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ChemicalBook >> CAS DataBase List >>Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Structure
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) structure
CAS No.
346457-41-8
Chemical Name:
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms
(R)-Ru(OAc)2(BINAP);(R)-[(RUCL(SEGPHOS)2(Μ-CL)3[NH2ME2];NH2ME2][(RUCL((R)-SEGPHOS))2(U-CL)3;(R)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2];[NH2ME2][(RUCL((R)-SEGPHOS))2(Μ-CL)3];(R)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2];[NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3];(R)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2];[NH2Me2][(RuCl((R)-segphos(regR)))2(mu-Cl)3];-bi-1,3-benzodioxole]diruthenate(II),[NH2Me2][
CBNumber:
CB11181057
Molecular Formula:
2C38H28O4P2.C2H7N.Cl.Cl3Ru2.ClH
Molecular Weight:
1646.66
MDL Number:
MFCD09753037
MOL File:
346457-41-8.mol
Last updated:2023-06-08 17:06:34
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Properties

Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color light brown
Sensitive air sensitive
CAS DataBase Reference 346457-41-8

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS08
Signal word  Danger
Hazard statements  H371-H373-H360
Precautionary statements  P260-P264-P270-P309+P311-P405-P501-P260-P314-P501
WGK Germany  3
HS Code  2843.90.0000

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692204 (R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] 346457-41-8 50mg $32.8 2024-03-01 Buy
Sigma-Aldrich 692204 (R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] 346457-41-8 100mg $54.9 2023-06-20 Buy
TCI Chemical N1021 [NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3] 346457-41-8 200mg $52 2024-03-01 Buy
TCI Chemical N1021 [NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3] 346457-41-8 1g $162 2024-03-01 Buy
Strem Chemicals 44-0518 Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos(R))}2(μ-Cl)3] 346457-41-8 250mg $53 2024-03-01 Buy
Product number Packaging Price Buy
692204 50mg $32.8 Buy
692204 100mg $54.9 Buy
N1021 200mg $52 Buy
N1021 1g $162 Buy
44-0518 250mg $53 Buy

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties,Uses,Production

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

General Description

(R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS?, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Suppliers

Global( 31)Suppliers
Supplier Tel Email Country ProdList Advantage
Alfa Chemistry 		+1-5166625404 Info@alfa-chemistry.com United States 21317 58
Hangzhou MolCore BioPharmatech Co.,Ltd. 		+86-057181025280; +8617767106207 sales@molcore.com China 49739 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340 307593986@qq.com China 475 58
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28398 80
TCI Europe 320-37350700 sales@tcieurope.eu Europe 23680 75
TCI AMERICA 800-4238616 sales@tciamerica.com Americas 23662 75
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Supplier Advantage
Alfa Chemistry 		58
Hangzhou MolCore BioPharmatech Co.,Ltd. 		58
J & K SCIENTIFIC LTD. 76
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Shanghai Incat Chemtech Co.,Ltd. 58
TOKYO CHEMICAL INDUSTRY CO., LTD. 80
TCI Europe 75
TCI AMERICA 75
Sigma-Aldrich 80

346457-41-8(Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II))Related Search:

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　
Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　 Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Tris(triphenylphosphine)ruthenium(II) chloride
(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
RUTHENIUM(III) CHLORIDE TRIHYDRATE Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole]diruthenate(II)

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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) (R)-Ru(OAc)2(BINAP) Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos)}2(Cl)3] (R)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2] (R)-[(RUCL(SEGPHOS)2(Μ-CL)3[NH2ME2] [NH2Me2][(RuCl((R)-segphos(regR)))2(mu-Cl)3] (R)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2] [NH2ME2][(RUCL((R)-SEGPHOS))2(Μ-CL)3] (R)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2] Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II) -bi-1,3-benzodioxole]diruthenate(II),[NH2Me2][ DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]DIRUTHENATE(II),[NH2ME2][ Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos(R))}2(μ-Cl)3] [NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3] NH2ME2][(RUCL((R)-SEGPHOS))2(U-CL)3 346457-41-8 C76H56Cl5O8P4Ru2C2H7NH C48H38O4P2Ru CH32NH2C76H56Cl5O8P4Ru2 C78H55Cl5NO8P4Ru2 C78H64Cl5NO8P4Ru2 C78H64Cl5O8P4Ru2N Ru