey HXIQYSLFEXIOAV-UHFFFAOYSA-N
LogP 5.24 at 25℃
CAS DataBase Reference 96-69-5(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances 4,4'-THIOBIS(6-TERT-BUTYL-M-CRESOL)
FDA 21 CFR 175.105; 177.2600; 178.2010
FDA UNII 3CA5G9822V
NIST Chemistry Reference 4,4'-Thiobis(3-methyl-6-t-butylphenol)(96-69-5)
EPA Substance Registry System 4,4'-Thiobis(6-tert-butyl-m-cresol) (96-69-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H317-H410
Precautionary statements  P261-P272-P273-P280-P302+P352-P333+P313
Hazard Codes  Xi,N
Risk Statements  36/37/38-50/53-43
Safety Statements  37/39-26-61-60-36/37-24/25
WGK Germany  WGK 2 water endangering
RTECS  GP3150000
Autoignition Temperature 402 °C
HS Code  29309070
Toxicity LD50 orally in Rabbit: 2345 mg/kg
NFPA 704
0
1 0

4,4'-Thiobis(6-tert-butyl-m-cresol) price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.18449 4,4′-Thiobis(2-tert-butyl-5-methylphenol) for synthesis 96-69-5 100g $71.1 2024-03-01 Buy
Sigma-Aldrich 90557 4,4′-Thiobis(2-tert-butyl-5-methylphenol) analytical standard 96-69-5 100MG $75.1 2022-05-15 Buy
TCI Chemical T0196 4,4'-Thiobis(6-tert-butyl-m-cresol) >98.0%(GC) 96-69-5 25g $30 2024-03-01 Buy
TCI Chemical T0196 4,4'-Thiobis(6-tert-butyl-m-cresol) >98.0%(GC) 96-69-5 100g $56 2024-03-01 Buy
TCI Chemical T0196 4,4'-Thiobis(6-tert-butyl-m-cresol) >98.0%(GC) 96-69-5 500g $163 2024-03-01 Buy
Product number Packaging Price Buy
8.18449 100g $71.1 Buy
90557 100MG $75.1 Buy
T0196 25g $30 Buy
T0196 100g $56 Buy
T0196 500g $163 Buy

4,4'-Thiobis(6-tert-butyl-m-cresol) Chemical Properties,Uses,Production

Chemical Properties

4,40-Thiobis(6-tert-butyl-m-cresol) is a light gray to tan powder. Aromatic odor.

Chemical Properties

white to almost white crystals or crystalline

Uses

Protection of light-colored rubber from oxidation and of nonstaining neoprene compounds against deterioration.

Uses

4,4''-Thiobis(2-tert-butyl-5-methylphenol) is an antioxidant. 4,4''-Thiobis(2-tert-butyl-5-methylphenol) is a radical inhibitor which prevented thermal decomposition of the peracid.

Uses

As an antioxidant in the rubber and plastics industry; as a stabilizer in polyethylene and polyolefin packaging materials for foodstuffs.

General Description

White or light gray to tan powder.

Air & Water Reactions

Sensitive to base hydrolysis and may spontaneously oxidize in solution. . Insoluble in water.

Reactivity Profile

4,4'-Thiobis(6-tert-butyl-m-cresol) may be sensitive to light.

Hazard

Toxic by inhalation. Upper respiratory tract irritant. Questionable carcinogen.

Health Hazard

4,4'-Thiobis(6-tert-butyl-mcresol) (TBBC) is of low systemic toxicity in animals; allergic contact dermatitis has been reported in humans.

Fire Hazard

4,4'-Thiobis(6-tert-butyl-m-cresol) is combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by intraperitoneal route and probably by ingestion and inhalation. Mutation data reported. See also SULFIDES. When heated to decomposition it emits highly toxic fumes of SOx.

Potential Exposure

This material is used as an antioxidant in the plastics and rubber industries; in Neoprene and other synthetic rubbers; in polyethylene and polypropylene.

Carcinogenicity

TBBC was not mutagenic in Salmonella typhimurium strains with or without metabolic activation. In Chinese hamster ovary cells, TBBC induced an increase in sister chromatid exchanges but there were no increases in chromosomal aberrations.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May evolve explosive hydrogen sulfide upon contact with moisture or acids.

