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Benzotrifluoride

Benzotrifluoride
Benzotrifluoride structure
CAS No.
98-08-8
Chemical Name:
Benzotrifluoride
Synonyms
Oxsol2000;usafma-16;USAF ma-16;Benzotrifluorid;Triflorotoluene;Benzotrifluoide;BENZOTRIFLUORIDE;Phenylfluoroform;BENZOTRIFLOURIDE;benzenylfluoride
CBNumber:
CB1292738
Molecular Formula:
C7H5F3
Formula Weight:
146.11
MOL File:
98-08-8.mol

Benzotrifluoride Properties

Melting point:
−29 °C(lit.)
Boiling point:
102 °C(lit.)
Density 
1.19 g/mL at 20 °C(lit.)
vapor pressure 
53 hPa (25 °C)
refractive index 
n20/D 1.414(lit.)
Flash point:
54 °F
storage temp. 
2-8°C
solubility 
0.45g/l Hydrolysis
form 
Liquid
color 
Clear colorless
Specific Gravity
1.199
explosive limit
1.4-9.3%(V)
Water Solubility 
<0.1 g/100 mL at 21 ºC
Merck 
14,1110
BRN 
1906908
Stability:
Stable. Highly flammable. Incompatible with strong oxidizing agents, strong bases, strong reducing agents.
InChIKey
GETTZEONDQJALK-UHFFFAOYSA-N
CAS DataBase Reference
98-08-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, (trifluoromethyl)-(98-08-8)
EPA Substance Registry System
Benzene, (trifluoromethyl)-(98-08-8)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F,T,C,N,Xn
Risk Statements  45-46-11-36/38-48/23/24/25-65-51/53-39/23/24/25-23/24/25-48/20/22-40-38-22
Safety Statements  53-26-36/37-45-62-61-23-16
RIDADR  UN 2338 3/PG 2
WGK Germany  3
RTECS  XT9450000
Autoignition Temperature 650 °C
Hazard Note  Flammable/Corrosive
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29049090
Hazardous Substances Data 98-08-8(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 15000 mg/kg LD50 dermal Rat > 2000 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H340 May cause genetic defects Germ cell mutagenicity Category 1A, 1B Danger
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.

NFPA 704

Diamond Hazard Value Description
3
3 1
Health   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
Flammability   3 Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
Instability   1 Normally stable, but can become unstable at elevated temperatures and pressures (e.g. propene)
Special  

(NFPA, 2010)

Benzotrifluoride price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 47582-U α,α,α-Trifluorotoluene solution certified reference material, 10,000 μg/mL in methanol 98-08-8 u $37.6 2018-11-13 Buy
Sigma-Aldrich 547948 α,α,α-Trifluorotoluene anhydrous, ≥99% 98-08-8 1l $77.2 2018-11-13 Buy
TCI Chemical T0439 Benzotrifluoride >98.0%(GC) 98-08-8 25g $14 2018-11-22 Buy
TCI Chemical T0439 Benzotrifluoride >98.0%(GC) 98-08-8 500g $42 2018-11-22 Buy
Alfa Aesar B21340 Benzotrifluoride, 99% 98-08-8 250g $23 2018-11-13 Buy

Benzotrifluoride Chemical Properties,Uses,Production

Chemical Properties

Clear colourless to light yellow liquid

Uses

An alternative solvent to dichloromethane

Uses

In dye chemistry; in the manufacture of substituted benzotrifluorides contg an ethylenic group, used in high polymer chemistry; in dielectric fluids, such as transformer oils.

Definition

ChEBI: A fluorohydrocarbon that is fluoroform in which the hydrogen is substituted by a phenyl group.

General Description

A clear colorless liquid with an aromatic odor. Flash point of 54°F. Vapors are heavier than air. Insoluble in water and slightly denser than water. May be toxic by inhalation.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Benzotrifluoride may react with oxidizing materials, strong bases and reducing agents.

Hazard

Highly toxic by inhalation. Flammable, dangerous fire risk.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Purification Methods

Purify benzotrifluoride by repeated treatment with boiling aqueous Na2CO3 (until no test for chloride ion is obtained), dry it with K2CO3, then with P2O5, and fractionally distil it. [Beilstein 5 IV 802.]

Benzotrifluoride Preparation Products And Raw materials

Raw materials

Preparation Products


Benzotrifluoride Suppliers

Global( 239)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
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Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40277 62
3B Pharmachem (Wuhan) International Co.,Ltd. 86-21-50328103 * 801、802、803、804 Mobile:18930552037
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021-67582001/03/05 saleschina@alfa-asia.com China 30168 84

Benzotrifluoride Spectrum


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