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Boron trifluoride-methanol solution

CAS No.
373-57-9
Chemical Name:
Boron trifluoride-methanol solution
Synonyms
trifluoride;BF3/METHANOL;uoride methanoL;14% in methanol;150g/L in methanol;BORON FLUORIDE-METHANOL;trifluoro(methanol)boron;BORON TRIFLUORIDE-METHANOL;Boron trifluoride solution;Boron Trifluoride in Methanol
CBNumber:
CB1184013
Molecular Formula:
CH3BF3O
Molecular Weight:
98.84
MDL Number:
MFCD00071635
MOL File:
373-57-9.mol
Last updated:2023-06-08 17:06:37

Boron trifluoride-methanol solution Properties

Melting point -93℃ (Methanol)
Boiling point 59 °C4 mm Hg
Density 1.203 g/mL at 25 °C
vapor pressure 19.5 mm Hg ( 20 °C)
refractive index n20/D 1.328
Flash point 52 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light yellow
Specific Gravity 0.890 (20/4℃)
Merck 14,1349
BRN 3611499
InChIKey FQZVTMBNNNQKJY-UHFFFAOYSA-N
CAS DataBase Reference 373-57-9
EPA Substance Registry System Boron, trifluoro(methanol)-, (T-4)- (373-57-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H225-H301+H311-H314-H330-H335-H370-H373
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T,C,T+,F
Risk Statements  20/22-34-48/23-39/23/24/25-35-26-24/25-11-14-23/24/25
Safety Statements  26-28-36/37/39-45-23-16
RIDADR  UN 3286 3/PG 2
WGK Germany  3
RTECS  ED2275000
21
Autoignition Temperature 788 °F
HazardClass  8
PackingGroup  I
HS Code  28129019
NFPA 704
3
3 0

Boron trifluoride-methanol solution price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 134821 Boron trifluoride-methanol solution 50% w/w in methanol 373-57-9 4x25ml $125.4 2024-03-01 Buy
Sigma-Aldrich 134821 Boron trifluoride-methanol solution 50% w/w in methanol 373-57-9 1l $420 2024-03-01 Buy
TCI Chemical X0036 Boron Trifluoride - Methanol Reagent (10-20%) [for Esterification] (1mL×10) 373-57-9 1set $97 2024-03-01 Buy
Sigma-Aldrich B1252 Boron trifluoride-methanol solution 14% in methanol 373-57-9 5ml $62.4 2024-03-01 Buy
Sigma-Aldrich B1252 Boron trifluoride-methanol solution 14% in methanol 373-57-9 100ml $76 2024-03-01 Buy
Product number Packaging Price Buy
134821 4x25ml $125.4 Buy
134821 1l $420 Buy
X0036 1set $97 Buy
B1252 5ml $62.4 Buy
B1252 100ml $76 Buy

Boron trifluoride-methanol solution Chemical Properties,Uses,Production

Chemical Properties

Boron trifluoride etherates: (compounded with methyl ether) is moisture-sensitive, corrosive, flammable liquid.

Chemical Properties

colorless to amber solution

Uses

It was used in transmethylation of 1,2-Diacylglycerol (DAG) containing fractions which were purified using HPLC. It may be used to treat lipids during GC analysis done for determination of fatty acid methyl esters and dimethylacetals.

Uses

Reagent for the GC analysis of ritalinic acid. Alternative to Cl2CHCO2H for synthesis of purine rich oligomers.
Lewis acid used in the preparation of geminal bis-peroxides from ketals and enol ethers with t-butyl hydroperoxide. Reagent used for the mild deacetylation of amines.

Uses

Trifluoro(methanol)boron is a reagent used for the GC analysis of ritalinic acid.

General Description

Boron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.

Potential Exposure

Used as a catalyst.

Shipping

Diethyl: UN2604 Boron trifluoride diethyl etherate, Hazard class: 8; Labels: 8—Corrosive material, 3—Flammable liquid. Dimethyl: UN2965 Boron trifluoride dimethyl etherate, Hazard class: 4.3; Labels: 4.3— Dangerous when wet, 8—Corrosive material, 3— Flammable liquid.

