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ETHYL ANTHRANILATE

CAS No.
87-25-2
Chemical Name:
ETHYL ANTHRANILATE
Synonyms
ETHYL 2-AMINOBENZOATE;ethyl-o-amino;o-(Ethoxycarbonyl)aniline;FEMA 2421;Ethylanthranilat;ETHYL ANTHRANILATE;2-carboethoxyaniline;ETHYL O-AMINOBENZOATE;Ethylanthranilate,98+%;Anthranilic acid ethyl
CBNumber:
CB1221396
Molecular Formula:
C9H11NO2
Molecular Weight:
165.19
MDL Number:
MFCD00007711
MOL File:
87-25-2.mol
MSDS File:
SDS
Last updated:2024-04-22 16:39:17

ETHYL ANTHRANILATE Properties

Melting point 13-15 °C (lit.)
Boiling point 129-130 °C/9 mmHg (lit.)
Density 1.117 g/mL at 25 °C (lit.)
vapor density 5.7 (vs air)
refractive index n20/D 1.564(lit.)
FEMA 2421 | ETHYL ANTHRANILATE
Flash point >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Insoluble in water but soluble in organic solvents
pka 2.20±0.10(Predicted)
form Clear liquid
color Light yellow
Specific Gravity 1.1170
Odor at 100.00 %. sweet floral grape orangeblossom wintergreen
Odor Type floral
JECFA Number 1535
BRN 878874
Stability Stable. Combustible. Incompatible with acids, bases, oxidizing agents.
LogP 2.57
CAS DataBase Reference 87-25-2(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) ETHYL ANTHRANILATE
FDA 21 CFR 172.515
EWG's Food Scores 1
FDA UNII 38Y050IUE4
EPA Substance Registry System Ethyl anthranilate (87-25-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H303-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/38
Safety Statements  26-36
WGK Germany  2
RTECS  DG2448000
Hazard Note  Irritant
TSCA  Yes
HS Code  29224999
Toxicity The acute oral LD50 value in rats was reported as 3.75 g/kg (3.32-4.18 g/kg) and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
NFPA 704
1
2 0

ETHYL ANTHRANILATE price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W242101 Ethyl 2-aminobenzoate ≥96%, FCC, FG 87-25-2 sample-k $54.6 2024-03-01 Buy
Sigma-Aldrich W242101 Ethyl 2-aminobenzoate ≥96%, FCC, FG 87-25-2 1kg $173 2024-03-01 Buy
Sigma-Aldrich W242101 Ethyl 2-aminobenzoate ≥96%, FCC, FG 87-25-2 10Kg $1070 2024-03-01 Buy
Sigma-Aldrich 242977 Ethyl 2-aminobenzoate ≥99% 87-25-2 100g $61.9 2024-03-01 Buy
Sigma-Aldrich PHR9022 Ethyl 2-aminobenzoate reference material 87-25-2 100MG $318 2022-05-15 Buy
Product number Packaging Price Buy
W242101 sample-k $54.6 Buy
W242101 1kg $173 Buy
W242101 10Kg $1070 Buy
242977 100g $61.9 Buy
PHR9022 100MG $318 Buy

ETHYL ANTHRANILATE Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Chemical Properties

Ethyl anthranilate has a faint, orange-flower odor and similar taste.

Occurrence

Reported found in grapes, orange juice, orange peel oil, starfruit and Vitis labrusca L.

Uses

Ethyl 2-aminobenzoate is used as a reactant in the amination of aryl chlorides, bromides, and triflates.

Uses

Perfumery and flavors, similar to methyl anthranilate.

Preparation

By esterification of anthranilic acid with ethanol in the presence of acid catalysts; by reacting sodium hypochlorite with an alkaline solution of phthalimide

Definition

ChEBI: Ethyl 2-aminobenzoate is a benzoate ester.

General Description

Colorless liquid with a fruity odor. Insoluble in water.

Air & Water Reactions

ETHYL ANTHRANILATE should be protected from air and light. Insoluble in water.

Reactivity Profile

ETHYL ANTHRANILATE may hydrolyze under acidic and basic conditions.

Fire Hazard

Flash point data for ETHYL ANTHRANILATE are not available. ETHYL ANTHRANILATE is probably combustible.

Pharmacology

Ethyl anthranilate behaved as a local anaesthetic, as measured by depression of muscle twitch, but was 50% less effective than the m- and p-aminobenzoate isomers. All three compounds potentiated the initial phase of caffeine-induced contracture of frog sartorius muscle, but the o-isomer had no effect on the peak tension of the contracture (Friedman, Bianchi & Weiss. 1974). It was proposed that the o-amino group has both steric and polar effects, its bulk preventing the inhibitory action of the carbonyl group on the caffeine-induced contracture of sartorius muscle, while the lone electron pair of the nitrogen atom induces a contracture on its own accord and potentiates a caffeine-induced contracture (Friedman, 1975).
Ethyl anthranilate (0-1 mmol/litre) decreased the frequency of the electric-organ discharges of the electric fish, Gnathonemus moori, but did not affect the individual pulse amplitudes, indicating that the compound acted on the pacemaker cells of the mesencephalic command nucleus (Walsh & Schopp, 1966).

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx.

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View Lastest Price from ETHYL ANTHRANILATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ETHYL ANTHRANILATE pictures 2024-04-22 ETHYL ANTHRANILATE
87-25-2
US $20.00 / kg 1kg 99% 20MT Hebei Zhuanglai Chemical Trading Co.,Ltd
ETHYL ANTHRANILATE pictures 2024-04-15 ETHYL ANTHRANILATE
87-25-2
US $32.00-1.30 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
ETHYL ANTHRANILATE pictures 2023-10-12 ETHYL ANTHRANILATE
87-25-2
US $20.00-9.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
FEMA 2421 ETHYL ANTHRANILATE ETHYL O-AMINOBENZOATE 2-AMINOBENZOIC ACID ETHYL ESTER o-aminobenzoicacid,ethylester o-amino-benzoicaciethylester ETHYL ANTHRANILATE 96+% FCC ETHYL 2-AMINOBENZOATE, 99+% ETHYL-2-AMINOBENZOATE 99% (GC) Ethylanthranilate,98+% Ethylanthranilat 2-Aminobenzoic acid ethyl Anthranilic acid ethyl Ethyl 2-aminobenzoate,Ethyl anthranilate ANTHRANILIC ACID ETHYL ESTER 2-(ethoxycarbonyl)aniline 2-amino-benzoicaciethylester 2-carboethoxyaniline Aminobenzoicacid,ethylester Benzoic acid, o-amino-, ethyl ester benzoicacid,2-amino-,ethylester Ethyl 2-aMinobenzoate, 99% 100GR 2-Aminobenzoic Acid Ethyl Ester Ethyl 2-Aminobenzoate Anthranilic Acid Ethyl Ester 4-(phenylmethylthio)quinazoline Ethyl Anthranilate > Tetracaine Impurity 6 (Ethyl 2-Aminobenzoate) Ethyl anthranilate USP/EP/BP ETHYL ANTHRANILATE FOR SYNTHESIS ETHYL 2-AMINOBENZOATE ethyl-o-amino o-(Ethoxycarbonyl)aniline Benzocaine Impurity D (BP) 87-25-2 H2NC6H4CO2C2H5 Organic Building Blocks Esters ESTER Building Blocks C8 to C9 Carbonyl Compounds Aromatic Esters