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5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester structure

CAS No.: 474330-54-6

Chemical Name:: 5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester

Synonyms: Methyl 5-aMino-2-broMo-4-Methylbenzoate;5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester;methyl 5-amino-2-bromo-4-methylbenzoate hydrochloride;Benzoic acid, 5-aMino-2-broMo-4-Methyl-, Methyl ester

CBNumber:: CB12609963

Molecular Formula:: C9H10BrNO2

Molecular Weight:: 244.09

MDL Number:

MOL File:: 474330-54-6.mol

MSDS File:: SDS

Last updated:2026-03-18 11:52:23

Product description	Number	Pack Size	Price
Methyl 5-amino-2-bromo-4-methylbenzoate 97%	M49799	250mg	$29
Methyl 5-amino-2-bromo-4-methylbenzoate 97%	M49799	1g	$35
Methyl 5-amino-2-bromo-4-methylbenzoate 97%	M49799	5g	$160
Methyl 5-amino-2-bromo-4-methylbenzoate 97%	M49799	10g	$310
Methyl 5-amino-2-bromo-4-methylbenzoate 97%	M49799	25g	$640
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5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester Properties

Boiling point	328.4±37.0 °C(Predicted)
Density	1.506±0.06 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
pka	2.60±0.10(Predicted)
Appearance	Light brown to gray Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302
Precautionary statements	P280-P305+P351+P338

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester price More Price(20)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Synthonix	M49799	Methyl 5-amino-2-bromo-4-methylbenzoate 97%	474330-54-6	250mg	$29	2026-05-06	Buy
Synthonix	M49799	Methyl 5-amino-2-bromo-4-methylbenzoate 97%	474330-54-6	1g	$35	2026-05-06	Buy
Synthonix	M49799	Methyl 5-amino-2-bromo-4-methylbenzoate 97%	474330-54-6	5g	$160	2026-05-06	Buy
Synthonix	M49799	Methyl 5-amino-2-bromo-4-methylbenzoate 97%	474330-54-6	10g	$310	2026-05-06	Buy
Synthonix	M49799	Methyl 5-amino-2-bromo-4-methylbenzoate 97%	474330-54-6	25g	$640	2026-05-06	Buy

Product number	Packaging	Price	Buy
M49799	250mg	$29	Buy
M49799	1g	$35	Buy
M49799	5g	$160	Buy
M49799	10g	$310	Buy
M49799	25g	$640	Buy

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester Chemical Properties,Uses,Production

Synthesis

67-56-1

745048-63-9

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester

474330-54-6

General procedure for the synthesis of methyl 5-amino-2-bromo-4-methylbenzoate from methanol and 5-amino-2-bromo-4-methylbenzoic acid: 5-amino-2-bromo-4-methylbenzoic acid (39.90 g, 0.17 mol) was suspended in methanol (500 mL). The suspension was cooled to 0 to 5 °C and thionyl chloride (40 mL, 0.54 mol) was added slowly and dropwise. The reaction mixture was heated to reflux for 6 hours. Upon completion of the reaction, the solution was concentrated under reduced pressure and the residue was diluted with ice water (500 g). The pH was adjusted to 7.5 with saturated aqueous sodium bicarbonate and subsequently extracted with ethyl acetate (3 x 200 mL). The organic phases were combined, washed with saturated saline (3 x 200 mL), dried over anhydrous magnesium sulfate, filtered and concentrated to dryness under reduced pressure to afford methyl 5-amino-2-bromo-4-methylbenzoate as a white solid (40.35 g, 95% yield).

References

[1] Patent: US2007/275907, 2007, A1. Location in patent: Page/Page column 19
[2] Patent: US2008/242596, 2008, A1. Location in patent: Page/Page column 15
[3] Bioorganic and Medicinal Chemistry Letters, 2009, vol. 19, # 19, p. 5632 - 5635
[4] Bioorganic and Medicinal Chemistry Letters, 2009, vol. 19, # 24, p. 6877 - 6881
[5] ChemMedChem, 2010, vol. 5, # 6, p. 827 - 831

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester synthesis

Synthesis of 5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester from Methyl 3-amino-4-methylbenzoate

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester Preparation Products And Raw materials

Raw materials

Methyl 3-amino-4-methylbenzoate 3-Amino-4-methylbenzoic acid 5-amino-2-bromo-4-methylbenzoic acid Methanol

Preparation Products

1H-Indazole-6-carboxylic acid, 5-broMo-, Methyl ester

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester Suppliers

Global( 73)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14304	58
CR Corporation Limited	+8613062833949	fred.wen@crcorporation.cn	China	8645	58
Changzhou Helios Biomedical Science and Technology Co.,LTD.	+8618961213068	gaoxue@czhelios.com	China	512	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19987	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +8618949823763	sales@tnjchem.com	China	25356	58
Aromsyn Co., Ltd.	+86-0571-85585865 +8613336024896	CB@aromsyn.com	China	19183	58
Aceschem Inc.	+1-817863-6948 +1-（817）863-6948	sales@aceschem.com	United States	19632	58
Jilin Chinese Academy of Sciences-yanshen Technology	+undefined18143011203	info@chemextension.com	China	42056	58

Supplier	Advantage
ATK CHEMICAL COMPANY LIMITED	60
Accela ChemBio Inc.	58
Win-Win chemical CO., Limited	58
CR Corporation Limited	58
Changzhou Helios Biomedical Science and Technology Co.,LTD.	58
Labnetwork lnc.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Aromsyn Co., Ltd.	58
Aceschem Inc.	58
Jilin Chinese Academy of Sciences-yanshen Technology	58

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester Spectrum

5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester(474330-54-6)¹HNMR

474330-54-6(5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester)Related Search:

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Methyl 5-amino-2,4-difluorobenzoate methyl 5-amino-o-anisate METHYL 5-AMINO-2-FLUOROBENZOATE 5-Amino-2-fluoro-4-methyl-benzoic acid methyl ester 5-AMino-2-chloro-4-fluoro-benzoic acid Methyl ester

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5-aMino-2-broMo-4-Methylbenzoic acid Methyl ester Methyl 5-aMino-2-broMo-4-Methylbenzoate Benzoic acid, 5-aMino-2-broMo-4-Methyl-, Methyl ester methyl 5-amino-2-bromo-4-methylbenzoate hydrochloride 474330-54-6