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Perfluorooctanesulfonic acid

CAS No.
1763-23-1
Chemical Name:
Perfluorooctanesulfonic acid
Synonyms
PFOS;PERFLUOROOCTANESULFONIC ACID;PERFLUOROOCTANESULFONIC ACID;PERFLUOROOCTANESULFONATE;PFOSA;Perfluoro(octane-1-sulfonic acid);Perfluorooctane sulfonic acid,100 ug/mL in MeOH;1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluorooctane-1-sulfonic acid;EF 101;HeptadecafL
CBNumber:
CB0745383
Molecular Formula:
C8HF17O3S
Molecular Weight:
500.13
MDL Number:
MFCD00042454
MOL File:
1763-23-1.mol
Last updated:2023-12-21 13:45:48

Perfluorooctanesulfonic acid Properties

Melting point 90 °C
Boiling point 260 °C
Density 1.25
Flash point 11 °C
storage temp. 2-8°C
solubility Ethanol: 10 mg/ml
pka -3.27±0.50(Predicted)
BRN 1813859
CAS DataBase Reference 1763-23-1(CAS DataBase Reference)
FDA UNII 9H2MAI21CL
Proposition 65 List Perfluorooctane sulfonate (PFOS)
EPA Substance Registry System Perfluorooctane sulfonic acid (1763-23-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H351-H360D-H362-H372-H411
Precautionary statements  P201-P202-P263-P273-P301+P312-P308+P313
Hazard Codes  C,N,T,F
Risk Statements  34-57-51/53-22-39/23/24/25-23/24/25-11-64-48/25-40-20/22-61
Safety Statements  26-36/37/39-45-61-36/37-16-7-53
RIDADR  UN 3265 8/PG 2
WGK Germany  -
RTECS  RG9701600
Hazard Note  Corrosive
HS Code  29049090
NFPA 704
3
2 0

Perfluorooctanesulfonic acid price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 33607 Heptadecafluorooctanesulfonic acid solution 100 μg/mL in methanol, analytical standard 1763-23-1 1ml $127 2024-03-01 Buy
Sigma-Aldrich 77283 Heptadecafluorooctanesulfonic acid solution ~40% in H 1763-23-1 10ml $146 2023-06-20 Buy
Sigma-Aldrich 77283 Heptadecafluorooctanesulfonic acid solution ~40% in H 1763-23-1 50ml $550 2024-03-01 Buy
Matrix Scientific 099842 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluoro-octane-1-sulfonic acid 95+% 1763-23-1 5g $609 2021-12-16 Buy
American Custom Chemicals Corporation HCH0026163 HEPTADECAFLUOROOCTANESULFONIC ACID 95.00% 1763-23-1 1G $629.48 2021-12-16 Buy
Product number Packaging Price Buy
33607 1ml $127 Buy
77283 10ml $146 Buy
77283 50ml $550 Buy
099842 5g $609 Buy
HCH0026163 1G $629.48 Buy

Perfluorooctanesulfonic acid Chemical Properties,Uses,Production

Description

Perfluorooctanesulfonic acid or perfluorooctane sulfonate (PFOS), is a man-made fluorosurfactant and global pollutant. It is a very useful catalyst in chemical industry. It can catalyze the Intramolecular Hydroamination of Olefinic Sulfonamides in Fluorous Biphase System (FBS)1. It can also catalyze ring-opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide2. It is useful in the nitroaldol reaction in fluorous media, which is an important improvement of the chemo-selective addition of aldehyde3.

Chemical Properties

Perfluorooctane sulfonate can exist as a liquid or a powder. It is soluble in water (NTP, 2013). Perfluorooctane sulfonate has the ability to react with strong oxidizing agents. Upon decomposition, PFOS can form carbon oxides, sulfur oxides, and hydrogen fluoride. Additional information related to the physical and chemical properties of PFOS are not currently available.

Uses

Perfluorooctane sulfonate (PFOS, 1-octanesulfonic acid, heptadecafluorooctanesulfonic acid, perfluorooctanesulfonic acid, 1-perfluorooctanesulfonic acid) is an eight-carbon compound in the perfluoroalkyl family of chemicals. Perfluorooctane sulfonate is used in a variety of applications, including textiles, leather products, cleaning products, and pesticides. Its main use was as a stain repellent on carpet, furniture, and other consumer products. 3M was the primary manufacturer of the chemical until it voluntarily phased it out in 2002 (USEPA, 2012). Perfluorooctane sulfonate is not manufactured any longer in the United States, but it can be imported for use in specific applications.

Application

Heptadecafluorooctanesulfonic acid may be used as an analytical reference standard for the determination of the analyte in water samples using solid-phase microextraction combined with high-performance liquid chromatography with electrospray-ion trap mass spectrometry.

Definition

ChEBI: Perfluorooctane-1-sulfonic acid is a perfluoroalkanesulfonic acid that is octane-1-sulfonic acid in which all seventeen of the hydrogens that are attached to carbons hvae been replaced by fluorines. It has a role as an antilipemic drug and a persistent organic pollutant. It is functionally related to an octane-1-sulfonic acid.

General Description

Heptadecafluorooctanesulfonic acid belongs to the class of perfluorinated alkyl acids and is emerging as persistent organic contaminants in the environment.

