Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Structure
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) structure
CAS No.
142962-95-6
Chemical Name:
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
Synonyms
Ru(OAc)2[(S)-H8-binap];(S)-Ru(OAc)2(H8-BINAP);Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II);Diacetato[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II);Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II),95%;Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]rutheniuM(II) Ru(OAc)2[(S)-H8-binap];Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]　
CBNumber:
CB11181062
Molecular Formula:
C44H40P2.C4H6O4Ru
Molecular Weight:
849.905
MDL Number:
MFCD09753023
MOL File:
142962-95-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
Request For Quotation

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Properties

Melting point >100°C
storage temp. 2-8°C
solubility Chloroform
form solid
color yellow to dark brown
Sensitive air sensitive
CAS DataBase Reference 142962-95-6

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335
Precautionary statements  P261-P264-P271-P280-P304+P340+P312-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37
Safety Statements  26
WGK Germany  3

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 693278 (S)-Ru(OAc)2(H8-BINAP) 142962-95-6 50mg $98 2023-06-20 Buy
Sigma-Aldrich 693278 (S)-Ru(OAc)2(H8-BINAP) 142962-95-6 100mg $186 2023-06-20 Buy
Strem Chemicals 44-0167 Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap] 142962-95-6 50mg $83 2024-03-01 Buy
Strem Chemicals 44-0167 Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap] 142962-95-6 250mg $332 2024-03-01 Buy
TRC R701610 (S)-Ru(OAc)2(H8-BINAP) 142962-95-6 25mg $140 2021-12-16 Buy
Product number Packaging Price Buy
693278 50mg $98 Buy
693278 100mg $186 Buy
44-0167 50mg $83 Buy
44-0167 250mg $332 Buy
R701610 25mg $140 Buy

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Chemical Properties,Uses,Production

Reaction

  1. Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
  2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
Reactions of 142962-95-6

Uses

(S)-Ru(OAc)2(H8-BINAP) is a reagent used in the synthesis of optically active carboxylic acids.

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) Suppliers

Global( 29)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
changzhou huayang technology co., ltd 		+8615250961469 2571773637@qq.com China 9821 58
Alfa Chemistry 		+1-5166625404 Info@alfa-chemistry.com United States 21317 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340 307593986@qq.com China 475 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-0371-65511006 18625597674 sales@kingorgchem.com China 950 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Shandong Ono Chemical Co., Ltd. 0539-6362799 20） China 9998 58
Supplier Advantage
career henan chemical co 		58
Chongqing Chemdad Co., Ltd 		58
changzhou huayang technology co., ltd 		58
Alfa Chemistry 		58
J & K SCIENTIFIC LTD. 76
Shanghai Incat Chemtech Co.,Ltd. 58
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
LaaJoo 58
Shandong Ono Chemical Co., Ltd. 58

View Lastest Price from Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) pictures 2019-08-09 Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
142962-95-6
 US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co

142962-95-6(Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II))Related Search:

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) (R)-H8-BINAP
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) (S)-Ru(OAc)2(H8-BINAP) Diacetato[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II) Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]　 Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]rutheniuM(II) Ru(OAc)2[(S)-H8-binap] Ru(OAc)2[(S)-H8-binap] Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II),95% 142962-95-6 Ru