methyl 3-bromo-5-fluoro-2-methylbenzoate
- CAS No.
- 1187318-53-1
- Chemical Name:
- methyl 3-bromo-5-fluoro-2-methylbenzoate
- Synonyms
- methyl 3-bromo-5-fluoro-2-methylbenzoate;3-BROMO-5-FLUORO-2-METHYL-BENZOIC ACID METHYL ESTER;Benzoic acid, 3-bromo-5-fluoro-2-methyl-, methyl ester
- CBNumber:
- CB13033143
- Molecular Formula:
- C9H8BrFO2
- Molecular Weight:
- 247.06
- MDL Number:
- MFCD19440363
- MOL File:
- 1187318-53-1.mol
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P305+P351+P338 |
HS Code | 2916399090 |
methyl 3-bromo-5-fluoro-2-methylbenzoate price More Price(17)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TRC | B679560 | 3-Bromo-5-fluoro-2-methyl-benzoicAcidMethylEster | 1187318-53-1 | 500mg | $330 | 2021-12-16 | Buy |
Apolloscientific | PC510281 | Methyl 3-Bromo-5-fluoro-2-methylbenzoate | 1187318-53-1 | 5g | $1122 | 2021-12-16 | Buy |
ChemScene | CS-0061182 | Methyl3-bromo-5-fluoro-2-methylbenzoate | 1187318-53-1 | 5g | $597 | 2021-12-16 | Buy |
ChemScene | CS-0061182 | Methyl3-bromo-5-fluoro-2-methylbenzoate | 1187318-53-1 | 100mg | $54 | 2021-12-16 | Buy |
ChemScene | CS-0061182 | Methyl3-bromo-5-fluoro-2-methylbenzoate | 1187318-53-1 | 250mg | $94 | 2021-12-16 | Buy |
methyl 3-bromo-5-fluoro-2-methylbenzoate Chemical Properties,Uses,Production
Synthesis

67-56-1

1187318-52-0

1187318-53-1
At room temperature, 2-methyl-3-bromo-5-fluorobenzoic acid (4.2 g, crude) was dissolved in methanol (16 mL) and thionyl chloride (2.5 mL) was added slowly. The reaction mixture was heated to 70 °C with continuous stirring for 3 hours. Upon completion of the reaction, the mixture was cooled to room temperature and the solvent was removed under reduced pressure by rotary evaporator to give the crude product. The crude product was purified by silica gel column chromatography with the eluent of petroleum ether/ethyl acetate (50:1, v/v) to afford methyl 3-bromo-5-fluoro-2-methylbenzoate (2.3 g, 51% yield) as a yellow oil.
References
[1] Patent: WO2017/201069, 2017, A1. Location in patent: Paragraph 0516
methyl 3-bromo-5-fluoro-2-methylbenzoate Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10035 | 58 |
Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14459 | 58 |
CR Corporation Limited | +8613062833949 | fred.wen@crcorporation.cn | China | 8647 | 58 |
Changzhou Helios Biomedical Science and Technology Co.,LTD. | +8618961213068 | gaoxue@czhelios.com | China | 512 | 58 |
Nanjing Hengbei Chemicals Co., Ltd. | +86-25-58393656 | sales@hengbeichem.cn | China | 6854 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
Aromsyn Co., Ltd. | +86-0571-85585865 +8613336024896 | CB@aromsyn.com | China | 19183 | 58 |
Aceschem Inc. | +1-817863-6948 +1-(817)863-6948 | sales@aceschem.com | United States | 19632 | 58 |
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