Health effects

Exposure to unsafe levels of PFOA/PFOS concentrations through drinking water may result in health effects including developmental effects to fetuses during pregnancy, cancer, liver effects, immune effects and thyroid effects.

Environmental considerations

Perfluorooctane sulfonic acid (PFOS) is one of a group of related chemicals known as perfluorinated alkylated substances (PFAS). These are also called perfluorochemicals (PFCs). This group of chemicals is commonly used in a wide range of industrial processes and is found in many consumer products. PFOS can enter groundwater from multiple sources, including sewage treatment plants, industrial sites, landfills, and places where it is used in firefighting foam such as airports, firefighter training sites, and military installations. Fish and shellfish can take up PFOS from water contaminated with the chemical.

References

[1] YAN YIN Gang Z. Heptadecafluorooctanesulfonic acid (C8F17SO3H) catalyzed intramolecular hydroamination of olefinic sulfonamides in fluorous biphase system (FBS)[J]. Journal of Fluorine Chemistry, 2007, 128 1: Pages 40-45. DOI:10.1016/j.jfluchem.2006.09.012.
[1] SHI M, CHEN Y, XU B, et al. Heptadecafluorooctanesulfonic acid catalyzed ring opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide[J]. Green Chemistry, 2003, 1: 85-88. DOI:10.1039/B210988C.
https://www.sciencedirect.com/science/article/pii/S1566736707001240
https://www.p65warnings.ca.gov/fact-sheets/pfos-perfluorooctane-sulfonate-or-perfluorooctane-sulfonic-acid
https://19january2021snapshot.epa.gov/sites/static/files/2017-12/documents/ffrrofactsheet_contaminants_pfos_pfoa_11-20-17_508_0.pdf
https://www.health.state.mn.us/communities/environment/risk/docs/guidance/gw/pfosinfo.pdf
[1] PING QI. Aquatic predicted no-effect-concentration derivation for perfluorooctane sulfonic acid[J]. Environmental Toxicology and Chemistry, 2011, 30 4: 836-842. DOI:10.1002/etc.460.

Perfluorooctanesulfonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 72)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Fluoropharm Co., Ltd.
+86-0571-85586753; +8613336034509 sales@fluoropharm.com China 1290 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
Allfluoro pharmaceutical co. ltd.
021-26137118 +8615821363818 sales@allfluoro.com China 5791 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58

View Lastest Price from Perfluorooctanesulfonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
HEPTADECAFLUOROOCTANESULFONIC ACID pictures 2021-08-12 HEPTADECAFLUOROOCTANESULFONIC ACID
1763-23-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
HEPTADECAFLUOROOCTANESULFONIC ACID pictures 2019-07-06 HEPTADECAFLUOROOCTANESULFONIC ACID
1763-23-1
US $1.00 / KG 1KG 99% 1ton Career Henan Chemical Co
1-Octanesulfonicacid,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro heptadecafluorooctanesulfonicacidsol. heptadecafluorooctanesulfonic acid solution Perfluorooctanesulphonic acid 98% Perfluorooctanesulphonicacid98% PERFLUOROOCTANESULPHONATE PERFLUOROOCTANYLSULFONATE heptadecafluorooctane-1-sulphonic acid PERFLUOROOCTANESULFONIC ACID SOLN. 50% & HEPTADECAFLUOROOCTANESULFONIC ACID SOL., ~40% IN WATER HEPTADECAFLUOROOCTANESULFONIC ACID 98% 1-Perfluorooctanesulfonic acid EF 101 Eftop EF 101 Perfluoro-n-octanesulfonic acid Heptadecafluorooctanesulfonic acid solution ~40% in H2O (T) Perfluorooctylsulfonic acid HeptadecafluorooctanesulfoniAcid HEPTADECAFLUOROOCTANESULFONIC ACID HEPTADECAFLUOROOCTANE SULPHONIC ACID HEPTADECAFLUORO-1-OCTANESULFONIC ACID PERFLUOROOCTANESULPHONIC ACID 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-HEPTADECAFLUORO-1-OCTANESULFONIC ACID 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-1-octanesulfonicaci Perfluorooctanesulfonic acid solution fonic acid soL HeptadecafL Perfluorooctylsulfonic Acid (50μg/mL in Methanol) DISCONTINUED Perfluorooctylsulfonic Acid DISCONTINUED 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluorooctane-1-sulfonic acid Perfluoro(octane-1-sulfonic acid) PERFLUOROOCTANESULFONATE PFOS PFOSA PERFLUOROOCTANESULFONIC ACID Perfluorooctane sulfonic acid,100 ug/mL in MeOH PERFLUOROOCTANESULFONIC ACID (MIX OF ISOMERS) UNLABELED 50 UG/ML IN METHANOL Caprylic Acid Impurity 76 (Perfluorooctylsulfonic Acid) PERFLUOROOCTANESULFONIC ACID Perfluorooctane sulfonic acid in methanol 1763-23-1 CF3CF27SO3H C8HF17O3S Fluorous Chemistry Fluorous Compounds Surfactants Fluorochemical Surfactants Building Blocks Sulfur Compounds Sulfonic/Sulfinic Acids Organic Building Blocks Building Blocks Chemical Synthesis Fluorinated Building Blocks F-Tagged Organic Building Blocks Organic Fluorinated Building Blocks Sulfonic/Sulfinic Acids