Guanidine carbonate
- CAS No.
- 593-85-1
- Chemical Name:
- Guanidine carbonate
- Synonyms
- GUANIDINIUM CARBONATE;Guanidonium-carbonat;Guanidinecarbonate,98%;DIGUANIDINIUM CARBONATE;GUANIDINE CARBONATE SALT;ai3-14631;C2H10N6H2CO3;Carbonate pus;GUANIDINE CARBONAT;Iminoureacarbonate
- CBNumber:
- CB1200944
- Molecular Formula:
- C2H7N3O3
- Molecular Weight:
- 121.1
- MDL Number:
- MFCD00013029
- MOL File:
- 593-85-1.mol
- MSDS File:
- SDS
| Melting point | >300 °C(lit.) |
|---|---|
| Density | 1.25 |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Store below +30°C. |
| solubility | 450g/l |
| form | Crystalline Powder |
| pka | 12.5[at 20 ℃] |
| color | White to almost white |
| PH | 11.7 (110g/l, H2O, 20℃) |
| Water Solubility | 450 g/L (20 ºC) |
| BRN | 3628359 |
| InChIKey | KMSRVXJGTIRNNK-UHFFFAOYSA-N |
| LogP | -1.63 at 20℃ |
| CAS DataBase Reference | 593-85-1(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | V3394X3G2W |
| NIST Chemistry Reference | Guanidine carbonate(593-85-1) |
| EPA Substance Registry System | Guanidine carbonate (2:1) (593-85-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H318 | |||||||||
| Precautionary statements | P264-P270-P280-P301+P312-P305+P351+P338-P501 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-36/37/38-20/21/22 | |||||||||
| Safety Statements | 26-36-22 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | FG1750000 | |||||||||
| Autoignition Temperature | 530 °C | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29252000 | |||||||||
| Toxicity | LD50 orally in Rabbit: 1045 mg/kg | |||||||||
| NFPA 704 |
|
Guanidine carbonate price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | G11659 | Guanidine carbonate salt 99% | 593-85-1 | 5g | $84.7 | 2024-03-01 | Buy |
| Sigma-Aldrich | G11659 | Guanidine carbonate salt 99% | 593-85-1 | 1kg | $114 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.20611 | Guanidinium carbonate for synthesis | 593-85-1 | 100g | $53.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.20611 | Guanidinium carbonate for synthesis | 593-85-1 | 1kg | $106 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.20611 | Guanidinium carbonate for synthesis | 593-85-1 | 50kg | $1450 | 2024-03-01 | Buy |
Guanidine carbonate Chemical Properties,Uses,Production
High purity Guanidine carbonate synthesis method
Guanidine carbonate is an extremely versatile organic chemical products, it is mainly used in flame retardants, flocculants, foaming agents, synthetic sulfa drugs, etc. Guanidine carbonate is also used as synthetic detergent builders, high-quality cosmetics raw materials.Synthesis of guanidine carbonate is reported by many literatures [1-3] .The main domestic guanidine carbonate production is that molt dicyandiamide and ammonium chloride to generate guanidine hydrochloride, generate free guanidine under the action of the alkali, and then by the reaction of free guanidine and carbon dioxide to produce guanidine carbonate. this route is easy to generate melamine and its dimers, trimers and other impurities because of the high-temperature melting , and the presence of Cl-, Na + in the system is difficult to completely removed , even if the purity is> 99% of guanidine carbonate, its ash content is still up 0.2%, it is difficult to obtain high purity guanidine carbonate. in this paper, cyanamide as raw materials, reacts with carbon dioxide and ammonia in one step synthesis of guanidine carbonate, also known as ash-free guanidine carbonate, and then purify , to obtain a high purity guanidine carbonate, the reaction equation is as follows: 2NH2CN + CO2 + 2NH3 + H20 → [NH2C (: NH) NH2] 2H2CO3
Author: Zhouzhao Liang Xie Jianwei Zhou Xiaohong Jiang Yongqing
Author: Zhouzhao Liang, Xie Jianwei (Research Institute of Zhejiang University of West Branch Quzhou 324006)
Zhou Xiaohong, Jiang Yongqing (Institute of Fine Chemicals Group Technology Center Juhua Quzhou 324004)
Reference quality standards
[Industry Grade ] Name of Item Technical index
Premium grade B product
Appearance white crystalline white powder
Content of ≥ 99% 98%
Ammonium ≤ 0.45% 1.0%
Water insoluble matter ≤ 0.2% 0.2%
Moisture ≤ 0.2% 0.2%
Ash ≤ 0.15% 0.2%
Water-soluble test Qualified Qualified
PH value (4% 25 ℃) 11.4 11.4
[Pharmaceutical Grade ]
Name of Item Technical index
Premium grade
Appearance white crystals
Content ≥ 99%
Ammonium salt (with NH4Cl meter) ≤ 0.45%
Water insoluble matter ≤ 0.2%
Moisture ≤ 0.2%
Ash ≤ 0.1%
Water-soluble test Qualified
PH value (4% 25 ℃) 11.4
Heavy Metal ppm ≤10
Arsenic ppm ≤3
The above information is edited by the Chemicalbook of Tian Ye.
