1,5-Dibromopentane
- CAS No.
- 111-24-0
- Chemical Name:
- 1,5-Dibromopentane
- Synonyms
- Br(CH2)5Br;1,5-Dibrompentan;1,5-DIBROMPENTANE;1,5-DIBROMOPENTANE;1,5-dibromo-pentan;Dibromo-1,5 pentane;Pentan-1,5-dibromid;Pentane,1,5-dibromo-;PENTANE-1,5-DIBROMIDE;1,5-PENTANE DIBROMIDE
- CBNumber:
- CB1317884
- Molecular Formula:
- C5H10Br2
- Molecular Weight:
- 229.94
- MDL Number:
- MFCD00000268
- MOL File:
- 111-24-0.mol
| Melting point | ?34 °C (lit.) |
|---|---|
| Boiling point | 110 °C/15 mmHg (lit.) |
| Density | 1.688 g/mL at 25 °C (lit.) |
| vapor density | 8 (vs air) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform, Methanol (Sparingly) |
| form | Liquid |
| color | Clear colorless to yellow-brown |
| Water Solubility | insoluble |
| BRN | 1209245 |
| InChIKey | IBODDUNKEPPBKW-UHFFFAOYSA-N |
| CAS DataBase Reference | 111-24-0(CAS DataBase Reference) |
| FDA UNII | B8Q228QYS1 |
| NIST Chemistry Reference | Pentane, 1,5-dibromo-(111-24-0) |
| EPA Substance Registry System | 1,5-Dibromopentane (111-24-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313 | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/38-22 | |||||||||
| Safety Statements | 23-26-36-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | SA0320000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29033036 | |||||||||
| NFPA 704 |
|
1,5-Dibromopentane price More Price(36)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 128007 | 1,5-Dibromopentane 97% | 111-24-0 | 100g | $42.9 | 2024-03-01 | Buy |
| Sigma-Aldrich | 128007 | 1,5-Dibromopentane 97% | 111-24-0 | 500g | $126 | 2024-03-01 | Buy |
| TCI Chemical | D0198 | 1,5-Dibromopentane >98.0%(GC) | 111-24-0 | 25g | $18 | 2024-03-01 | Buy |
| TCI Chemical | D0198 | 1,5-Dibromopentane >98.0%(GC) | 111-24-0 | 100g | $40 | 2024-03-01 | Buy |
| Alfa Aesar | A18465 | 1,5-Dibromopentane, 98% | 111-24-0 | 100g | $40.1 | 2024-03-01 | Buy |
1,5-Dibromopentane Chemical Properties,Uses,Production
Chemical Properties
clear colorless to yellow-brownish liquid and has an aromatic odor.. soluble in benzene and chloroform, insoluble in water.
Uses
1,5-Dibromopentane is used in the preparation of 1,5-di-Grignard reagent and novel spirocyclic pyrrolidones. It acts as a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast. It is involved in the synthesis of N-alkylated piperidine as well as tetrydrothiopyran (thiane) by reaction with primary amine and sodium sulfide respectively.
Uses
1,5-Dibromopentane can be used to prepare:
Derivatives of 5-pyrazolones.
O-alkylated phloroglucinol derivatives, which forms the core of poly(alkyl aryl ether) dendrimers.
Intermediate for dezocine viz, (R)-(+)-1-(5-bromopentyl)-1-methyl-7-methoxy-2-tetralone using 1-methyl-7-methoxy-2-tetralone.
Preparation
1,5-Dibromopentane was obtained by ring-opening bromination of tetrahydropyran. In a 500ml flask, add 250g of 48% hydrobromic acid, 75g of concentrated sulfuric acid, 21.5g of redistilled tetrahydropyran (86.5-87.5°C fraction) in turn to a reflux condenser and heat the brown mixture gently to reflux for 3h. After cooling to room temperature, partition the lower layer of dibromide and wash each with saturated sodium carbonate solution and water once. Dried with anhydrous calcium chloride. Distill under reduced pressure and collect the 104-106°C (2.53 kPa) fraction as 1,5-dibromopentane in 46-47 g yield and 80-82% yield.
1,5-Dibromopentane synthesis route
Synthesis Reference(s)
Organic Syntheses, Coll. Vol. 3, p. 692, 1955
The Journal of Organic Chemistry, 48, p. 1678, 1983 DOI: 10.1021/jo00158a018
General Description
1,5-Dibromopentane is a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast.
1,5-Dibromopentane Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Yancheng Longshen Chemical Co.,Ltd. | +86-0515-88706880; +8618352073383 | sales@longshenchem.com | China | 79 | 55 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 | cherry@crovellbio.com | China | 18458 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Firsky International Trade (Wuhan) Co., Ltd | +8615387054039 | admin@firsky-cn.com | China | 436 | 58 |
| Suzhou Sanyi Polymer Chemical Technology Co., Ltd. | +8615571922873 | 15571922873@163.com | China | 106 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7377 | 58 |
| Shaanxi Franta Biotechnology Co., Ltd | +86-13082019107 +86-13082019107 | admin@flanderff.com | China | 229 | 58 |
| hebei hongtan Biotechnology Co., Ltd | +86-86-1913198-3935 +8617331935328 | sales03@chemcn.cn | China | 951 | 58 |
| CONTIDE BIOTECH CO.,LTD | +85253358525 | xena@healthtide-api.com | China | 525 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
View Lastest Price from 1,5-Dibromopentane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2024-04-19 | 1,5-Dibromopentane
111-24-0
|
US $0.00 / G | 1G | 99% | 20 | CONTIDE BIOTECH CO.,LTD | |
 |
2024-04-19 | 1,5-Dibromopentane
111-24-0
|
US $2.00 / KG | 1KG | 99% | 500mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-04-15 | 1,5-Dibromopentane
111-24-0
|
US $30.00 / kg | 1kg | 99 | 20 ton | Suzhou Sanyi Polymer Chemical Technology Co., Ltd. |
-
- 1,5-Dibromopentane
111-24-0
- US $0.00 / G
- 99%
- CONTIDE BIOTECH CO.,LTD
-
- 1,5-Dibromopentane
111-24-0
- US $2.00 / KG
- 99%
- Jinan Finer Chemical Co., Ltd
-
- 1,5-Dibromopentane
111-24-0
- US $30.00 / kg
- 99
- Suzhou Sanyi Polymer Chemical Technology Co., Ltd.