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Zinc dimethyldithiocarbamate

Zinc dimethyldithiocarbamate
Zinc dimethyldithiocarbamate structure
CAS No.
137-30-4
Chemical Name:
Zinc dimethyldithiocarbamate
Synonyms
ZC;z75;ZDMC;Z 75;CUMAN;ZIRAM;Tuzet;Ciram;Milam;Zitox
CBNumber:
CB1202261
Molecular Formula:
C6H12N2S4Zn1
Formula Weight:
305.829
MOL File:
137-30-4.mol

Zinc dimethyldithiocarbamate Properties

Melting point:
248-257 °C(lit.)
Density 
1.66
vapor pressure 
<1 x 10-6 Pa
storage temp. 
APPROX 4°C
form 
Powder
Specific Gravity
1.71
color 
White
Water Solubility 
0.0065 g/100 mL
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck 
14,10172
BRN 
3707008
InChIKey
DUBNHZYBDBBJHD-UHFFFAOYSA-L
Indirect Additives used in Food Contact Substances
ZINC DIMETHYLDITHIOCARBAMATE
FDA 21 CFR
178.3120
CAS DataBase Reference
137-30-4(CAS DataBase Reference)
EWG's Food Scores
6
FDA UNII
73D8UA974J
IARC
3 (Vol. Sup 7, 53) 1991
NIST Chemistry Reference
Zinc, bis(dimethylcarbamodithioato-s,s')-, (t-4)-(137-30-4)
EPA Substance Registry System
Ziram (137-30-4)
Pesticides: Freedom of Information Act (FOIA)
Ziram
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS06,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H317-H318-H330-H335-H373-H410-H301-H340-H361-H371-H372
Precautionary statements  P260-P273-P280-P284-P305+P351+P338-P310-P201-P202-P264-P270-P271-P272-P301+P310+P330-P302+P352+P333+P313+P363-P304+P340+P310-P305+P351+P338+P310-P308+P311-P391-P403+P233-P405-P501
Hazard Codes  T+,N
Risk Statements  22-26-37-41-43-48/22-50/53
Safety Statements  22-26-28-36/37/39-45-60-61
RIDADR  UN 2811 6.1/PG 2
WGK Germany  3
RTECS  ZH0525000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29302000
Toxicity LD50 orally in rats: 1.4 g/kg (Hodge)

Zinc dimethyldithiocarbamate price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45708 Ziram PESTANAL 137-30-4 250mg $28 2021-12-16 Buy
Sigma-Aldrich 329711 Zinc dimethyldithiocarbamate 97% 137-30-4 1kg $145 2021-12-16 Buy
TCI Chemical D0717 Zinc Dimethyldithiocarbamate >97.0%(T) 137-30-4 25g $18 2021-12-16 Buy
TCI Chemical D0717 Zinc Dimethyldithiocarbamate >97.0%(T) 137-30-4 500g $52 2021-12-16 Buy
TRC Z439650 Zinc Dimethyldithiocarbamate 137-30-4 1g $80 2021-12-16 Buy

Zinc dimethyldithiocarbamate Chemical Properties,Uses,Production

Chemical Properties

White and odorless when pure. Almost insoluble inwater; soluble in acetone, carbon disulfide, chloroform, dilute alkalies, and concentrated hydrochloric acid.

Uses

Ziram is a protective fungicide applied to foliage to control diseases on pome fruit, stone fruit, nuts, vines, vegetables and ornamentals. It is used to control scab in apples and pears and Monilia, Alternaria, Septoria, peach leaf curl, shot hole, rusts, black rot and anthracnose. It is also used as a wildlife repellent, smeared as a paste onto tree trunks or sprayed onto ornamentals, dormant fruit trees and other crops.

Uses

Zinc Dimethyldithiocarbamate is a member of a class of dithiocarbamates, and has been used in agriculture as a fungicide and in the rubber industry as a vulcanization accelerator.

Uses

Rubber vulcanization accelerator; agricultural fungicide.

Definition

ChEBI: A dithiocarbamate salt that is the zinc salt of dimethyldithiocarbamic acid. It is a broad-spectrum fungicide and bird and animal repellent that is also used to accelerate the vulcanisation of rubber.

Air & Water Reactions

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Insoluble in water.

Reactivity Profile

Zinc bis dimethyldithiocarbamate is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides. Zinc bis dimethyldithiocarbamate is corrosive to iron and copper. Zinc bis dimethyldithiocarbamate is incompatible with strong oxidizing agents and acids. Zinc bis dimethyldithiocarbamate is also incompatible with mercury.