Chemical Properties
white to almost white crystalline powder. Soluble in water, slightly soluble in methanol, almost insoluble in acetone, benzene and ether.
Uses
Guanidine Carbonate is used in the cytidine triphosphate injection stabilization. It also acts as a powerful and versatile protein denaturants.
As a strong chemical base, guanidine carbonate is used as an intermediary in a variety of applications:
Organic synthesis materials and analytical reagents.
pH adjusting agents for amino resins, antioxidants, resin stabilizer and guanidine soap, also a grout agent, cement additives, surfactants.
In terms of synthetic detergent,it is used as a moisture agent and a synergist.
For Zinc, cadmium, manganese weight measurement, it is used as a precipitating agent, it is also used in the separation of alkali metal magnesium.
Uses
Guanidine Carbonate is a strong organic alkali. It is used to adjust the pH of a formulation, organic intermediate, soap and cosmetic products.
Application
Guanidine carbonate salt can be used as a reactant for the synthesis of:
An oxidizer, guanidinium dinitramide (GDN), by reacting with ammonium dinitramide.
Guanidinium cyclopropanecarboxylate by reacting with cyclopropanecarboxylic acid.
Preparation
Synthesis of guanidine carbonate: Melt double cyanide salts and ammonia to generate guanidine salts (guanidine hydrochloride, guanidine nitrate) at 170-230 ℃ . Then make guanidine salt into an alcohol solution, add soda to free guanidine, absorb carbon dioxide to obtain guanidine carbonate.
Hazard
Toxic by ingestion.
Flammability and Explosibility
Non flammable
Purification Methods
Crystallise it from MeOH. [Beilstein 3 H 86, 3 I 41, 3 II 72, 3 III 161, 3 IV 152.]
Guanidine carbonate Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| hebei hongtan Biotechnology Co., Ltd | +86-86-1913198-3935 +8617331935328 | sales03@chemcn.cn | China | 951 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15371 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9352 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| Shanxi Naipu Import and Export Co.,Ltd | +86-13734021967 +8613734021967 | kaia@neputrading.com | China | 1011 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Related articles
- Exploring the Uses and Safety Considerations of Guanidine Carbonate
- Guanidine carbonate has versatile applications due to its strong organic alkali properties, but requires careful handling due ....
- Jan 12，2024
- Preparation and Application of the Guanidine Carbonate
- Guanidine carbonate, also known as carbonic acid aminourea. It can be dissolved in water and slightly dissolved in ethanol and....
- Feb 14，2023
View Lastest Price from Guanidine carbonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-12 | Guanidine carbonate
593-85-1
|
US $25.00 / kg | 1kg | 99% | 1000kg | hebei hongtan Biotechnology Co., Ltd | |
 |
2024-04-12 | Guanidine carbonate
593-85-1
|
US $10.00 / kg | 1kg | 99% | 1000 | hebei hongtan Biotechnology Co., Ltd | |
 |
2023-11-04 | Guanidine carbonate
593-85-1
|
US $20.00-1.00 / kg | 1kg | 0.99 | 10 tons | Hebei Yanxi Chemical Co., Ltd. |
-
- Guanidine carbonate
593-85-1
- US $25.00 / kg
- 99%
- hebei hongtan Biotechnology Co., Ltd
-
- Guanidine carbonate
593-85-1
- US $10.00 / kg
- 99%
- hebei hongtan Biotechnology Co., Ltd
-
- Guanidine carbonate
593-85-1
- US $20.00-1.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.