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Potassium trifluoromethanesulfonate

CAS No.
2926-27-4
Chemical Name:
Potassium trifluoromethanesulfonate
Synonyms
TRIFLUOROMETHANESULFONIC ACID POTASSIUM SALT;Potassium trifL;POTASSIUM TRIFLATE;Potassium trifluorometh;POTASSIUM TRIFLUOROMETHANESULFOTE;Potassium trifluoromethylsulfonate;Potassium trifluoromethanesulfonate;POTASSIUM TRIFLUOROMETHANESULPHONATE;Potassiumtrifluoromethanesulphonate99%;POTASSIUM TRIFLUOROMETHANESULFONIC ACID
CBNumber:
CB1215063
Molecular Formula:
CF3KO3S
Molecular Weight:
188.17
MDL Number:
MFCD00042370
MOL File:
2926-27-4.mol
MSDS File:
SDS
Last updated:2024-03-12 14:17:34

Potassium trifluoromethanesulfonate Properties

Melting point 238.5°C
storage temp. Inert atmosphere,Room Temperature
form solid
color White to Almost white
Water Solubility Soluble in water.
Sensitive Hygroscopic
Hydrolytic Sensitivity 6: forms irreversible hydrate
BRN 3727495
InChI InChI=1S/CHF3O3S.K/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChIKey GLGXXYFYZWQGEL-UHFFFAOYSA-M
SMILES C(F)(F)(F)S([O-])(=O)=O.[K+]
CAS DataBase Reference 2926-27-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,C
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
3-10
TSCA  No
HazardClass  CORROSIVE
HS Code  29049090
NFPA 704
1
2 1

Potassium trifluoromethanesulfonate price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 422843 Potassium trifluoromethanesulfonate 98% 2926-27-4 5g $37.4 2024-03-01 Buy
Sigma-Aldrich 422843 Potassium trifluoromethanesulfonate 98% 2926-27-4 25g $117 2024-03-01 Buy
TCI Chemical T1549 Potassium Trifluoromethanesulfonate >98.0%(T) 2926-27-4 25g $80 2024-03-01 Buy
Alfa Aesar 020361 Potassium trifluoromethanesulfonate, 98% 2926-27-4 10g $51.7 2024-03-01 Buy
Alfa Aesar 020361 Potassium trifluoromethanesulfonate, 98% 2926-27-4 50g $177 2024-03-01 Buy
Product number Packaging Price Buy
422843 5g $37.4 Buy
422843 25g $117 Buy
T1549 25g $80 Buy
020361 10g $51.7 Buy
020361 50g $177 Buy

Potassium trifluoromethanesulfonate Chemical Properties,Uses,Production

Chemical Properties

white crystals or crystalline powder

Uses

Potassium trifluoromethanesulfonate is used in studies of mixed alkali effects and short range interactions in poly(ethylene oxide) electrolytes,1 and characteristics of the electrochemical behavior of glassy carbon in super-acid media.

Uses

Potassium trifluoromethanesulfonate is used as a reagent in the synthesis of guanine-quadruplex hybrid materials. It acts as a supporting electrolyte in the electrochemical study of evidence for gold anion in ethylenediamine. It is involved in the preparation of N-fluoro-2,4,6-trimethylpyridinium triflate by reacting with 2,4,6-trimethyl-pyridine. Further, it is used in the preparation of imidazolium salt, 3-methyl-1-(3R,3aR,6S,6aR)-[6-(benzyloxy)-hexahydrofuro[3,2-b]furan-3-yl]imidazolium trifluoromethanesulfonate.

