(4-Methoxyphenyl)dimethylsilanol

CAS No.
22868-26-4
Chemical Name:
(4-Methoxyphenyl)dimethylsilanol
Synonyms
(4-METHOXYPHENYL)DIMETHYLSILANOL;(4-Methoxyphenyl)dimethylsilanol 96%;Silanol, 1-(4-methoxyphenyl)-1,1-dimethyl-
CBNumber:
CB0972859
Molecular Formula:
C9H14O2Si
Molecular Weight:
182.29
MDL Number:
MFCD08276887
MOL File:
22868-26-4.mol

(4-Methoxyphenyl)dimethylsilanol Properties

Boiling point 82 °C(Press: 0.004 Torr)
Density 1.101 g/mL at 25 °C
refractive index n 20/D 1.522
Flash point 110 °C
storage temp. 2-8°C
pka 14.49±0.53(Predicted)

SAFETY

Risk and Safety Statements

WGK Germany  3

(4-Methoxyphenyl)dimethylsilanol price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 667951 (4-Methoxyphenyl)dimethylsilanol 96% 22868-26-4 1g $138 2023-06-20 Buy
Sigma-Aldrich 667951 (4-Methoxyphenyl)dimethylsilanol 96% 22868-26-4 5g $548 2023-01-07 Buy
TRC D494860 Dimethyl(4-methoxyphenyl)silanol 22868-26-4 100mg $60 2021-12-16 Buy
American Custom Chemicals Corporation ORS0000812 (4-METHOXYPHENYL)DIMETHYLSILANOL 95.00% 22868-26-4 1G $718.8 2021-12-16 Buy
Biosynth Carbosynth FD39976 DiMethyl(4-Methoxyphenyl)silanol 22868-26-4 5G $788 2021-12-16 Buy
Product number Packaging Price Buy
667951 1g $138 Buy
667951 5g $548 Buy
D494860 100mg $60 Buy
ORS0000812 1G $718.8 Buy
FD39976 5G $788 Buy

(4-Methoxyphenyl)dimethylsilanol Chemical Properties,Uses,Production

Uses

(4-Methoxyphenyl)dimethylsilanol can be used:

  • As a starting material in the Pd-catalyzed cross-coupling reactions with various aryl halides to obtain biaryl compounds using Cs2CO3 base.
  • As a starting material to prepare potassium (4-methoxyphenyl)dimethylsilanolate, which in turn is used to synthesize biaryl derivatives by reacting with aryl bromides.
  • As a co-catalyst along with Mo(CO)6 applicable in the 4-decyne metathesis.

Uses

(4-Methoxyphenyl)dimethylsilanol is a useful silicon nucleophile for Pd-catalyzed cross-coupling.

(4-Methoxyphenyl)dimethylsilanol Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 13)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52927 58
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42959 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Meng Cheng Technology (Shanghai) Co., LTD 400-820-6829 sales@mitachieve.com China 8864 58
Energy Chemical 021-58432009 400-005-6266 marketing1@energy-chemical.com China 44843 58
Zhuhai Aobokai Biomedical Technology Co., Ltd. 400-0628126 15976997964; sales-team@aobchem.com.cn China 50497 58
Shanghai Aladdin Biochemical Technology Co.,Ltd. +86-18521732826 market@aladdin-e.com China 48465 58
Baoji Didu Pharmaceutical and Chemical Co., Ltd 029-81148929 13186179623 1049@dideu.com China 10011 58
Carbosynth -- sales@carbosynth.com United Kingdom 6018 58
(4-METHOXYPHENYL)DIMETHYLSILANOL Silanol, 1-(4-methoxyphenyl)-1,1-dimethyl- (4-Methoxyphenyl)dimethylsilanol 96% 22868-26-4 CH3OC6H4SiCH32OH Chemical Synthesis Organometallic Reagents Organosilicon Silanols