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O-TOLUAMIDE

O-TOLUAMIDE
O-TOLUAMIDE structure
CAS No.
527-85-5
Chemical Name:
O-TOLUAMIDE
Synonyms
O-TOLUAMIDE;2-TOLUAMIDE;o-Tolylamide;o-Toluic amide;ORTHO-TOLUAMIDE;o-Toluene amide;2-methyl-benzamid;2-METHYLBENZAMIDE;o-Methylbenzamide;Formyl-o-toluidine
CBNumber:
CB1311529
Molecular Formula:
C8H9NO
Formula Weight:
135.16
MOL File:
527-85-5.mol

O-TOLUAMIDE Properties

Melting point:
141-142 °C (lit.)
Boiling point:
248.86°C (rough estimate)
Density 
1.086
refractive index 
1.5589 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
alcohol: very soluble(lit.)
pka
16.01±0.50(Predicted)
Merck 
13,9606
CAS DataBase Reference
527-85-5
FDA UNII
13WGF92B0H
EPA Substance Registry System
o-Toluamide (527-85-5)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302
Hazard Codes  Xn
Risk Statements  22
WGK Germany  3

O-TOLUAMIDE price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 260827 2-Methylbenzamide 98% 527-85-5 25g $54.3 2021-03-22 Buy

O-TOLUAMIDE Chemical Properties,Uses,Production

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 2, p. 586, 1943
The Journal of Organic Chemistry, 57, p. 2700, 1992 DOI: 10.1021/jo00035a030

General Description

White powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

O-TOLUAMIDE is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

Health Hazard

ACUTE/CHRONIC HAZARDS: O-TOLUAMIDE may react violently if exposed to open flame; it should be isolated from all sources of ignition.

Fire Hazard

Flash point data for O-TOLUAMIDE are not available, however O-TOLUAMIDE is probably combustible.

Purification Methods

Crystallise o-toluamide from hot water (10mL/g) and dry in air. [Noller Org Synth Coll Vol II 586 1943, Beilstein 9 H 465, 9 II 319, 9 III 2304.]

O-TOLUAMIDE Preparation Products And Raw materials

Raw materials

Preparation Products


O-TOLUAMIDE Suppliers

Global( 52)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
CONIER CHEM AND PHARMA LIMITED
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sales@conier.com CHINA 47496 58
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Dayang Chem (Hangzhou) Co.,Ltd.
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SiChuang NanBu Honesty Technology Co., Ltd. 15883665058 0838-5675166
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Dr. J. Pharmachem (India) +91 20 24332987
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Energy Chemical 400-005-6266 021-58432009-
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JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078
86-021-50426522,50426273 sales@jingyan-chemical.com China 10006 60

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