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3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE

CAS No.
38002-45-8
Chemical Name:
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
Synonyms
(3-BroMoprop-1-yn-1-yl)triMethylsilane;)-1-propyne;(3-Bromo-1-pr;3-Bromo-1-(trimethyL;(3-BROMO-1-PROPYNYL)TRIMETHYLSILANE;3-(TRIMETHYLSILYL)PROPARGYL BROMIDE;3-(trimethylsilyl)-propagyl bromide;3-bromoprop-1-ynyl(trimethyl)silane;3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE;3-Bromo-1-(trimethulsilyl)-1-propyne
CBNumber:
CB1151699
Molecular Formula:
C6H11BrSi
Molecular Weight:
191.14
MDL Number:
MFCD00134460
MOL File:
38002-45-8.mol
MSDS File:
SDS
Last updated:2023-08-16 18:05:29

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Properties

Melting point <0°C
Boiling point 44-45 °C2 mm Hg(lit.)
Density 1.17 g/mL at 25 °C(lit.)
refractive index n20/D 1.483(lit.)
Flash point 145 °F
storage temp. 2-8°C
solubility Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form Oil
color Colourless to Pale Yellow
Specific Gravity 1.351
Water Solubility Immiscible with water.
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 2037650
Stability Hygroscopic
InChIKey GAPRPFRDVCCCHR-UHFFFAOYSA-N
CAS DataBase Reference 38002-45-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-28-36/37/39
RIDADR  UN 3334
WGK Germany  3
8-9-19
TSCA  No
HS Code  29319090
NFPA 704
2
2 1

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 377775 3-Bromo-1-(trimethylsilyl)-1-propyne 98% 38002-45-8 1g $50.9 2024-03-01 Buy
Sigma-Aldrich 377775 3-Bromo-1-(trimethylsilyl)-1-propyne 98% 38002-45-8 10g $297 2024-03-01 Buy
TCI Chemical B1654 3-Bromo-1-(trimethylsilyl)-1-propyne >97.0%(GC) 38002-45-8 1g $34 2024-03-01 Buy
TCI Chemical B1654 3-Bromo-1-(trimethylsilyl)-1-propyne >97.0%(GC) 38002-45-8 5g $99 2024-03-01 Buy
Alfa Aesar H53451 3-Bromo-1-trimethylsilyl-1-propyne, 98% 38002-45-8 5g $97.9 2024-03-01 Buy
Product number Packaging Price Buy
377775 1g $50.9 Buy
377775 10g $297 Buy
B1654 1g $34 Buy
B1654 5g $99 Buy
H53451 5g $97.9 Buy

3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to pale yellow liquid

Uses

3-Bromo-1-(trimethylsilyl)-1-propyne may be used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It may be used as reagent for the alkylation of dianion of β-keto esters at γ-carbon. It may be employed in the preparation of terminal conjugated enynes and allenic alcohols.

General Description

3-Bromo-1-(trimethylsilyl)-1-propyne is reported as a propargylating agent. Selective reaction of 3-bromo-1-(trimethylsilyl)-1-propyne with α-keto ester using indium metal has been studied.

5272-36-6
38002-45-8
Synthesis of 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE from 3-TRIMETHYLSILYL-2-PROPYN-1-OL
Global( 197)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12453 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15371 58
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9352 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58

View Lastest Price from 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE pictures 2023-08-16 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
38002-45-8
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE pictures 2022-12-26 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
38002-45-8
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Guanlang Biotechnology Co., Ltd.
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE pictures 2022-09-17 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE
38002-45-8
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE 98% 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE, 98 % 3-(TRIMETHYLSILYL)PROPARGYL BROMIDE 97+% 3-(Trimethylsilyl)propargyl bromide, 3-Bromo-1-(trimethylsilyl)-1-propyne (3-BROMO-1-PROPYNYL)TRIMETHYLSILANE 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE (3-Bromo-1-propyn-1-yl)trimethyl-silane 3-(TRIMETHYLSILYL)PROPARGYL BROMIDE 3-Bromo-1-(trimethyL 3-Bromo-1-(trimethylsilyl)-1-propyne > Silane, (3-bromo-1-propyn-1-yl)trimethyl- )-1-propyne (3-Bromo-1-pr 3-bromo-1-trimethylsilyl-1-propargyne 3-Bromo-1-(trimethulsilyl)-1-propyne 3-(trimethylsilyl)-propagyl bromide 3-bromoprop-1-ynyl(trimethyl)silane silane, (3-bromo-1-propynyl)trimethyl- 3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97%3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97%3-BROMO-1-TRIMETHYLSILYL-1-PROPYNE, 97% (3-BroMoprop-1-yn-1-yl)triMethylsilane 3-Bromo-1-(Trimethylsilyl)-1-Propyne,95% 38002-45-8 BrCH2CCSiCH33 C6H11BrSi BrCH2C8801CSiCH33 Building Blocks Alkynes Organic Building Blocks Internal Acetylenes Si-(C)4 Compounds Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Functionalized Acetylenes Ethynylsilanes Acetylenes Ethynylsilanes Functionalized Acetylenes Si (Classes of Silicon Compounds) Si-(C)4 Compounds Silicon Compounds (for Synthesis) Synthetic Organic Chemistry