ChemicalBook >> CAS DataBase List >>Dess-Martin periodinane
Dess-Martin periodinane
- CAS No.
- 87413-09-0
- Chemical Name:
- Dess-Martin periodinane
- Synonyms
- DESS-MARTIN;Dess-Martin periodane;DESS-MARTIN REAGENT;PERIODINANE;DESS-MARTINE;1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE;Dess-Martin periodinane,D M P, TAPI;3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate;1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE;Martin's reagent
- CBNumber:
- CB0776475
- Molecular Formula:
- C13H13IO8
- Molecular Weight:
- 424.14
- MDL Number:
- MFCD00130127
- MOL File:
- 87413-09-0.mol
- MSDS File:
- SDS
Last updated:2024-04-03 13:17:41
| Melting point | 130-133 °C (lit.) |
|---|---|
| Boiling point | 40 °C |
| Density | 1.369 g/mL at 25 °C |
| Flash point | >221 °F |
| storage temp. | -20°C |
| solubility | Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane. |
| form | Liquid |
| color | Colorless to light yellow |
| Sensitive | Light Sensitive |
| Merck | 14,2933 |
| BRN | 4548207 |
| Stability | Light Sensitive |
| InChI | InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3 |
| InChIKey | NKLCNNUWBJBICK-UHFFFAOYSA-N |
| SMILES | I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2 |
| CAS DataBase Reference | 87413-09-0(CAS DataBase Reference) |
| FDA UNII | 336B74JK56 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS03,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H272-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P220-P261-P264-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,O,Xi | |||||||||
| Risk Statements | 22-36/37/38-40-8-20/21/22-44 | |||||||||
| Safety Statements | 26-36-36/37-24/25-23-17-45-36/37/39 | |||||||||
| RIDADR | UN 1593 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Harmful/Light sensitive | |||||||||
| TSCA | No | |||||||||
| HazardClass | 5.1 | |||||||||
| PackingGroup | Ⅲ | |||||||||
| HS Code | 29349990 | |||||||||
| NFPA 704 |
|
Dess-Martin periodinane price More Price(60)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 274623 | Dess-Martin periodinane 97% | 87413-09-0 | 5g | $136 | 2024-03-01 | Buy |
| Sigma-Aldrich | 274623 | Dess-Martin periodinane 97% | 87413-09-0 | 25g | $648 | 2024-03-01 | Buy |
| TCI Chemical | D2045 | Dess-Martin Periodinane >95.0%(T) | 87413-09-0 | 1g | $35 | 2024-03-01 | Buy |
| TCI Chemical | D2045 | Dess-Martin Periodinane >95.0%(T) | 87413-09-0 | 5g | $106 | 2024-03-01 | Buy |
| Alfa Aesar | L15779 | Dess-Martin periodinane | 87413-09-0 | 1g | $39.3 | 2024-03-01 | Buy |
Dess-Martin periodinane Chemical Properties,Uses,Production
Description
Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.
Chemical Properties
White Crystalline powder
Uses
Oxidizing reagent.
Uses
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
Uses
Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.
Advantages
Benefits of using Dess-Martin periodinane (DMP) as an oxidizing reagent:
milder reaction conditions (room temperature, neutral pH)
shorter reaction times and higher yields
high chemoselectivity
tolerance of sensitive functional groups, and a long shelf life
simplified workups
Dess-Martin periodinane Preparation Products And Raw materials
Global( 578)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hunan aslsen technology co.,ltd | +8615308460054 | aslsc@aslsen.com | China | 124 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9352 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| Zjartschem | +86-571-8723 8903 jocelynpan@zjarts.com | jocelynpan@zjarts.com | CHINA | 993 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
View Lastest Price from Dess-Martin periodinane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-10 | 2-benziodoxol-(1H)-one
87413-09-0
|
US $10.00 / kg | 1kg | 99.99% | 1000000000 ton | Hunan aslsen technology co.,ltd | |
 |
2024-01-30 | Dess-Martin periodinane
87413-09-0
|
US $1.00 / g | 1g | 99% | 10 tons | ANHUI WITOP BIOTECH CO., LTD | |
 |
2022-07-25 | Dess-Martin periodinane
87413-09-0
|
US $1.10 / g | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited |
-
- 2-benziodoxol-(1H)-one
87413-09-0
- US $10.00 / kg
- 99.99%
- Hunan aslsen technology co.,ltd
-
- Dess-Martin periodinane
87413-09-0
- US $1.00 / g
- 99%
- ANHUI WITOP BIOTECH CO., LTD
-
- Dess-Martin periodinane
87413-09-0
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
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Dess-MartinPeriodinane>
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Dess-Martin periodinane,D M P, TAPI
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Martin's reagent
DESS-MARTIN
DESS-MARTIN REAGENT
1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE
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Dess-Martin periodane
3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate
DesmartinPeriodinane
DESS-MARTINE