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4-Carboxyphenylboronic acid

Description Reference
4-Carboxyphenylboronic acid
4-Carboxyphenylboronic acid
CAS No.
14047-29-1
Chemical Name:
4-Carboxyphenylboronic acid
Synonyms
NSC 221170;AURORA 14935;AKOS BRN-0008;WLN: VHOR DBQQ;ZERENEX ZX001647;p-boronobenzoicacid;p-borono-benzoicaci;4-borono-benzoicaci;TIMTEC-BB SBB003899;RARECHEM AH PB 0147
CBNumber:
CB1312607
Molecular Formula:
C7H7BO4
Formula Weight:
165.94
MOL File:
14047-29-1.mol

4-Carboxyphenylboronic acid Properties

Melting point:
220 °C (dec.)(lit.)
storage temp. 
0-6°C
form 
Powder
color 
Off-white to light beige
BRN 
3031088
InChIKey
SIAVMDKGVRXFAX-UHFFFAOYSA-N
CAS DataBase Reference
14047-29-1(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  37/39-26-36
WGK Germany  2
RTECS  CY8925000
Hazard Note  Irritant
HazardClass  IRRITANT
HS Code  29319090
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H303 May be harmfulif swallowed Acute toxicity,oral Category 5 P312
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

4-Carboxyphenylboronic acid price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 456772 4-Carboxyphenylboronic acid 14047-29-1 1g $34.9 2017-11-08 Buy
Sigma-Aldrich 456772 4-Carboxyphenylboronic acid 14047-29-1 10g $254.5 2017-11-08 Buy
TCI Chemical C1353 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 14047-29-1 1g $28 2017-11-08 Buy
TCI Chemical C1353 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 14047-29-1 5g $96 2017-11-08 Buy
Alfa Aesar B20954 4-Carboxybenzeneboronic acid, 97% 14047-29-1 1g $28.1 2017-11-08 Buy

4-Carboxyphenylboronic acid Chemical Properties,Uses,Production

Description

4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.

Reference

  1. Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
  2. Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.

Chemical Properties

Off-white to light beige powder

Uses

suzuki reaction

Uses

Intermediates of Liquid Crystals

4-Carboxyphenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products


4-Carboxyphenylboronic acid Suppliers

Global( 374)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Frapp's ChemicalNFTZ Co., Ltd.
+86 (576) 8169-6106
+86 (576) 8169-6105 sales@frappschem.com China 887 50
Shenzhen Sendi Biotechnology Co.Ltd.
0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3218 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
inquiry@dakenchem.com CHINA 22144 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20803 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1374 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32765 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070;product@chemlin.com.cn
product@chemlin.com.cn CHINA 3015 60
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 10714 60
Zjartschem
+86-571-8723 8903 jocelynpan@zjarts.com
+86-571-87063838 jocelynpan@zjarts.com CHINA 660 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 10012 58

View Lastest Price from 4-Carboxyphenylboronic acid manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-12 4-Carboxyphenylboronic acid
14047-29-1
US $1.00 / KG 1G 99% 100KG

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