88-60-8
96-69-5
Synthesis of 4,4'-Thiobis(6-tert-butyl-m-cresol) from 6-tert-Butyl-m-cresol

4,4'-Thiobis(6-tert-butyl-m-cresol) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 278)Suppliers
Supplier Tel Email Country ProdList Advantage
QINGDAO JADE NEW MATERIAL TECNOLOGY CO.,LTD
+86 13658692156 zandrew@jadenmtc.com China 220 58
Qingdao Truelight functional Material Technology Co., Ltd.
+86-13573844393 songjames@truelightchem.com China 219 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12452 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 14936 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9354 55
Tianjin Zhongxin Chemtech Co., Ltd.
+86-022-66880623 +8618622897568 sales@tjzxchem.com China 558 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58

View Lastest Price from 4,4'-Thiobis(6-tert-butyl-m-cresol) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ANTIOXIDANT TRUELICHT AN300C pictures 2024-02-29 ANTIOXIDANT TRUELICHT AN300C
96-69-5
US $0.00 / KG 1drums 98.0% 1000TON Qingdao Truelight functional Material Technology Co., Ltd.
Antioxidant 300 pictures 2023-10-14 Antioxidant 300
96-69-5
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Antioxidant 300 pictures 2023-09-06 Antioxidant 300
96-69-5
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
  • Antioxidant 300 pictures
  • Antioxidant 300
    96-69-5
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
4,4'-Thiobis(6-tert-butyl-3-methylphenol) 5-t-Butyl-4-hydroxy-2-methylphenyl sulfide antagecrystal antioxidantao antioxidanttmb6 Bis(4-hydroxy-5-tert-butyl-2-methylphenyl) sulfide bis(4-hydroxy-5-tert-butyl-2-methylphenyl)sulfide Disperse MB-61 dispersemb-61 Lowinox 44S36 m-Cresol, 4,4'-thiobis*6-tert-butyl- m-Cresol, 4,4'-thiobis[6-tert-butyl- nocrac300 nonflexbps Phenol, 4,4'-thiobis*2-(1,1-dimethylethyl)-5-methyl- Phenol, 4,4'-thiobis[2-(1,1-dimethylethyl)-5-methyl- Santonox BM santonoxbm Sumilizer WX sumilizerwx sumilizerwx-r Thioalkofen BM 4 Thioalkofen BMCh Thioalkofen MBCh thioalkofenbm4 thioalkofenbmch thioalkofenmbch Thioalkophene BM-4 thioalkophenebm-4 Ultranox 236 USAF B-15 usafb-15 Yoshinox S Yoshinox SR yoshinoxs 4,4'-Thiobis(6-tert-butyl-m-cresol) 4,4'-Thiobis(2-tert-butyl-5-methylphenol) for synthesis 44THIOBIS6TERTBUTYLMETACRESOL 6,6′-Di-tert-butyl-4,4′-thiodi-m-kresol 6,6-Di-tert-butyl-4,4-thiodi-m-cresol - Total dust 6,6-Di-tert-butyl-4,4-thiodi-m-cresol -Respirable 6,6'-di-tert-butyl-4,4'-thiodi-m-cresol 5-TERT-BUTYL-4-HYDROXY-2-METHYLPHENYL & Thanox300 5-TERT-BUTYL-4-HYDROXY-2-METHYLPHENYL SULFIDE 96% 4,4'-thiobis(2-(tert-butyl)-3-Methylphenol) Antioxidant AN-300 Bis(2-methyl-4-hydroxy-5-tert-butylphenyl) sulfide 4,4'-Thiobis[3-methyl-6-(1,1-dimethylethyl)phenol] 4,4'-THIOBIS(6-T-BUTYL-M-CRESOL) 5-tert-Butyl-4-hydroxy-2-methylphenyl sulfide,96% 4,4-Thiob 4,4'-Thio bis-(6-butyl-3-Methyl-phenol ) 5-tert-Butyl-4-hydroxy-2-Methylphenyl sulfide, 96% 500GR Antioxidant K3004,4'-Thiobis(6-tert-butyl-M-cresol) yoshinoxsr 4,4'-Thiobis(3-methyl-6-tert-butylphenol) 4,4'-THIO-BIS-(6-T-BUTYL-3-METHYLPHENOL)