ChemicalBook >> CAS DataBase List >>5-Benzyloxyindole

5-Benzyloxyindole

CAS No.
1215-59-4
Chemical Name:
5-Benzyloxyindole
Synonyms
NSC 62895;bredreck`s;5-Benzyindole;5-BENZYLOXYINDOLE;5-benzyloxy-indol;Benzyloxy-5 indole;BENZYLOXYINDOLE(5-);TIMTEC-BB SBB003331;5-BENZYLOXY-1H-INDOLE;5-Benzyloxyindole,95%
CBNumber:
CB0772987
Molecular Formula:
C15H13NO
Molecular Weight:
223.27
MDL Number:
MFCD00005676
MOL File:
1215-59-4.mol
MSDS File:
SDS
Last updated:2023-04-27 16:27:43

5-Benzyloxyindole Properties

Melting point 100-104 °C (lit.)
Boiling point 364.56°C (rough estimate)
Density 1.0707 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. 2-8°C
solubility ethanol: may be hazy yellow
form powder
pka 16.63±0.30(Predicted)
color white to light yellow
BRN 173532
Exposure limits ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
CAS DataBase Reference 1215-59-4(CAS DataBase Reference)
FDA UNII YCI4Z02E1C
NIST Chemistry Reference 1H-indole, 5-(phenylmethoxy)-(1215-59-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Warning
Hazard statements  H315-H319-H333-H335-H361
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P201-P261-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-24/25-22
WGK Germany  3
RTECS  NL4850000
8-10
HazardClass  IRRITANT
HS Code  29339990
NFPA 704
1
2 0

5-Benzyloxyindole price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B27803 5-(Benzyloxy)indole 95% 1215-59-4 5g $33.7 2024-03-01 Buy
Sigma-Aldrich B27803 5-(Benzyloxy)indole 95% 1215-59-4 25g $90.9 2024-03-01 Buy
TCI Chemical B1833 5-Benzyloxyindole >98.0%(HPLC)(N) 1215-59-4 5g $114 2024-03-01 Buy
Alfa Aesar B25143 5-Benzyloxyindole, 94%, may contain up to ca 7% toluene 1215-59-4 1g $36.5 2024-03-01 Buy
Alfa Aesar B25143 5-Benzyloxyindole, 94%, may contain up to ca 7% toluene 1215-59-4 5g $107 2024-03-01 Buy
Product number Packaging Price Buy
B27803 5g $33.7 Buy
B27803 25g $90.9 Buy
B1833 5g $114 Buy
B25143 1g $36.5 Buy
B25143 5g $107 Buy

5-Benzyloxyindole Chemical Properties,Uses,Production

Chemical Properties

Off-white to beige powder

Uses

5-Benzyloxyindole is used as reagent/reactant in regioselective preparation of CF3-β-tryptamine derivatives via base-free thermal ring-opening reaction of N-nosyl-2-CF3-aziridine with indoles.

Uses

  • Reactant in regio- and stereoselective morpholine-catalyzed direct C-3 alkenylation with α,β-unsaturated aldehydes
  • Reactant in selective debenzylation of protective groups using SiliaCat-palladium under mild reaction conditions
  • Reactant in metal-free Friedel-Crafts alkylation reactions
  • Reactant in preparation of protein kinase (PKC) inhibitors
  • Reactant in preparation of indole/quinoline carbothioic acid amide derivatives

Uses

Reactant in regio- and stereoselective morpholine-catalyzed direct C-3 alkenylation with α,β-unsaturated aldehydes Reactant in selective debenzylation of protective groups using SiliaCat-palladium under mild reaction conditions Reactant in metal-free Friedel-Crafts alkylation reactions Reactant in preparation of protein kinase (PKC) inhibitors Reactant in preparation of indole/quinoline carbothioic acid amide derivatives.

Purification Methods

It is recrystallised from *C6H6/pet ether or pet ether. The picrate forms red crystals from *C6H6 and has m 142-143o. [Burton & Leong Chem Ind (London) 1035 1953, Ek & Witkop J Am Chem Soc 76 5579 1954, fluorescence: Bridges & Williams Biochem J 107 225 1968, Beilstein 27 III/IV 1758.]

153805-85-7
1953-54-4
1215-59-4
Synthesis of 5-Benzyloxyindole from 1-[2-(5-BENZYLOXY-2-NITROPHENYL)VINYL]PYRROLIDINE
Global( 373)Suppliers
Supplier Tel Email Country ProdList Advantage
Dideu Industries Group Limited
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ATK CHEMICAL COMPANY LIMITED
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career henan chemical co
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CONIER CHEM AND PHARMA LIMITED
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SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58

View Lastest Price from 5-Benzyloxyindole manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
 5-Benzyloxyindole  pictures 2023-07-27 5-Benzyloxyindole
1215-59-4
US $1.50 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
5-Benzyloxyindole pictures 2022-12-28 5-Benzyloxyindole
1215-59-4
US $24.00 / kg 1kg 99% 1000kg Hebei Duling International Trade Co. LTD
5-Benzyloxyindole pictures 2021-09-19 5-Benzyloxyindole
1215-59-4
US $1.10 / g 1g 99.00% 100 Tons min Dideu Industries Group Limited
BENZYLOXYINDOLE(5-) 5-(Phenylmethoxy)-1H-indole 5-benzyloxy-indol Benzyloxy-5 indole Indole, 5-(benzyloxy)- TIMTEC-BB SBB003331 5-BENZYLOXY-1H-INDOLE 5-BENZYLOXYINDOLE 5-BENZYLOXYINDOLE CRYSTALLINE 5-BENZYLOXYINDOLE: 94%, MAY CONTAIN UP TO CA 7% TOLUENE bis-hydroxyethyl-p-aniline sulphate bredreck`s 5-(Phenylmethoxy)indole 5-Benzyloxyindole ,98% 5-Benzyloxyindole (contains ca. 5% Toluene and Ethanol) 5-Benzyloxyindole,95% 5-Benzyloxyindole, 95% 5GR 1H-Indole, 5-(phenylmethoxy)- 5-Benzyloxyindole, May Contain up to ca 7% Toluene Benzyl 1H-Indol-5-yl Ether NSC 62895 5-Benzyindole 5-Benzyloxyindole in stock Factory 5-Benzyloxyindole > Hydrogenated(stearic acid)Phosphatidylcholine 1215-59-4 Indoles Simple Indoles Building Blocks Heterocyclic Building Blocks Heterocycle-Indole series Aromatics Indole Derivatives Simple Indoles Indole Pyrroles & Indoles Building Blocks Heterocyclic Building Blocks Indoles Indoles and derivatives Pyrroles & Indoles Indoline & Oxindole Indole Series blocks IndolesOxindoles