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(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene

(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene Structure
(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene structure
CAS No.
1063949-39-2
Chemical Name:
(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene
Synonyms
Bicyclo[2.2.2]octa-2,5-diene-2-methanol, α,α,5-trimethyl-7-(1-methylethyl)-, (1R,4R,7R)-;(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene
CBNumber:
CB12755479
Molecular Formula:
C15H24O
Molecular Weight:
220.35
MDL Number:
MFCD16876054
MOL File:
1063949-39-2.mol
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(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene Properties

Boiling point 303.0±11.0 °C(Predicted)
Density 0.952 g/mL at 25 °C
refractive index n20/D1.495
pka 14.85±0.29(Predicted)
optical activity [α]22/D +42.0°, c = 0.5 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H400
Precautionary statements  P273
Hazard Codes  Xn,N
Risk Statements  22-50/53
Safety Statements  60-61
RIDADR  UN 3077 9 / PGIII
WGK Germany  2

(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation CCH0005085 (1R,4R,7R)-7-ISOPROPYL-2-(1-HYDROXY-1-METHYLETHYL)-5-METHYLBICYCLO[2.2.2]OCTA-2,5-DIENE 95.00% 1063949-39-2 1G $726.44 2021-12-16 Buy
Product number Packaging Price Buy
CCH0005085 1G $726.44 Buy

(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene Chemical Properties,Uses,Production

Uses

Reactant for:

  • Chiral ligand for asymmetric 1,4-conjugate addition

Used for:
  • Rh-catalyzed asymmetric conjugate addition reaction of boronic acids to α,β-unsaturated ketones
  • Rhodium-catalyzed asymmetric arylation of imines

(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene Preparation Products And Raw materials

Raw materials

Preparation Products

(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene Suppliers

Global( 5)Suppliers
Supplier Tel Email Country ProdList Advantage
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Shandong Ono Chemical Co., Ltd. 0539-6362799 20） China 9998 58
Jinan ponder chemical co. LTD 0531-0000 thinklifescience@163.com China 19690 58
Energy Chemical 021-58432009 400-005-6266 marketing1@energy-chemical.com China 44894 58
Supplier Advantage
Sigma-Aldrich 80
Shandong Ono Chemical Co., Ltd. 58
Jinan ponder chemical co. LTD 58
Energy Chemical 58
(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene Bicyclo[2.2.2]octa-2,5-diene-2-methanol, α,α,5-trimethyl-7-(1-methylethyl)-, (1R,4R,7R)- 1063949-39-2