General Description

Potassium trifluoromethanesulfonate (KOTf, potassium triflate) is the potassium salt of trifluoromethanesulphonic acid. It has been prepared by neutralizing a warm aqueous solution of trifluoromethanesulphonic acid with potassium carbonate. The structure of siloxane–poly(oxyethylene) hybrids doped with potassium triflate has been investigated.

structure and hydrogen bonding

According to the results of temperature dependent powder diffractometry potassium trifluoromethanesulfonate is dimorphic. The phase transition occurs between -63 degreesC and 45 degreesC. The low-temperature modification crystallizes monoclinic with a=10.300(3)Angstrom, b = 6.052(1) Angstrom, c = 14.710(4) Angstrom, beta =111.83(2)degrees (-120 degreesC) and the room-temperature modification with a=10.679(5) Angstrom, b=5.963(2)Angstrom, c=14.624(5)Angstrom, beta =111.57(3)degrees, Z=6, P2(1). According to single crystal structure determination, potassium trifluoromethanesulfonate consists of three different potassium-oxygen-coordination polyhedra, linked by sulfur atoms of the trifluoromethanesulfonate groups. This results in a channel structure with all lipophilic trifluoromethane groups pointing into these channels[1].

References

[1] Korus, G. , and M. Jansen . "Crystal structure, phase transition, and potassium ion conductivity of potassium trifluoromethanesulfonate." (2001).

335-05-7
2926-27-4
Synthesis of Potassium trifluoromethanesulfonate from TRIFLUOROMETHANESULFONYL FLUORIDE

Potassium trifluoromethanesulfonate Preparation Products And Raw materials

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View Lastest Price from Potassium trifluoromethanesulfonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Potassium trifluoromethanesulfonate pictures 2024-01-08 Potassium trifluoromethanesulfonate
2926-27-4
US $9.00 / KG 1KG 99% 50000tons Wuhan Boyuan Import & Export Co., LTD
Potassium trifluoromethanesulfonate pictures 2023-09-06 Potassium trifluoromethanesulfonate
2926-27-4
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
POTASSIUM TRIFLUOROMETHANESULFONATE pictures 2023-08-24 POTASSIUM TRIFLUOROMETHANESULFONATE
2926-27-4
US $100.00 / KG 1KG 99% 5000KG Hebei Mojin Biotechnology Co., Ltd
POTASSIUM TRIFLATE POTASSIUM TRIFLUOROMETHANESULFONIC ACID POTASSIUM TRIFLUOROMETHANESULPHONATE Potassium trifluoromethanesulfonate, pure, 99% Potassium trifluoromethanesulphonate 99% Potassiumtrifluoromethanesulphonate99% POTASSIUM TRIFLUOROMETHANESULFONATE (SEE 2983) TRIFLUOROMETHANESULFONIC ACID, POTASSIUM SALT (SEE 5144) Potassium trifluoromethylsulfonate POTASSIUM TRIFLUOROMETHANESULFOTE Potassium triflate, Trifluoromethanesulfonic acid potassium salt Potassium trifluoromethanesulfonate,Potassium triflate, Trifluoromethanesulfonic acid potassium salt Potassium trifluoromethanesulfonate,99%,pure Methanesulfonic acid, 1,1,1-trifluoro-, potassiuM salt(1:1) PotassiuM trifluoroMethanesulfonate 98% Potassium trifluorometh potassium trifluoromethanesulfonate CF3KO3S POTASSIUM TRIFLUOROMETHANESULFONATE, 98%POTASSIUM TRIFLUOROMETHANESULFONATE, 98%POTASSIUM TRIFLUOROMETHANESULFONATE, 98%POTASSIUM TRIFLUOROMETHANESULFONATE, 98% Potassium trifL POTASSIUM TRIFLUOROMETHANESULFONATE ISO 9001:2015 REACH TRIFLUOROMETHANESULFONIC ACID POTASSIUM SALT Potassium trifluoromethanesulfonate 2926-27-4 CF3SO3K CF3KSO3 CF3KO3S KCF3SO3 CF3O3SK Organic Building Blocks Sulfonic/Sulfinic Acid Salts Sulfur Compounds Metal Triflates Homogeneous Catalysts Catalysts for Organic Synthesis Building Blocks Building Blocks Chemical Synthesis Organic Building Blocks Sulfonic/Sulfinic Acid Salts Sulfur Compounds triflate Catalysts for Organic Synthesis Homogeneous Catalysts Metal Triflates Synthetic Organic Chemistry