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(S)-(+)-KETOPINIC ACID

CAS No.
40724-67-2
Chemical Name:
(S)-(+)-KETOPINIC ACID
Synonyms
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid;(1S)-7;(+)-Ketopinic acid;(S)-(+)-onepinic acid;(S)-(+)-KETOPINIC ACID;(1S)-(+)-KETOPINIC ACID;(S)-(+)-KetopinicAcid>(1S)-(+)-Ketopinic acid 99%;(1S)-(+)-KETOPINIC ACID 97+%;(1S,4R)-2-Oxobornane-10-oic acid
CBNumber:
CB0748218
Molecular Formula:
C10H14O3
Molecular Weight:
182.22
MDL Number:
MFCD08061242
MOL File:
40724-67-2.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:36

(S)-(+)-KETOPINIC ACID Properties

Melting point 237-239 °C(lit.)
Boiling point 313.3±25.0 °C(Predicted)
alpha 58 º (C=1 IN CHLOROFORM)
Density 1.238±0.06 g/cm3(Predicted)
refractive index 25.5 ° (C=0.65, MeOH)
storage temp. Sealed in dry,Room Temperature
pka 3.67±0.40(Predicted)
form powder to crystal
color White to Almost white
optical activity [α]23/D +58°, c = 1 in chloroform
BRN 4180005
CAS DataBase Reference 40724-67-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  2918300090
NFPA 704
0
2 0

(S)-(+)-KETOPINIC ACID price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 420964 (1S)-(+)-Ketopinic acid 99% 40724-67-2 1g $77 2024-03-01 Buy
TCI Chemical K0028 (S)-(+)-Ketopinic Acid >98.0%(GC)(T) 40724-67-2 1g $72 2024-03-01 Buy
TCI Chemical K0028 (S)-(+)-Ketopinic Acid >98.0%(GC)(T) 40724-67-2 5g $285 2024-03-01 Buy
TRC D460165 7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylicAcid 40724-67-2 500mg $175 2021-12-16 Buy
Chem-Impex 39504 (S)-(+)-Ketopinicacid,98%(Assaybytitration,GC) 98%(Assaybytitration,GC) 40724-67-2 5G $241.92 2021-12-16 Buy
Product number Packaging Price Buy
420964 1g $77 Buy
K0028 1g $72 Buy
K0028 5g $285 Buy
D460165 500mg $175 Buy
39504 5G $241.92 Buy

(S)-(+)-KETOPINIC ACID Chemical Properties,Uses,Production

Uses

7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.

Uses

7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.

Uses

(1S)-(+)-Ketopinic acid may be used to prepare:

  • Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.
  • A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.
  • A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.

General Description

(1S)-(+)-Ketopinic acid is a chiral ketone.

(S)-(+)-KETOPINIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 154)Suppliers
Supplier Tel Email Country ProdList Advantage
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10828 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Hubei Ipure Biology Co., Ltd
+8613367258412 ada@ipurechemical.com China 10326 58
Shanghai Gubang New Materail Technology Co. LTD
21-51317962 +8618721305404 16728589@qq.com CHINA 272 58
Alfa Chemistry
info@alfa-chemistry.com United States 2344 58
Aston Chemical
13000000000 sales@astonchem.com United States 1634 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
GLR Innovations
+91 9891111994 info@glrgroup.in India 4542 58

View Lastest Price from (S)-(+)-KETOPINIC ACID manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-(+)-KETOPINIC ACID pictures 2021-08-12 (S)-(+)-KETOPINIC ACID
40724-67-2
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(S)-(+)-KETOPINIC ACID pictures 2021-07-02 (S)-(+)-KETOPINIC ACID
40724-67-2
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(S)-(+)-KETOPINIC ACID pictures 2020-01-13 (S)-(+)-KETOPINIC ACID
40724-67-2
US $3.00 / KG 1KG 98% 200KG Career Henan Chemical Co

(S)-(+)-KETOPINIC ACID Spectrum

(1S)-(+)-KETOPINIC ACID (1S)-(+)-KETOPINIC ACID 97+% (1s)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid (S)-7,7-DIMETHYL-2-OXO-BICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID (S)-(+)-KETOPINIC ACID rac-(1S*,4R*)-2-Oxobornane-10-oic acid (1S,4R)-2-Oxobornane-10-oic acid (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]-1-carboxylic acid (4α)-2-Oxo-7,7-dimethylbicyclo[2.2.1]heptane-1β-carboxylic acid Bicyclo[2.2.1]heptane-1-carboxylic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (1S)-(+)-Ketopinic acid,(1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid (1S)-(+)-Ketopinic acid 99% (1S)-7 7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanecarboxylic acid (S)-(+)-KetopinicAcid> (1S,4R)-7,7-dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-methanoic acid (S)-(+)-onepinic acid (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid (+)-Ketopinic acid 40724-67-2 Chiral Building Blocks Carboxylic Acids Terpenes Asymmetric Synthesis Bicyclic Monoterpenes Organic Building Blocks Asymmetric Synthesis Bicyclic Monoterpenes Biochemistry Synthetic Organic Chemistry Terpenes Chiral Reagents