Incompatibilities

Reacts with air forming corrosive hydrogen fluoride vapors. Incompatible with oxidizers (may cause fire and explosion), water, steam or heat, forming corrosive and flammable vapors. Peroxide containing etherate reacts explosively with aluminum lithium hydride, magnesium tetrahydroaluminate. Mixtures with phenol react explosively with 1,3-butadiene. Presumed to form explosive peroxides.

Boron trifluoride-methanol solution Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 140)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17368 58
Hubei Ipure Biology Co., Ltd
+8613367258412 ada@ipurechemical.com China 10326 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
HONG KONG IPURE BIOLOGY CO.,LIMITED
86 18062405514 18062405514 ada@ipurechemical.com CHINA 3465 58
LUYUNJIA CHEMISTRY XIAMEN LIMITED
+86-592-5360779 +86-13055435203 China 5996 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259 cherry@crovellbio.com China 18459 58

View Lastest Price from Boron trifluoride-methanol solution manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Trifluoro(methanol)boron pictures 2020-03-08 Trifluoro(methanol)boron
373-57-9
US $3.00 / KG 1KG 99%min 200kg Career Henan Chemical Co

Boron trifluoride-methanol solution Spectrum

Boron Trifluoride in Methanol Boron Trifluoride, 50-55wt.% in Methanol Boron trifluoride-Methanol solution,50-55% Boron trifluoride, 12% (1.5M) in Methanol Boron trifluoride, 12% (1.5M) in Methanol, AcroSeal Boron trifluoride Methanol, 50 wt.% solution in MeOH BF3/METHANOL BORON TRIFLUORIDE-METHANOL BORON TRIFLUORIDE, METHANOL REAGENT 15 Boron Trifluoride 14 Percent in Methanol Boron trifluoride-Methanol solution 14% in Methanol Boron trifluoride-Methanol solution 50% w/w in Methanol Boron trifluoride Methanol, 50 wt.% solution in MeOH, Hyseal Boron Trifluoride - Methanol Reagent (10-20%) Boron Trifluoride Methanol, 50-55wt.% in Methanol BORON FLUORIDE-METHANOL BORN TRIFLUORIDE-METHANOL COMPLEX Boron trifluoride methanol solution Boron trifluoride solution trifluoro(methanol)boron BORON TRIFLUORIDE-METHANOL COMPLEX, IN E XCESS METHANOL (CA. 12 WT. % BF3) BORON TRIFLUORIDE-METHANOL SEALED AMPULES BORON TRIFLUORIDE-METHANOL COMPLEX, IN E XCESS METHANOL (CA. 50 WT. % BF3) BORON TRIFLUORIDE-METHANOL 50% BF310%,13-15%or20%solutioninmethanol Boron Trifluoride - Methanol Reagent (10-20%) [for Esterification] (1ml*10) BORON TRIFLUORIDE METHANOL COMPLEX METHANOL SOLUTION Boron, trifluoro(methanol)-, (T-4)- BORONTRIFLUORIDE50%INMETHANOL uoride methanoL Boron Trifluoride Dimethanol Complex, 50 - 52 wt.% 14% in methanol Boron Trifluoride in Methanol (14%) Solution Boron trifluoride-methanol solution, 15% in methanol trifluoride 150g/L in methanol 373-57-9 73-57-9 CH4BF3O BF3CH3OH BF3MeOH Synthetic Reagents Lewis Acids BCl3, BF3, HCl-Alkanol Solutions (GC Derivatizing Reagents) Boron Trifluorides Boron Trihalides GC Derivatizing Reagents B (Classes of Boron Compounds) Esterification & Alkylation (GC Derivatizing Reagents) Alkylation Acylation Chemical Synthesis Fluorides Analytical Chemistry BCl3, BF3, HCl-Alkanol Solutions (GC Derivatizing Reagents) Esterification & Alkylation (GC Derivatizing Reagents) GC Derivatizing Reagents Reagents for Alkylation&Esterification