Hazard

Strong irritant to eyes and mucous membranes.

Fire Hazard

Zinc bis dimethyldithiocarbamate is combustible. Zinc bis dimethyldithiocarbamate may form explosive dust-air mixtures.

Agricultural Uses

Fungicide, Microbiocide, Animal repellant: Ziram is an agricultural fungicide registered to control fungal diseases on a wide range of crops including stone fruits, pome fruits, nut crops, vegetables and commercially grown ornamentals, and as a soil and seed treatment. In addition, it is formulated as a bird and rabbit repellent for outdoor foliar applications to ornamentals. Registered for use in EU countries . Registered for use in the U.S.

Trade name

AAPROTECT®; AAVOLEX®; AAZIRA®; ACCELERATOR®-L; ACCELERATOR® MZ® Powder; ACETO ZDED®; ACETO ZDMD®; ALCOBAM ZM®; ANCANZATE ME®; CARBAZINC®; CIRAM®; CORONA COROZATE®; COROZATE®; CUMAN®; CUMAN L®; CYMATE®; DRUPINA® 90; EPTAC-1®; FUCLASIN®; FUCLASIN® ULTRA; FUKLASIN®; FUNGOSTOP®; HERMAT ZDM®; HEXAZIR®; KARBAM WHITE®; KYPZIN®; METHASAN®; METHAZATE®; MEXENE®; MEZENE®; MILBAM®; MILBAN®; MOLURAME®; MYCRONIL®; OCTOCURE ZDM-50®; ORCHARD® BRAND ZIRAM; PERKACIT ZDMC®; POMARSOL® Z FORTE; PRODARAM®; PROKIL® Ziram; RHODIACID®; SOXINAL®-PZ; SOXINOL®-PZ; TRICARBAMIX Z®; TSIMAT®; TSIRAM® (Russian); ULTRA ZINC DMC®; VANCIDE® MZ-96; VANCIDE® 51Z Dispersion (with Zinc 2-mercaptobenzothiazolate); VANCIDE® 51Z Dispersion (with Ziram); ZERLATE®; ZINCMATE®; ZIMATE®; ZIMATE®; METHYL®; ZIRAMVIS®; ZIRASAN®; ZIRBERK®; ZIREX 90®; ZIRIDE®; ZIRTHANE®; ZITOX®

Contact allergens

Ziram is a rubber vulcanization accelerator of the dithiocarbamate group. Sensitization was reported in several patients. Ziram is also used as a fungicide and can cause contact dermatitis in agricultural workers.

Safety Profile

Poison by ingestion,intraperitoneal, and intravenous routes. Moderately toxicby inhalation. Questionable carcinogen with experimentalcarcinogenic and tumorigenic data. An experimentalteratogen. Other experimental reproductive effects.Human mutation d

Metabolic pathway

Ziram is one of the metal containing dithiocarbamates which generates dimethyldithiocarbamic acid by being cleaved in acidic conditions and in biological media. The resulting acid is conjugated with glucose and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic acid is further degraded to dimethylamine and CS2. An extensive review of the properties of dithiocarbamate pesticides was published by the World Health Organisation (WHO, 1988) from which much of the following information is taken.

Purification Methods

Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. [Beilstein 4 III 149, 4 IV 234.]

Degradation

Ziram is decomposed in acidic media and by UV irradiation (PM). Ziram is stable in alkaline media but unstable in acidic conditions, decomposing to dimethylamine and carbon disulfide.

Zinc dimethyldithiocarbamate synthesis

7646-85-7
128-04-1
137-30-4
Synthesis of Zinc dimethyldithiocarbamate from Zinc chloride and Sodium dimethyldithiocarbamate

Zinc dimethyldithiocarbamate Preparation Products And Raw materials

Raw materials

Preparation Products


Zinc dimethyldithiocarbamate Suppliers

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View Lastest Price from Zinc dimethyldithiocarbamate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-08-12 Zinc bis dimethyldithiocarbamate
137-30-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2020-11-16 ccelerator PZ (ZDMC); Ziram; Bis(dimethylcarbamodithioato-S,S')zinc
137-30-4
US $3.00 / KG 100KG 99% 10000kg Longyan Tianhua Biological Technology Co., Ltd
2019-07-06 Zinc bis dimethyldithiocarbamate
137-30-4
US $1.00 / kg 1kg 99% Customized Career Henan Chemical Co

Zinc dimethyldithiocarbamate Spectrum


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