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(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) structure

CAS No.: 174810-09-4

Chemical Name:: (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

Synonyms: (R,R)-TROST LIGAND(NAPHTHYL);(R,R)-DACH-naphthyl Trost ligand;(R,R)-DACH-naphthyl Trost ligand 95%;(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...;N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide);N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide);(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL);(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide;1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

CBNumber:: CB0725802

Molecular Formula:: C52H44N2O2P2

Molecular Weight:: 790.87

MDL Number:: MFCD02684551

MOL File:: 174810-09-4.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Properties

Melting point	224-231 °C
alpha	69o (C=1 IN METHANOL)
form	Powder
pka	13.43±0.40(Predicted)
color	off-white
optical activity	[α]20/D +69.0°, c = 1 in methanol
InChIKey	VXFKMKXTPXVEMU-AWSIMMLFSA-N
CAS DataBase Reference	174810-09-4

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H302-H315-H318-H361-H370-H372-H317-H402
Precautionary statements	P501-P273-P272-P260-P270-P202-P201-P264-P280-P302+P352-P308+P311-P362+P364-P333+P313-P301+P312+P330-P305+P351+P338+P310-P405
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
HS Code	2931499090

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) price More Price(16)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	692778	(R,R)-DACH-naphthyl Trost ligand 95%	174810-09-4	250mg	$80.4	2024-03-01	Buy
Sigma-Aldrich	692778	(R,R)-DACH-naphthyl Trost ligand 95%	174810-09-4	1g	$306.6	2024-03-01	Buy
Strem Chemicals	15-0963	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand	174810-09-4	100mg	$43	2024-03-01	Buy
Strem Chemicals	15-0963	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand	174810-09-4	500mg	$157	2024-03-01	Buy
Strem Chemicals	15-0963	(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand	174810-09-4	2g	$499	2024-03-01	Buy

Product number	Packaging	Price	Buy
692778	250mg	$80.4	Buy
692778	1g	$306.6	Buy
15-0963	100mg	$43	Buy
15-0963	500mg	$157	Buy
15-0963	2g	$499	Buy

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties,Uses,Production

Reactions

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles. Reactions of 174810-09-4_1
Reactions of 174810-09-4_2

Chemical Properties

white to off-white powder

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) synthesis

Synthesis of (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) from METHYL 2-HYDROXY-1-NAPHTHOATE

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Preparation Products And Raw materials

Raw materials

2-DIPHENYLPHOSPHINO-1-NAPHTHOIC ACID Methyl 2-diphenylphosphino-1-n METHYL 2-HYDROXY-1-NAPHTHOATE METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE (1R,2R)-(-)-1,2-Diaminocyclohexane

Preparation Products

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Suppliers

Global( 82)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47465	58
Shaanxi Dideu Medichem Co. Ltd	18192627656	1012@dideu.com	China	3453	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58
Henan Alfa Chemical Co., Ltd	+8618339805032	alfa4@alfachem.cn	China	12755	58
changzhou huayang technology co., ltd	+8615250961469	2571773637@qq.com	China	9821	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19994	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Shaanxi Dideu Medichem Co. Ltd	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Henan Alfa Chemical Co., Ltd	58
changzhou huayang technology co., ltd	58
Labnetwork lnc.	58

View Lastest Price from (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-03-16	(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) 174810-09-4	US $1.00-0.00 / KG	1KG	99%	20 tons	Shaanxi Dideu Medichem Co. Ltd
	2019-08-09	(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 174810-09-4	US $1.00 / KG	1KG	98%	1kg,5kg,100kg	Career Henan Chemical Co

(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)
174810-09-4
US $1.00-0.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
174810-09-4
US $1.00 / KG
98%
Career Henan Chemical Co

174810-09-4((1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL))Related Search:

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 1,2-Diaminocyclohexane N,N'-Dimethyl-1,2-cyclohexanediamine TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine

2-Diphenylphosphinobenzaldehyde

1of3

(R,R)-TROST LIGAND(NAPHTHYL) (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand (R,R)-DACH-naphthyl Trost ligand (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide) 1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- (R,R)-DACH-naphthyl Trost ligand 95% N,N'-(1R,2R)-Cyclohexane-1,2-diylbis[2-(diphenylphosphanyl)naphthalene-1-carboxamide] 2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide (1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph... N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide) 174810-09-4 Chiral Nitrogen DACH&Trost Series